Publications in 2009

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(533)   “all-trans-[ClRuII(py)4(NC)RuII(py)4(CN)RuII(py)4(NO)](PF6)4 a redox active 2-donor/1-acceptor system based on the electrophilic {RuNO}6 motif”, A.G. De Candia, P. Singh, W. Kaim und L.D. Slep, Inorg. Chem. 48 (2009) 565-573.

(534)   “Structure, electrochemistry, spectroscopy, and magnetic resonance, including high-field EPR, of {(m<-abpy)[Re(CO)3X]2}0,·- where abpy = 2,2’-azobispyridine and X = F, Cl, Br, I”, S. Frantz, M. Sieger, I. Hartenbach, F. Lissner, Th. Schleid, J. Fiedler, C. Duboc, und W. Kaim, J. Organomet. Chem. 694 (2009) 1122-1133.  

(535)   “Nano and Dendritic Structured Carboranes and Metallacarboranes: From Materials to Cancer Therapy”, N.S. Hosmane, Y. Zhu, J.A. Maguire, M. Takagaki und W. Kaim, J. Organomet. Chem. 694 (2009) 1690-1697.

(536)   “Silver(I), Copper(I) and Copper(II) Complexes of the New N,Se-Chelate Ligand 2-Phenylselenomethyl-1H-benzimidazole: Electrochemistry and Structure”, M. Leboschka, M. Sieger, B. Sarkar, M. Niemeyer, T. Schurr, J. Fiedler, S. Záliš und W. Kaim, Z. Anorg. Allg. Chem. 635 (2009) 1001-1009.

(537)   “An Odd-Electron Complex [Ruk(NOm)(Qn)(terpy)]2+ with Two Prototypical Non-Innocent Ligands”, A. Das, B. Sarkar, C. Duboc, S. Strobel, J. Fiedler, S. Záliš, G.K. Lahiri und W. Kaim, Inorg. Chem. 121 (2009) 4306-4309; Angew. Chem. Int. Ed. 48 (2009) 4242-4245.

(538)   “Boron Atoms as Spin Carriers in Two- and Three-Dimensional Systems”, W. Kaim,  N.S. Hosmane,  S. Záliš, J.A. Maguiere und W.N. Lipscomb, Angew. Chem. 121 (2009) 5184-5193; Angew. Chem. Int Ed. 48 (2009) 5082-5091.

(539)    “Stabilization of {RuNO}6 and {RuNO}7 States in [RuII(trpy)(bik)(NO)]n+ (trpy = 2,2/:6/,2//-Terpyridine, bik = 2,2/-Bis(1-methylimidazolyl)ketone). Synthesis, Reactivity and Photorelease of Metal Bound Nitrosyl”, P. De, B. Sarkar, S. Maji, A.K. Das, E. Bulak, S.M. Mobin, W. Kaim und G.K. Lahiri, Eur. J. Inorg. Chem. 2009, 2702-2710.

(540)    “Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4- Association in the Solid and Stepwise Oxidation (3 e) or Reduction (2 e) to Spectroelectrochemically Characterized Species”, S. Roy, B. Sarkar, C. Duboc, J. Fiedler, O. Sarper, F. Lissner, S.M. Mobin, G.K. Lahiri und W. Kaim, Chem. Eur. J., im Druck.

(541)   “A Five-­Center Redox System: Molecular Coupling of Two Non-Innocent Imino-o-benzoquinonato-Ruthenium Functions through a p Acceptor Bridge”, A.K. Das, B. Sarkar, J. Fiedler, S. Záliš, I. Hartenbach, S. Strobel, G.K. Lahiri und W. Kaim, J. Am. Chem. Soc. 131 (2009) 8895-98902.

(542)   “Evidence for the Dimer-of-(Mixed-Valent Dimers) Model for the Complex Ions {(m4-TCNX)[Ru(NH3)5]4}8+, TCNX = TCNE and TCNQ, from DFT Calculations”, S. Záliš, W. Kaim, B. Sarkar und C. Duboc, Chem. Monthly 140 (2009) 765-773.

(543)   “Effect of Metal Exchange (Os vs Ru) and Co-Ligand Variation (Cl- vs acac-) on the Oxidation State Distribution in Complexes of an o-Phenylenediamido(2-)/o-Quinonediimine Redox System”, S. Chatterjee, P. Singh, J. Fiedler, S. Zališ, W. Kaim und S. Goswami, Dalton Trans., im Druck.

(544)    “Spectroelectrochemistry: The best of two worlds”, W. Kaim und J. Fiedler, Chem. Soc. Rev., im Druck.

(545)   “Charge Delocalization in a Heterobimetallic Ferrocene-(Vinyl)Ru(CO)Cl(PiPr3)2 System”, K. Kowalski, M. Linseis, R.F. Winter, M. Zabel, S. Záliš, H. Kelm, H.-J. Krüger, B. Sarkar und W. Kaim, Organometallics, im Druck.

(546)   “2-Organoselenomethyl-1H-benzimidazole Complexes of Copper(II) and Copper(I)”
M. Leboschka, M. Sieger, B. Sarkar, J. Heck, M. Niemeyer, F. Lissner, Th. Schleid, S. Záliš, J. Fiedler und W. Kaim, Z. Anorg. Allg. Chem., eingereicht.

(547)   “Mixed-valency with cyanide as terminal ligands: Diruthenium(III,II) complexes with the 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine bridge and variable co-ligands (CN- vs bpy or NH3)”
M.M. Vergara, M.E. García Posse, F. Fagalde, N.E. Katz, J. Fiedler, B. Sarkar, M. Sieger und W. Kaim, Inorg. Chim. Acta, eingereicht.

(548)   “Multidimensional Potential of Boron-Containing Molecules in Functional Materials”
W. Kaim und N.S. Hosmane, J. Chem. Sci., im Druck.

(549)   “Ambivalence Taken Literally: Ru vs. Fe Oxidation in 1,1'-Diphosphinoferroceneruthenium(II) Complexes – Structures, Spectroelectrochemistry, and EPR of the Heterodimetallic Mixed-Valent Intermediates”
T. Sixt, M. Sieger, J. Fiedler und W. Kaim, Organometallics, in Vorbereitung.