Publications in 2008

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(508)   “Pseudo-base formation in the attempted synthesis of a conjugatively coupled bis(nitrosylruthenium) complex and spectroelectrochemistry of bipyrimidine-bridged dinuclear Ru(terpy)x precursor compounds (X = Cl, NO2)”
P. Singh, M. Sieger, J. Fiedler, C.-Y. Su und W. Kaim, Dalton Trans. 2008, 868-873.   

(509)   “Ruthenium Complexes with Vinyl, Styryl, and Vinylpyrenyl Ligands: A Case of Non-Innocence in Organometallic Chemistry” J. Maurer, M. Linseis, B. Sarkar, B. Schwederski, M. Niemeyer, W. Kaim, S. Zalis, C. Anson, A.K. Powell, M. Zabel und R.F. Winter, J. Am. Chem. Soc. 130 (2008) 259-268.

(510)   “Structures and Redox Properties of Metal Complexes of the Electron-Deficient Diphosphine Chelate Ligand R,R-QuinoxP” A.K. Das, E. Bulak, B. Sarkar, F. Lissner, Th. Schleid, M. Niemeyer, J. Fiedler und W. Kaim, Organometallics 27 (2008) 218-223.

(511)   “Spectro-Electrochemistry: Two worlds come together” W. Kaim, in Discussion Meet on ElectroAnalytical Techniques and their Applications (DM-ELANTE-2008), Hrsg. S.K. Aggarwal, N. Gopinath, R. Govindan, R.M. Sawant, Indian Society for ElectroAnalytical Chemistry, Mumbai, 2008, S. 35-47, ISBN 978-81-901950-1-0.

(512)   “Singlet Diradical Complexes of Ruthenium and Osmium: Geometrical and Electronic Structures and their Unexpected Changes on Oxidation” S. Samanta, P. Singh, J. Fiedler, S. Zalis, W. Kaim und S. Goswami, Inorg. Chem. 47 (2008) 1625-1633.

(513)   “A series of metal complexes with the non-innocent N,N’-bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure” M. M. Khusniyarov, K. Harms, O. Burghaus, J. Sundermeyer, B. Sarkar, W. Kaim, J. van Slageren, C. Duboc und J. Fiedler, Dalton Trans. 2008, 1355-1365.

(514)   “A radical-bridged bis(ferrocenylcopper(I)) complex: Structural identity, multifrequency EPR, and spectroelectrochemistry” S. Roy, M. Sieger, P. Singh, M. Niemeyer, J. Fiedler, C. Duboc und W. Kaim, Inorg. Chim. Acta 361 (2008) 1699-1704.

(515)   “Mixed-Valent Metals Bridged by a Radical Ligand: Fact, or Fiction Based on Structure-Oxidation State Correlations” B. Sarkar, S. Patra, J. Fiedler, R.B. Sunoj, D. Janardanan, G.K. Lahiri und W. Kaim, J. Am. Chem. Soc. 130 (2008) 3532-3542.

(516)   “Formation, Reactivity and Photorelease of Metal Bound Nitrosyl  in [Ru(trpy)(L11)(NO)]n+ (trpy = 2,2/:6/,2//-Terpyridine, L11 = 2-phenylimidazo[4,5-f]1,10-phenanthroline)”

S. Maji, B. Sarkar, M. Patra, A. Das, S.M. Mobin, W. Kaim und G.K. Lahiri, Inorg. Chem. 47 (2008) 3218-3227.

(517)   “Double cyclometallation of bridging 3,6-bis(2-thienyl)-1,2,4,5-tetrazine in a dinuclear mesityl(dimethylsulfoxide)platinum(II) complex: Structure and properties”

B. Sarkar, T. Schurr, I. Hartenbach, Th. Schleid, J. Fiedler und W. Kaim, J. Organomet. Chem. 693 (2008) 1703-1706.

(518)   “Metal Compounds of the TCNX Redox Systems – From Electron Transfer to Spin Distribution and Magnetism”

W. Kaim, J. Chil. Chem. Soc. 53 (2008) 1342-1344.

(519)   “1,4,7,10-Tetraazacyclododecane Metal Complexes as Potent Promoters of Phosphodiester Hydrolysis under Physiological Conditions”

M. Subat, K. Woinaroschy, C. Gerstl, B. Sarkar, W. Kaim und B. König, Inorg. Chem. 47 (2008) 4661-4668.

(520)   “Valence State Alternatives in Diastereoisomeric Complexes [(acac)2Ru(m-QL)Ru(acac)2]n (QL2- = 1,4-Dioxido-9,10-anthraquinone, n = +2,+1,0,-1,-2)”

S. Maji, B. Sarkar, S.M. Mobin, J. Fiedler, F.A. Urbanos, R. Jimenez-Aparicio, W. Kaim und G.K. Lahiri, Inorg. Chem. 47 (2008) 5204-5211.

(521) “Redox Properties of Ruthenium Nitrosyl Porphyrin Complexes with Different Axial Ligation: Structural, Spectroelectrochemical (IR, UV-VIS, EPR) and Theoretical Studies” P. Singh, A.K. Das, B. Sarkar, M. Niemeyer, F. Roncaroli, J.A. Olabe, J. Fiedler, S. Záliš und W. Kaim, Inorg. Chem. 47 (2008) 7106-7113.

(522)   “Establishing the Chelating a-Azocarbonyl Function in Acceptor Ligands” S. Roy, M. Sieger, B. Sarkar, B. Schwederski, F. Lissner, Th. Schleid, J. Fiedler und W. Kaim, Angew. Chem. 120 (2008) 6287-6289; Angew. Chem. Int. Ed. 47 (2008) 6192-6194.

(523)   “High-frequency EPR and structure data as complementary information on stable radical complexes containing the semi-reduced azo function” B. Sarkar, S. Frantz, S. Roy, M. Sieger, C. Duboc, G. Denninger, H.J. Kümmerer und W. Kaim, J. Mol. Struct. 890 (2008) 133-138.

(524)   “The Shortest Metal-Metal Bond Yet: Molecular and Electronic Structure of a Dinuclear Chromium Diazadiene Complex (Commentary)” W. Kaim, Chem. Tracts 20 (2008) 292-296.

(525)   “Ligand-Centered Oxidations and Electron Delocalisation in a Tetranuclear Complex of a Tetradonor-Substituted Olefin” M. Linseis, R.F. Winter, B. Sarkar, W. Kaim und S. Zalis, Organometallics 27 (2008) 3321-3324.

(526)   “Mixed-Valence Intermediates as Ideal Targets for Spectroelectrochemistry (SEC)” W. Kaim, B. Sarkar und G.K. Lahiri in Spectroelectrochemistry, Hrsg. W. Kaim und A. Klein, Royal Society of Chemistry (Cambridge), 2008, S. 68-90, ISBN 9780854045501.

(527)    “Dimerization of the 2-(Methylselenomethyl)benzimidazole-silver(I) Cation Involving a AgI--AgI Interaction” M. Leboschka, M. Sieger, M. Niemeyer, S. Záliš und W. Kaim, Z. Anorg. Allg. Chem. 634 (2008) 2343-2346.

(528)   “Stabilizing the Elusive ortho-Quinone/Copper(I) Oxidation State Combination through p/p Interaction in an Isolated Complex” S. Roy, B. Sarkar, D. Bubrin, M. Niemeyer, S. Zališ, G.K. Lahiri und W. Kaim, J. Am. Chem. Soc. 130 (2008) 15230-15231.

(529)   “A tetranuclear organorhenium(I) complex of the 2,3,5,6-tetrafluoro-7,7,8,8-tetracyano-p-quinodimethane radical anion, TCNQF4·-” A.N. Maity, B. Sarkar, M. Niemeyer, M. Sieger, C. Duboc, S. Zalis und W. Kaim, Dalton Trans 2008, 5749-5753.

(530)   “Structural and Spectroscopic Evidence for Marginal Metal-to-Ligand Charge Transfer in Complexes Pt(abpy)Me3X, abpy = 2,2’-Azobispyridine, X = Cl,Br,I” A. Dogan, C. Kavakli, M. Sieger, M. Niemeyer, B. Sarkar und W. Kaim, Z. Allg. Anorg. Chem. 634 (2008) 2527-2531.

(531)   “Valence State Analysis via Spectroelectrochemistry in Differently Quinonoid Bridged Diruthenium Complexes [(acac)2Ru(m-L)Ru(acac)2]n+ (n = +2, +1, 0, -1, -2)”  S. Ghumaan, B. Sarkar, S. Maji, V.G. Puranik, J. Fiedler, F.A. Urbanos, R. Jimenez-Aparicio, W. Kaim und G.K. Lahiri, Chem. Eur. J. 14 (2008) 10816-10828.

(532)    “Intramolecular Valence and Spin Interaction in meso and rac Diastereomers of a p-Quinonoid Bridged Diruthenium Complex” D. Kumbhakar, B. Sarkar, S.M. Mobin, J. Fiedler, F.A. Urbanos, R. Jimenez-Aparicio, W. Kaim und G.K. Lahiri, J. Am. Chem. Soc. 130 (2008) 17575-17583.

(533)   “all-trans-[ClRuII(py)4(NC)RuII(py)4(CN)RuII(py)4(NO)](PF6)4 a redox active s-donor/p-acceptor system based on the electrophilic {RuNO}6 motif” A.G. De Candia, P. Singh, W. Kaim und L.D. Slep, Inorg. Chem. 48 (2009) 565-573.

(534)   “Structure, electrochemistry, spectroscopy, and magnetic resonance, including high-field EPR, of {(m-abpy)[Re(CO)3X]2}0,·- where abpy = 2,2’-azobispyridine and X = F, Cl, Br, I” S. Frantz, M. Sieger, I. Hartenbach, F. Lissner, Th. Schleid, J. Fiedler, C. Duboc, und W. Kaim, J. Organomet. Chem. 694 (2009) 1122-1133.