Publications in 1995

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(242) "Molekül- und Kristallstrukturen zweier einkerniger Ruthenium(II)-Komplexe mit dem starken p-Akzeptorliganden 2,2'-Azobis(pyridin) (abpy): [mer-Ru(abpy)3](PF6)2 und Ru(abpy)2Cl2 (ctc-Isomer)" J. Fees, H.-D. Hausen und W. Kaim, Z. Naturforsch. 50b (1995) 15.

(243) "Variable Structure of the Cu2S2 Core in Doubly Thiolate-Bridged Dicopper(I) Complexes. X-ray Crystallographic Study of (dmp)2(o-CH3C6H4S)2Cu2, dmp = 2,9-Dimethyl-1,10-phenanthroline, and a Comment on the "Cu(0)" Complex
Cu(dpp)2, dpp = 2,9-Diphenyl-1,10-phenanthroline" A.F. Stange, E. Waldhör, M. Moscherosch und W. Kaim, Z. Naturforsch. 50b (1995) 115.

(244) "Electronic Structure of the 16 Valence Electron Fragments M(CO)3(PR3)2, M = Mo,W, R = iPr, Cy, in their Complexes with H2, THF and Three p-Conjugated Dinucleating Ligands: Electrochemistry and Spectroscopy of Different Oxidation States" W. Bruns, W. Kaim, E. Waldhör und M. Krejcik, Inorg. Chem 34 (1995) 663.

(245) "Metal-Metal Interaction in Ligand-Bridged Dimolybdenum(0,0) and -(I,0) Complexes with Very Small Frontier Orbital Gaps: Electrochemistry and Spectroscopic Properties of Three Neighboring Oxidation States" W. Kaim, W. Bruns, S. Kohlmann und M. Krejcik, Inorg. Chim. Acta 229 (1995) 143. 

(246) "The New Tetrafunctional p Acceptor Ligand 3,6-Bis(2'-pyrimidyl)-1,2,4,5-tetrazine (bmtz): Diruthenium Complexes of bmtz and of Its 1,4-Dihydro Form" W. Kaim und J. Fees, Z. Naturforsch. 50b (1995) 123.

(247) "Eine Metall-Metall-Bindung in der Biologie? Das dinukleare CuA-Zentrum in Cytochrom c-Oxidase und N2O-Reduktase H. Bertagnolli und W. Kaim, Angew. Chem. 107 (1995) 847; Angew. Chem. Int. Ed. Engl. 34 (1995) 771.

(248) "A Tale of Two Complexes: PtMen(RN=CH-CH=NR), n = 2 and n = 4 (R = Cyclohexyl). Why do Pt(II) and Pt(IV) Complexes Exhibit Virtually Identical Redox Behaviour and Colors?" S. Hasenzahl, H.-D. Hausen und W. Kaim, Chem. Eur. J. 1 (1995) 95.

(249) "A Systematic Synthetic Approach to a Novel, Mixed 2,3- and 2,4-C2B4-Erbium(III) Carborane Bent-Sandwich Complex" N.S. Hosmane, Y. Wang, H. Zhang, A.R. Oki, J.A. Maguire, E. Waldhör, W. Kaim, H. Binder und R.K. Kremer, Organometallics 14 (1995) 1101.

(250) "Axial Shielding of 5d8 and 5d7 Metal Centers in Dimesitylplatinum Complexes with Unsaturated Chelate Ligands: Spectroscopic and Spectroelectrochemical Studies of Four Different Oxidation States" W. Kaim und A. Klein, Organometallics 14 (1995) 1176.

(251) "When is an Odd-Electron Dinuclear Complex a Mixed-Valent Species? Tuning of Ligand-to-Metal Spin Shifts in Diruthenium Complexes of Non-Innocent Dicarbonylhydrazido Bis-Chelate Ligands" V. Kasack, W. Kaim, H. Binder, J. Jordanov und E. Roth, Inorg. Chem. 34 (1995) 1924.

(252) "Specific Insertion of O=C=S into the N-Si bond of an Extremely Electron-Rich Molecule as Evident from the X-Ray Crystal Structure" A. Ehlend, H.-D. Hausen und W. Kaim in Organosilicon Chemistry 2, Hrsg. N. Auner und J. Weis, VCH (Weinheim), 1995, S. 141.

(253) "EPR Evidence for Low-Lying MLCT States in Tetracyanoiron and -ruthenium Complexes with Strongly p-Accepting Chelate Ligands. Comparison with Isoelectronic Tetracarbonylmetal Species" E. Waldhör, J. Poppe, W. Kaim, E. Cutin, M. Garcia Posse und N.E. Katz, Inorg. Chem. 34 (1995) 3093.

(254) "Tetranuclear Pentaammineruthenium Complexes Bridged by p-Conjugated Tetracyano Ligands Related to TCNE. Synthesis and Spectroscopy of Different Oxidation States" M. Moscherosch, E. Waldhör, H. Binder, W. Kaim und J. Fiedler, Inorg. Chem. 34 (1995) 4326.

(255) "Bioanorganische Chemie"; W. Kaim und B. Schwederski, 2. überarbeitete Auflage, Teubner, Stuttgart, 1995.

(256) "Das Tetraalkyldigallan-Radikalanion [R2Ga-GaR2]·- mit Einelektronen-p-Bindung" W. Uhl, U. Schütz, W. Kaim und E. Waldhör, J. Organomet. Chem. 501 (1995) 79.

(257) "Insertion von CO2, COS und CS2 in die N-Si-Bindung des extrem elektronenreichen 1,4-Bis(trimethylsilyl)-1,4-dihydropyrazins und Bildung eines neuen poly(N,S-)heterocyclischen Systems durch mehrfache Cycloaddition" A. Ehlend, H.-D. Hausen, W. Kaim, A. Lichtblau und W. Schwarz, J. Organomet. Chem. 501 (1995) 283.

(258) "N,N’-Disilylated 1,4-Dihydropyrazines: Organosilyl Substitution Reactions, Structural Effects of Steric Hindrance, and Electron Exchange with C60" A. Lichtblau, A. Ehlend, H.-D. Hausen und W. Kaim, Chem. Ber. 128 (1995) 745.

(259) "Different Orbital Occupation by an Added Single Electron in 1,10-Phenanthroline and its 3,4,7,8-Tetramethyl Derivative. Evidence from EPR Spectroscopy of the Anion Radicals and of their Dimesitylplatinum(II) Complexes" A. Klein, W. Kaim, E. Waldhör und H.-D. Hausen, J. Chem. Soc., Perkin Trans. 2 1995 2121.

(260) "Conformational Equilibria of 2,5-Bis(1-phenyliminoethyl)pyrazine Anion Radical, Bpip·-. An EPR/ENDOR Study of Bpip·-, (Bpip·-)(RMg+)2, and of the Related Anion Radical of N-tert-Butyl-pyridine-2-carbaldimine (t-Bu-Pyca)" T. Stahl, V. Kasack und W. Kaim, J. Chem. Soc., Perkin Trans. 2 1995 2127.