Publications in 1996

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(261) "Coordination-Induced Switch between the Singly Occupied and the Lowest Empty MO in two Methylviologen-Derived Chromophors" E. Waldhör, M.M. Zulu, S. Zalis und W. Kaim, J. Chem. Soc., Perkin Trans. 2 1996 1197.

(262) "Kupfer - ein "modernes" Bioelement" W. Kaim und J. Rall, Angew. Chem. 108 (1996) 47; Angew. Chem. Int. Ed. Engl. 35 (1996) 43.

(263) "The d in 18+d Electron Complexes: Importance of the Metal/Ligand Interface for the Substitutional Reactivity of "Re(0)" Complexes (a-Diimine-I)Re+I(CO)3(X)" A. Klein, C. Vogler und W. Kaim, Organometallics 15 (1996) 236.

(264) "Generation and Characterization of Diphosphene and Triphosphene Radical Anions. Computational Studies on the Structure and Stability of P3H3·-" H. Binder, B. Riegel G. Heckmann, M. Moscherosch, W. Kaim, H.-G. von Schnering, W. Hönle, H.-J. Flad, A. Savin, Inorg. Chem. 35 (1996) 2119.

(265) "Pulled Molecular Strings and Stacked Molecular Decks. Chelate-Ring Formation vs. Metal-Metal-Bridging in Dicopper(I) Complexes of 2,2'-Bipyrimidine with Diphosphine Ligands of Variable Polymethylene Chain Length" M. Schwach, H.-D. Hausen und W. Kaim, Chem Eur. J. 2 (1996) 446.

(266) "p* Molecular Orbital Crossing a2(c)/b1(y) in 1,10-phenanthroline Derivatives. Ab initio Calculations and EPR/ENDOR Studies of 4,7-Diaza-1,10-phenanthroline Radical Anion and Its M(CO)4 Complexes (M=Cr,Mo,W) S. Ernst, C. Vogler, A. Klein, W. Kaim und S. Zalis, Inorg. Chem. 35 (1996) 1295.

(267) "UV/Vis, IR and EPR Spectroelectrochemical Study of the EC Redox Transition [(PR3)n(CO)3(R’-pz)M]+/o; M = Mo,W; R’-pz = N-Alkylpyrazinium; R = Isopropyl, Cyclohexyl; n = 1 or 2"  F. Hilgers, W. Bruns, J. Fiedler und W. Kaim, J. Organomet. Chem. 551 (1996) 273.

(268) "Gas Phase Structure of the Monomeric Alkylgallium(I) Compund Ga-C(SiMe3)3 and the Electrochemical Behavior of Ga4[C(SiMe3)3]4 and In4[C(SiMe3)3]4 with EPR Evidence for a Ga4R4 Radical Anion" A. Haaland, K.-G. Martinsen, H.V. Volden, W.Kaim, E. Waldhör, W. Uhl und U. Schütz, Organometallics 15 (1996) 1146.

(269) "Electronic Structure of p-Conjugated Redox Systems with Borane/Borataalkene End Groups" J. Fiedler, S. Zalis, A. Klein, F. Hornung und W. Kaim, Inorg. Chem. 35 (1996) 3039.

(270) "Chemistry of C-Trimethylsilyl-substituted Heterocarboranes. 20. Synthetic and Structural Studies on Sandwich Ln(III)-Carborane Clusters - Part II [Ln(III) = Sm, Gd, Dy, Ho and Er]" N.S. Hosmane, Y. Wang, H. Zhang, J.A. Maguire, M. McInnis, T.G. Gray, J.D. Collins, R.K. Kremer, H. Binder, E. Waldhör und W. Kaim, Organometallics 15 (1996) 1006.

(271) "Cp*Ir(dab), dab = 1,4-Bis(2,6-dimethylphenyl)-1,4-diazabutadiene: A Coordinatively Unsaturated 6 p Metallaheteroaromatic Compound ?" S. Greulich, W. Kaim, A. Stange, H. Stoll, J. Fiedler und S. Zalis, Inorg. Chem. 35 (1996) 3998.

(272) "Polychlorinated Biaryl Heterocycles as Potential Ligands. Reactions between Octachloro-1,10-phenanthroline and -2,2'-bipyridine with Copper(I) and other Metal Ions" C. Titze und W. Kaim, Z. Naturforsch. 51b (1996) 981.

(273) "A Tetragonal Bisphenoidal Tetracopper(I) Arrangement Supported by a Potentially Tridentate Ligand Containing Thiolate, Secondary Amine and 2-Pyridine Functions: Hydrogen-Bonded instead of Cu(I)-Coordinated Pyridine Rings in an S4-Symmetric Compound" A.F. Stange, K.-W. Klinkhammer und W. Kaim, Inorg. Chem. 35 (1996) 4087.

(274) "Bis(homoleptische) vs. heteroleptische Kupfer(I)-Komplexe: Elektrosynthese, Spektroskopie und Kristallstruktur von {[Cu(BIK)2]+}2{[Cu4(SR)6]2-}·3 (CH3CN)·(RSH); BIK = Bis(N-methylimidazol-2-yl)keton, R = o-Tolyl" A.F. Stange und W. Kaim, Z. Anorg. Allg. Chem. 622 (1996) 1118.

(275) "Ground State Electron Transfer Between TCNE and One or More 16 Electron Species Containing Vanadium, Osmium, Ruthenium or Cobalt"  F. Baumann, M. Heilmann, W. Matheis, A. Schulz, W. Kaim und J. Jordanov, Inorg. Chim. Acta 251 (1996) 239.

(276) "Electron Transfer and Chloride Ligand Dissociation in Complexes [(C5Me5)MCl(bpy)]+/[(C5Me5)M(bpy)]n (M = Co,Rh,Ir; n = 2+,+,0,-). A Combined Electrochemical and Spectroscopic Investigation" W. Kaim, R. Reinhardt, E. Waldhör und J. Fiedler, J. Organomet. Chem. 524 (1996) 195. 

(277) "Electron-Acceptor Behavior of 2,4,7,9-Tetracarba-nido-Dodecaborane(12) with Group 1 and Group 2 Metals: Synthesis and Crystal Structure of [(THF)4Li][SiMe3)4C4B8H9] and [(THF)2Mg(SiMe3)4C4B8H8]" N.S. Hosmane, H. Zhang, Y. Wang, K.-J. Lu, C.J. Thomas, M. Ezhova, S.C. Helfert, J.D. Collins, J.A. Maguire, T.G. Gray, F. Baumann und W. Kaim, Organometallics 15 (1996) 2425.

(278) "Structure, EPR and UV/vis/IR Spectroelectrochemistry of Reversibly Reducible Compounds [(C5Me5)IrCl(L)](PF6), L = 1,3-Dimethyllumazine or 1,3-Dimethylalloxazine" O. Heilmann, F.M. Hornung, W. Kaim und J. Fiedler, J. Chem. Soc., Faraday Trans. 92 (1996) 4233.

(279) "Configuration-Dependent Electron Hopping between Equivalent Ligands in Isomeric Ruthenium(II) Complexes" M. Heilmann, F. Baumann, W. Kaim und J. Fiedler, J. Chem. Soc., Faraday Trans. 92 (1996) 4227.

(280) "Synthese und Charakterisierung des stabilen Dicarbonylcyclopentadienyleisen-Radikals [(C5R5)Fe(CO2)]· (R = CHMe2)" H. Sitzmann, T. Dezember, W. Kaim, F. Baumann, D. Stalke, J. Kärcher, E. Dormann, H. Winter, C. Wachter und M. Kelemen, Angew. Chem. 108 (1996) 3013; Angew. Chem. Int. Ed. Engl. 35 (1996) 2872.