Veröffentlichungen in 2003

(396) "The copper(I)/copper(II) transition in complexes with 8-alkylthioquinoline based multidentate ligands" C.-Y. Su, S. Liao, M. Wanner, J. Fiedler, C. Zhang, B.-S. Kang und W. Kaim, Dalton Trans. 2003, 189.

(397) "Synthesis and structure of bis(2-N,N-dimethylaminoethyl-selenolato)zinc and its transformation to ZnSe" S. Dey, V.K. Jain, S. Chaudhury, A. Knoedler und W. Kaim, Polyhedron, 22 (2003) 489.

(398) "Formation of racemate and mesocate complexes from an achiral C3-symmetrical ligand containing three benzimidazole groups" Y.-P. Cai, C.-Y. Su, C.-L. Chen, Y.-M. Li, B.-S. Kang, A.S.C. Chan und W. Kaim, Inorg. Chem., 42 (2003) 163.

(399) "Configurational selectivity in benzyldimethylarsine complexes of palladium(II) and platinum(II): Synthesis, spectroscopy and structures" P.P. Phadnis, V.K. Jain, A. Klein, M. Weber und W. Kaim, Inorg. Chim. Acta, 346 (2003) 119.

(400) "Synthesis and characterization of 3-dimethylaminopropylselenolate complexes of palladium(II) and platinum(II)" S. Dey, V.K. Jain, A. Knoedler und W. Kaim, Inorg. Chim. Acta 349 (2003) 104.

(401) "Long-Range Electronic Coupling in Various Oxidation States of a C4-Linked Tris(b-diketonato)ruthenium Dimer" Y. Hoshino, S. Higuchi, J. Fiedler, C.-Y. Su, A. Knödler, B. Schwederski, B. Sarkar, H. Hartmann und W. Kaim, Angew. Chem. 115 (2003) 698; Angew. Chem. Int. Ed. 42 (2003) 674.

(402) "Low-Valent Cobalt Complexes with Three Different p Acceptor Ligands: Experimental and DFT Studies of the Reduced and the Low-Lying Excited States of (R-DAB)Co(NO)(CO), R-DAB = Substituted 1,4-Diaza-1,4-butadiene" M. Sieger, M. Wanner, W. Kaim, D.J. Stufkens, T. L. Snoeck und S. Zalis, Inorg. Chem. 42 (2003) 3340.

(403) "The chemistry and biochemistry of the copper-radical interaction" W. Kaim, Dalton Trans. 2003, 761.

(404) "Synthesis and Spectroelectrochemical Characterization of a Novel Oxalate-Bridged Binuclear Ruthenium(III) Complex" T. Fujino, Y. Hoshino, M. Eto, Y. Masuda, Y. Yukawa, J. Fiedler, und W. Kaim, Chem. Lett. 32 (2003) 274.

(405) "[Ga9(CMe3)9]- - ein beständiges Clusterradikalanion, Boranaloge Chemie mit dem schweren Homologen Gallium" W. Uhl, L. Cuypers, W. Kaim, B. Schwederski und R. Koch, Angew. Chem. 115 (2003) 2524; Angew. Chem. Int. Ed. 42 (2003) 2422.

(406) "Resolving the Two-Electron Process for the Couple [(C5Me5)M(N^N)Cl]+/[(C5Me5)M(N^N)], M = Rh or Ir, into Two One-Electron Steps Using the 2,2'-Azobispyridine N^N Ligand, Fast Scan Cyclovoltammetry and Spectroelectrochemistry: Detection of Radicals Instead of MII Intermediates" W. Kaim, R. Reinhardt, S. Greulich und J. Fiedler, Organometallics 22 (2003) 2240.

(407) "3,6-Bis(2-pyrazinyl)-1,2,4,5-tetrazin: Ein neuer mehrfunktioneller Ligand und sein syn, fac-konfigurierter Bis(tricarbonylchlororhenium)-Komplex" B. Sarkar, W. Kaim, T. Schleid, I. Hartenbach und J. Fiedler, Z. Anorg. Allg. Chemie 629 (2003) 1353.

(408) "Ligand-directed Molecular Architectures: Self-assembly of Two-dimensional Rectangular Metallocycles and Three-dimensional Trigonal or Tetragonal Prisms" C.-Y. Su, Y.-P. Cai, C.-L. Chen, M.D. Smith, W. Kaim und H.C. zur Loye, J. Am. Chem. Soc. 125 (2003) 8595.

(409) "Multistep redox sequences of azopyridyl-(L-)bridged reaction centres in stable radical complex ions {(m-L)[MCl(h5-C5Me5)]2}·+, M = Rh or Ir: Spectroelectrochemistry and high-frequency EPR spectroscopy" S. Frantz, R. Reinhardt, S. Greulich, M. Wanner, J. Fiedler, C. Duboc-Toia und W. Kaim, Dalton Trans. 2003, 3370.

(410) "Replacement of 2,2'-Bipyridine by 1,4-Diazabutadiene Acceptor Ligands: Why the Bathochromic Shift for [(N^N)IrCl(C5Me5)]+ Complexes but the Hypsochromic Shift for (N^N)Ir(C5Me5)?" S. Zalis, M. Sieger, S. Greulich, H. Stoll und W. Kaim, Inorg. Chem. 42 (2003) 5185.

(411) "Azo compounds as electron acceptor or radical ligands in transition metal species: spectroelectrochemistry and high-field EPR studies of ruthenium, rhenium and copper complexes of 2,2'-azobis(5-chloropyrimidine)" W. Kaim, N. Doslik, S. Frantz, T. Sixt, M. Wanner, F. Baumann, G. Denninger, H.-J. Kümmerer, C. Duboc-Toia, J. Fiedler und S. Zalis, J. Mol. Struct. 656 (2003) 183.

(412) "First Crystal Structure Determination and High-Frequency EPR Study of an Organoarsanecopper Radical Complex" S. Ye, W. Kaim, B. Sarkar, B. Schwederski, F. Lissner, T. Schleid, C. Duboc-Toia und J. Fiedler, Inorg. Chem. Commun. 6 (2003) 1196.

(413) "Unsolvated "Carbons Apart" Neodymacarborane Sandwich Stabilized by Bis(h6-benzene)potassium Cation: A Unique Dimeric Mixed-Metal Sandwiched Ion-Pair" J. Wang, S. Li, C. Zheng, J.A. Maguire, W. Kaim und N.S. Hosmane, Inorg Chem. Commun, 6 (2003) 1220.

(414) "Synthesis and mixed valence aspects of [{(L)ClRu}2(m-tppz)]n+ incorporating 2,2´-dipyridylamine (L) as ancillary and 2,3,5,6-tetrakis(2-pyridyl)pyrazine (tppz) as bridging ligand" N. Chanda, B. Sarkar, J. Fiedler, W. Kaim und G.K. Lahiri, Dalton Trans. 2003, 3550.

(415) "What a Difference Ancillary Thienyl Makes: Unexpected Additional Stabilisation of the Diruthenium(III,II) but not the Diosmium(III,II) Mixed-Valent State in Tetrazine Ligand-Bridged Complexes" B. Sarkar, W. Kaim, A. Klein, B. Schwederski, J. Fiedler, C. Duboc-Toia und G.K. Lahiri, Inorg. Chem. 42 (2003) 6172.

(416) "Separating Innocence and Non-Innocence of Ligands and Metals in Complexes [(L)Ru(acac)2]n (n = -1, 0,+1; L = o-Iminoquinone or o-Iminothioquinone)" S. Patra, B. Sarkar, S.M. Mobin, W. Kaim und G.K. Lahiri, Inorg. Chem. 42 (2003) 6469.

(417) "Tri(allyl)- and tri(methylallyl)arsine complexes of palladium(II) and platinum(II): synthesis, spectroscopy, photochemistry and structures" P.P. Phadnis, V.K. Jain, A. Klein, T. Schurr und W. Kaim, New. J. Chem. 27 (2003) 1584.

(418) "Proof of Innocence for the Quintessential Non-Innocent Ligand TCNQ in its Tetranuclear Complex with Four [fac-Re(CO)3(bpy)]+ Groups – Unusually Different Reactivity of the TCNX Ligands (TCNX = TCNE, TCNQ, TCNB)" H. Hartmann, W. Kaim, M. Wanner, A. Klein, S. Frantz, C. Duboc-Toia, J. Fiedler und S. Zalis, Inorg. Chem. 42 (2003) 7018.

(419) "Synthesis and Formation of Dinuclear Mixed-valent Complexes of Ruthenium and Osmium Bridged by 2-(2-Pyrimidyl)benzimidazolate" M. Haga, M. Ishizuya, T. Kanesugi, D. Sakiyama, J. Fees und W. Kaim, Ind. J. Chem. 42A (2003) 2290.

(420) "Synthesis and characterization of 2-dimethylaminoethylthiolate complexes of palladium(II) and platinum(II)" S. Dey, V.K. Jain, A. Knoedler und W. Kaim, Ind. J. Chem. 42A (2003) 2339.

(421) "Electron transfer reactions of (C5R5)2(CO)2Ti (R = H or Me) with TCNE or TCNQ. Spectroelectrochemical assignment of metal and ligand oxidation states in [(C5Me5)2(CO)Ti(TCNX)]2-/-/o/+ " H. Hartmann, B. Sarkar, W. Kaim und J. Fiedler, J. Organomet. Chem. 687 (2003) 100.

(422) "Chemistry of C-Trimethylsilsyl-Substituted Heterocarboranes. 29. Synthetic and Structural Studies on Lanthanacarboranes with Two and Three „Carbons Apart"-Carborane Cages Bonding to Ln(III) Metal [Ln(III) = Nd, Gd, Dy, Ho, Er, Tb and Lu" J. Wang, S. Li, C. Zheng, J.A. Maguire, B. Sarkar, W. Kaim und N.S. Hosmane, Organometallics 22 (2003) 4334.

(423) "An Oxygen-Encapsulating Tetraholmium Tetrahedron Stabilized by Complexation with the "Carbons Apart" C2B4-Carborane Ligands" J. Wang, S. Li, C. Zheng, N.S. Hosmane, J.A. Maguire, H.W. Roesky, C.C. Cummins und W. Kaim, Organometallics 22 (2003) 4390.