Terrae Rarae 2024

32. Tage der Seltenen Erden in Stuttgart, Germany

Program

11:30 Begin registration

13:00 Opening remarks

Chair: Prof. Dr. Rainer Niewa

13:15 Plenary Lecture: Dr. Florian Jaroschik (Institute Charles Gerhardt, Montpellier, France): Twenty years of low-valent lanthanide chemistry with superbulky Cp ligands

14:10 Dr. Sandeep K. Thakur (Friedrich-Alexander Universität Erlangen-Nürnberg, Germany): Similarities and Differences in Benzene Reduction with Ca, Sr, Yb and Sm: Benzene2− versus Benzene4−

14:30 Dr. Salauat Kiraev (École Normale Supérieure de Lyon, France): Photophysical Properties of Triazacyclononane Complexes with Thioanisolyl-Picolinates as a Function of the Lanthanide Ion

14:50 Dr. Dimitrii Roitershtein (Topochiev Institute of Petrochemical Synthesis, Moscow, Russia): N-Heterocyclic Tridentate Ligands for the Design of Rare Earth Complexes

15:10 − 15:40 Coffee break

Chair: Prof. Dr. Christian Sindlinger

15:40 Prof. Dr. Richard Layfield (University of Sussex, Brighton, UK): The Pursuit of Exotic Oxidation States in Rare Earth Chemistry

16:00 Dr. Elisabeth Kreidt (TU Dortmund University, Germany): Photoswitching lanthanoid luminescence with diazocines

16:20 Dina Akl (École Normale Supérieure de Lyon, France): NIR-NIR Lanthanide Emitting Bioprobes for Invivo Imaging

16:40 Dr. Nicolaj Kofod (University of Manchester, UK): Non-Radiative Transitions in Lanthanide Photophysics

17:00 Nathan Alcock (University of Manchester, UK): Determination of actinide central-field covalency with 3d4f resonant inelastic X-ray scattering (RIXS)

Chair: Prof. Dr. Thomas Schleid

17:20 Plenary lecture: Prof. Dr. Thomas Albrecht (Colorado School of Mines, Golden, CO, USA): Chemistry Beyond Plutonium

18:20 – 20:00 Poster session

Chair: Prof. Dr. Holger Kohlmann

09:00 Plenary lecture: Prof. Dr. Susan Kauzlarich (University of California, Davis, CA, USA): Zintl Phases, Hydrides, and Electrides: Synthesis, Properties, and Applications

10:00 Dr. Svetlana Klementyeva (Karlsruhe Institute of Technology, Germany): Lanthanide vertices in main group clusters

10:20 Villads Nielsen (University of Copenhagen, Denmark): Relating Electronic Structure with molecular structure of Neodymium(III) complexes

10:40 − 11:10 Coffee break

Chair: Prof. Dr. Stephan Hohloch

11:10 Dr. Jack Baldwin (University of Manchester, UK): Low-coordinate lanthanide complexes with bulky silylphosphide ligands

11:30 Dr. Sophie Corner (University of Manchester, UK): Rare Earth Diaza-diborolyl Complexes

11:50 Dr. Maxime Beauvois (University of Tübingen, Germany): Rare-earth-metal complexes bearing group 13 heterobenzene ligand

12:10 Dr. Johann Hlina (University of Graz, Austria): Towards Rare-Earth-Transition Metal Complexes for Application in Hydrofunctionalisation Catalysis

12:30 − 14:00 Lunch Break

Chair: Prof. Dr. Thomas Just Sørensen

14:00 Plenary lecture: Prof. Dr. Peter Junk (James Cook University, Townsville, Qld, Australia):  Recent developments in redox transmetallation chemistry involving rare earth metals (plenary lecture)

15:00 Prof. Dr. Sjoerd Harder (Friedrich-Alexander Universität Erlangen-Nürnberg, Germany): Synthesis and Structure of a Mg(0)-Yb(II) Complex

15:20 Dr. Guillaume Bousrez (Aarhus University, Denmark): Using ionic liquid to generate anhydrous lanthanide acetate

15:40 − 16:10 Coffee break

Chair: Prof. Dr. Reiner Anwander

16:10 Prof. Dr. Anja-Verena Mudring (Aarhus University, Denmark): Molten Salts and Ionic Liquids for f-Element Chemistry

16:30 Prof. Dr. David Mills (University of Manchester, UK): Towards linear lanthanide single-molecule magnets

16:50 Prof. Dr. Gaël Ung (University of Conneticut, Storrs, CT, USA): Circularly Polarized Luminescence of Curium and Americium molecular complexes

17:10 Prof. Dr. Thomas J. Sørensen (University of Copenhagen, Denmark): f-elements in solution, do we care?

17:30 Prof. Dr. Peter Roesky (Karlsruhe Institute of Technology, Germany): Multidecker Sandwich Compounds

From 19:15 Conference Dinner

Chair: Prof. Dr. Ingo Hartenbach

09:00 Plenary lecture: PD Dr. Oliver Janka (Saarland University, Saarbrücken, Germany): Rare earth based intermetallic aluminum compounds – structures and properties

10:00 Erich Turgunbajew (Augsburg University, Germany): Rare Earth doped Borosulfates – Candidates for Quantum cutting?

10:20 Marvin Michak (Leipzig University, Germany): In situ investigations on H/O exchange reactions in yttrium hydride oxide YHO

10:40 – 11:10 Coffee break

Chair: Prof. Dr. Peter Roesky

11:10 Prof. Dr. Stephan Hohloch (University of Innsbruck, Austria): Putting the F in Phosphorus: Lanthanide Chemistry with Anilidophosphine Ligands

11:30 Prof. Dr. Fabrizio Ortu (University of Leicester, UK): New rare earth iminophosphoranomethanide complexes: synthesis, characterisation and applications

11:50 Jonas Malzacher (University of Tübingen, Germany): Donor-free samarium silylamides

12:10 Elias Alexopoulus(University of Leicester, UK): Phosphinoaryloxide Rare Earth Complexes for Frustrated Lewis Pair Chemistry

12:30 Prof. Dr. Gerd Meyer (Aarhus University, Denmark): Halides as Electrolytes for All-Solid-State Batteries

12:50 Closing remarks

P01 M. Tomar, A. Thapper, K. E. Borbas: Exploring chromophore-Ln(III) Interaction to Improve Photocatalytic Efficiency
P02 C. Foster, D. Sneddon, L. Hacker, E. Hammond, S. J. Conway, S. Faulkner: Activatable lanthanide complexes for luminescence and MRI
P03 V. Wessels, N. S. Kaur, S. Kügle, H. A. Höppe: Sulfatotungstates – Promising Candidates as Antenna Phosphors?
P04 E. C. J. Gießelmann, S. Engel, G. Kickelbick, O. Janka: Synthesis and oxidation of intermetallic aluminum compounds
P05 S. Engel, O. Janka: The rare earth platinides series REAl5Pt3 and RE2Al16Pt9
P06 P. Preisenberger, C. Maichle-Mössmer, R. Anwander: Reactivity of Ytterbium and Calcium pyrazolate complexes towards CO2
P07 J. Emerson-King, C. Clayton, A. Adel a Babtain, S. Sarfraz, G. F.S. Whitehead, D. P. Mills: Synthesis and reactivity of low-coordinate rare-earth silylamide complexes
P08 K. Huang, M. P. Walter: Synthesis of Open Base-free Metallocenes with Diva­lent Rare-earth and Alkaline-earth Metals
P09 O. F. Fellner, P. Sagar, E. Moreno-Pineda, A. Sunil, R. Herchel, W. Wernsdorfer, I. Nemec: Towards a Toroidal Moment via Carboxylate Ligand Exchange
P10 G. Buchner, P. Ettlinger, H. A. Höppe: Silver-Rare-Earth-Double-Sulphate-Hydrates AgLn(SO4)2∙H2O (Ln = La – Nd, Sm – Gd)
P11 J. Locher, L. Vondung: Lanthanide Complexes with Bis-Phosphine Ligands
P12 P. Wetzel, D. C. Burghardt, C. Maichle-Mössmer, R. Anwander: Gallium outperforms aluminum in rare-earth-metal-based isoprene polymerization
P13 K. K. Wolff, L. H. Tjeng, M. Jansen: 3d-5d double perovskites containing rare earth metals
P14 C. Odenwald, C. Maichle-Mössmer, R. Anwander: Sandwich and Half-Sandwich Lanthanum Methyl Complexes
P15 H. Redmill, A. Brookfield, G. F. S. Whitehead, E. J. L McInnes, D. P Mills: Solvent-free Rare Earth Bis(trimethylsilyl)phosphide Complexes
P16 J. Kohl-Chandramohan, M. R. Schweikert, T. Junginger, I. Hartenbach, Marie-Louise Lemloh: Bioaccumulation and excretion of rare earth-containing par­ti­cles in the single-celled eukaryote Tetrahymena
P17 R. Risken, E. Kreidt: DOTA-based photoswitchable ligands for lanthanoids
P18 K. Mamonov, M. C. Wied, T. J. Sørensen: Effect of charge on oxyanion sensing in Eu(III)-based nanooptodes
P19 M. C. Wied, K. Mamonov, T. J. Sørensen: Preparation of a europium(III)-based nanooptode for bicarbonate sensing by nanoparticle surface post-complexation
P20 L. Y. Dorsch, T. Hansen, H. Kohlmann: Investigating the hydrogenation of Zintl phases EuTt (Tt = Si, Ge, Sn)
P21 C. Schwab, E. Kreidt: Azobenzene Cryptates as Photoswitchable Ligands
P22 N. Winterholler, E. Kreidt: Diazocines as building blocks in lanthanoid coordination compounds
P23 A. Babtain, D. Willcox, D. P. Mills: Expanding Lanthanide Chemistry Using Redox-Active Di(Imino)Pyridine Ligands
P24 R. E. MacKenzie, C. A. P. Goodwin: Valence Electron Configurational Isomers – f-Block Elements Acting Like d-Block Elements?
P25 K. Engel, Th. Schleid: From RbEu[AsS4] to Rb4Eu[AsS4]2: Synthesis and Characterization
P26 B. Knies, I. Hartenbach: The Neodymium Tantalate NdTaO4 in the M-Ferguso­nite Structure Type
P27 C. A. von Randow, G. Thiele: The Quest of a Samaride – The First Isolated Lanthanide Anion
P28 R. J. C. Locke, A. Erden, Th. Schleid: Pr3OI[AsO3]2: The First Oxide Iodide Oxoarsenate of the Rare-Earth Metals
P29 Y. Rechkemmer, J. Fischer, R. Marx, M. Dörfel, P. Neugebauer, M. Gysler, J. van Slageren: Crystal Field Splittings in Molecular Lanthanide Tetra- Carbonates
P30 V. Babizhetskyy, Yu. Tyvanchuk, V. Smetana, A.-V. Mudring: Crystal and electronic structure of the ternary silicides RFe1−xSi2 (R = Gd, Tb, Er, Tm, Yb)
This image shows Ingo Hartenbach

Ingo Hartenbach

Prof. Dr. rer. nat.

Group Leader

This image shows Falk Lissner

Falk Lissner

Dr. rer. nat.

Lecturer / Researcher

This image shows Björn Blaschkowski

Björn Blaschkowski

Dr. rer. nat.

Scientific Staff

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