Publications in 2000

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(337) "Insertion of Aromatic Diisocyanates into the N-Si Bonds of 1,4-Bis(trimethylsilyl)-1,4-dihydropyrazine" T. Sixt, K.-W. Klinkhammer, A. Weismann und W. Kaim in Organosilicon Chemistry IV, Hrsg. N. Auner und J. Weis, WILEY-VCH (Weinheim), 2000, S. 294.

(338) "Structures and Properties of Complexes [MCl(C5Me5)(N^S)](PF6), M = Rh, Ir, with N^S = 1-methyl-2-(alkylthiomethyl)-1H-benzimidazole ligands" M. Albrecht, T. Scheiring, T. Sixt und W. Kaim, J. Organomet. Chem. 596 (2000) 84.

(339) "Geometrical and Electronic Structures of the Acetyl Complex Re(bpy)(CO)3(COCH3) and of [M(bpy)(CO)4](OTf), M = Mn,Re"T. Scheiring, W. Kaim und J. Fiedler, J. Organomet. Chem. 598 (2000) 136.

(340) "Iron vs. ruthenium oxidation in 1,1'-bis(diphenylphosphino)ferrocene-ruthenium(II) complexes: EPR and spectroelectrochemical evidence" T Sixt, J. Fiedler und W. Kaim, Inorg. Chem. Commun. 3 (2000) 80.

(341) "Chemistry of C-Trimethylsilyl-Substitued Heterocarboranes. 28. Selective Alkylation and Reactivity of "Carbons Adjacent" and "Carbons Apart" Tetracarba-nido-dodecaborane(12) Derivatives toward Group 1 and Group 2 Metals. Synthetic, Spectroscopic, and Structural Investigations on Lithium-, Sodium-, Potassium-, Cesium- and Magnesium-Complexed C4B8 Carboranes" N.S. Hosmane, H. Zhang, J.A. Maguire, Y. Wang, T. Demissie, T.J. Colacort, M.B. Ezhova, K.-J. Lu, D. Zhu, T.G. Gray, S.C. Helfert, S.N. Hosmane, J.D. Collins, F. Baumann, W. Kaim und W.N. Lipscomb, Organometallics 19 (2000) 497.

(342) "Synthesis of a Large Organometallic Macrocycle Comprising Four Ga-Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands" W. Uhl, T. Spies, D. Haase, R. Winter und W. Kaim, Organometallics 19 (2000) 1128.

(343) "Syntheses, Structures and Properties of Complexes [Ag(N^S)n](X), N^S = 1-Methyl-2-(alkylthiomethyl)-1H-benzimidazoles, X = PF6 (n = 2) or PO2F2 (n =1)" M. Albrecht, K. Hübler und W. Kaim, Z. Anorg. Allg. Chem. 626 (2000) 1033.

(344) "A Copper(I) dimer [Cu(L)(CH3CN)]2(BF4)2 with the new chelating and bridging tridentate ligand 1-(2-pyridylmethyl)-2-(2-pyridyl)benzimidazole (L)" A. Knoedler, K. Hübler, T. Sixt und W. Kaim, Inorg, Chem. Commun. 3/4 (2000) 182.

(345) "The Valence-Localized Decacyanodiruthenium(III,II) Analogue of the Creutz-Taube Ion. Completing the Full d5/d6 Triad [(NC)5M(m-pz)M(CN)5]5-, M = Fe,Ru,Os; pz = Pyrazine" T. Scheiring, W. Kaim, J.A. Olabe, A.R. Parise und J. Fiedler, Inorg. Chim. Acta 300-302 (2000) 125.

(346) "Copper(I) Complexes with N,O-Donor Schiff Base Ligands Related to Intermediate Forms of the TPQ Cofactor in Amine Oxidases" T. Sixt und W. Kaim, Inorg. Chim. Acta 300-302 (2000) 762.

(347) "Electron Paramagnetic Resonance and Spectroscopic Characteristics of Electrogenerated Mixed-Valent Systems [(h5-C5Me5)M(m-L)M(h5-C5Me5)]+ (M = Rh,Ir; L = 2,5-diiminopyrazines) in Relation to the Radicals [(h5-C5Me5)ClM(m-L)MCl(h5-C5Me5)]+ and [(h5-C5Me5)M(m-L)MCl(h5-C5Me5)]2+" S. Berger, A. Klein, M. Wanner, J. Fiedler und W. Kaim, Inorg. Chem. 39 (2000) 2516.

(348) "Koordination von Rhodium(III), Iridium(III) und Kupfer(II) mit dem potentiell vierzähnigen Akzeptorliganden Bis(1-methylimidazol-2-yl)glyoxal (big) M. Albrecht und W. Kaim, Z. Anorg. Allg. Chem. 626 (2000) 1341.

(349) "Characterization of the Inorganic/Organometallic Osmium(IV) Compound [Cp*2OsIVCl]2[OsIVCl6] as Formed by the Reaction of OsCl3 with Pentamethylcyclopentadiene in Air" T. Sixt, W. Kaim, und W. Preetz, Z. Naturforsch. 55b (2000) 235.

(350) "Tri(supersilyl)dialanyl (tBu3Si)3Al and Tetra(supersilyl)cyclotrialanyl (tBu3Si)4Al - New Stable Radicals of a Group 13 Element from Thermolysis of (tBu3Si)4Al2" N. Wiberg, T. Blank, W. Kaim, B. Schwederski und G. Linti, Eur. J. Inorg. Chem. (2000) 1475.

(351) "Structures and spectroelectrochemistry (UV-vis, IR, EPR) of complexes [(OC)3ClRe]n(abpy), n = 1,2; abpy = 2,2'-azobispyridine" H. Hartmann, T. Scheiring, J. Fiedler und W. Kaim, J. Organomet. Chem. 604 (2000) 267.

(352) "Photochemical and Photophysical Deactivation of 2,4,6-Triaryl-1,3,5-triazines" F. Elbe, J. Keck, H.E.A. Kramer, P. Fischer, P. Hayoz, D. Leppard, G.Rytz, W. Kaim und M. Ketterle, J. Phys.Chem. A 104 (2000) 8296.

(353) "Metal vs. Ligand Reduction in Complexes of 1,3-Dimethylalloxazine (DMA) with Copper(I), Ruthenium(II) and Tungsten(VI). Crystal Structures of (DMA)WO2Cl2 and (Bis(1-methylimidazol-2-yl)ketone)WO2Cl2" F.M. Hornung, O. Heilmann, W. Kaim, S. Zalis und J. Fiedler, Inorg. Chem. 39 (2000) 4052.

(354) "Crucial Role of the Cu-S Bonding for Structural Changes Accompanying the Reversible CuI/CuII Transition in an Unrestrained Cu(N^S)2 Coordination Arrangement. An Experimental and DFT Study" M. Albrecht, K. Hübler, S. Zalis und W. Kaim, Inorg. Chem. 39 (2000) 4731.

(355) "Reversible and Site-Specific Reduction of the Ligand Sides in a Molecular Rectangle with up to Eight Electrons" H. Hartmann, S. Berger, R. Winter, J. Fiedler und W. Kaim, Inorg. Chem. 39 (2000) 4977.

(356) "Exploration of Mixed-Valence Chemistry: Inventing New Analogues of the Creutz-Taube Ion" W. Kaim, A. Klein und M. Glöckle, Acc. Chem. Res. 33 (2000) 755.