Dieses Bild zeigt Wolfgang Kaim

Wolfgang Kaim

Herr Prof. Dr. phil. nat.

Institut für Anorganische Chemie
Lehrstuhl für Anorganische Koordinationschemie

Kontakt

+49 711 685 64170
+49 711 685 64165

Pfaffenwaldring 55
70569 Stuttgart
Deutschland
Raum: 3.101

Fachgebiet

Koordinationschemie von ungesättigten Liganden mit organischen, organometallischen und anorganischen Elektrophilen (Hauptgruppen- und Nebengruppenelemente); Gemischte Valenz; Komplexe mit "nicht-unschuldigen" Liganden; organische Radikale; Elektron- und Spintransfer Prozesse; Metallkomplexierung von Chinonoid-Cofaktoren 


Methoden: UV/Vis/NIR/IR und ESR Spektroskopie; (Spektro-)elektrochemie

  1. 2020

    1. Kaim, Wolfgang. (2020). Sites of Electron Transfer Reactivity in Organometallic Compounds. European Journal of Inorganic Chemistry, 2020(11–12), Article 11–12. https://doi.org/10.1002/ejic.202000107
    2. Ansari, Mohd. A., Mondal, S., Kaim, W., & Lahiri, G. Kumar. (2020). Fused N-Heterocyclic-Bridged Isomeric Diruthenium Complexes (acac)2Ru(m-DIPQD)Ru(acac)2n, n = +2, + 1, 0, -1, -2. Inorganic Chemistry, 59(7), Article 7. https://doi.org/10.1021/acs.inorgchem.9b03543
    3. Bauer, S., Zalis, S., Fiedler, J., Ringenberg, M. R., & Kaim, Wolfgang. (2020). Oxidation State Assignments in the Organoplatinum One-Electron Redox Series (NN̂)PtMes2n, n = +,0, -,2-. European Journal of Inorganic Chemistry, 2020(25), Article 25. https://doi.org/10.1002/ejic.202000257
    4. Sondermann, C., Pizl, M., Paretzki, A., Feil, C., Ringenberg, M. R., Zalis, S., & Kaim, Wolfgang. (2020). Analysis of a Diimine-Organonickel Redox Series. European Journal of Inorganic Chemistry, Ahead of Print. https://doi.org/10.1002/ejic.202000455
    5. Bera, S. K., Mondal, S., Hazari, A. S., Priego, J. L., Jimenez-Aparicio, R., Kaim, W., & Lahiri, G. Kumar. (2020). Three Bis-BODIPY Analogous Diruthenium Redox Series: Characterization and Electronic Structure Analysis. Chemistry - An Asian Journal, 15(16), Article 16. https://doi.org/10.1002/asia.202000326
    6. Kaim, W., Das, A., Fiedler, J., Zalis, S., & Sarkar, Biprajit. (2020). NO and NO2 as non-innocent ligands: A comparison. Coordination Chemistry Reviews, 404, 213114. https://doi.org/10.1016/j.ccr.2019.213114
  2. 2019

    1. Sinhababu, S., Kundu, S., Siddiqui, M. M., Paesch, A. N., Herbst-Irmer, R., Schwederski, B., Saha, P., Zhao, L., Frenking, G., Kaim, W., Stalke, D., & Roesky, H. W. (2019). Synthesis of cAAC stabilized biradical of \textquotedblMe2Si\textquotedbl and \textquotedblMe2SiCl\textquotedbl monoradical from Me2SiCl2 - an important feedstock material. Chemical Communications (Cambridge, United Kingdom), 55(31), Article 31. https://doi.org/10.1039/c9cc01448a
    2. Mondal, S., Filippou, V., Bubrin, M., Schwederski, B., Fiedler, J., & Kaim, Wolfgang. (2019). Metalloradical Compounds with 1,2-Dipivaloylhydrazido Ligands: Electron Transfer and Alkylation/Protonation Effects. European Journal of Inorganic Chemistry, 2019(21), Article 21. https://doi.org/10.1002/ejic.201900391
    3. Kaim, W., & Lahiri, G. Kumar. (2019). The coordination potential of indigo, anthraquinone and related redox-active dyes. Coordination Chemistry Reviews, 393, 1--8. https://doi.org/10.1016/j.ccr.2019.05.002
    4. Kaim, Wolfgang. (2019). Chelate rings of different sizes with non-innocent ligands. Dalton Transactions, 48(24), Article 24. https://doi.org/10.1039/c9dt01411j
    5. Sarkar, S. K., Siddiqui, M. M., Kundu, S., Ghosh, M., Kretsch, J., Stollberg, P., Herbst-Irmer, R., Stalke, D., Stueckl, A. C., Schwederski, B., Kaim, W., Ghorai, S., Jemmis, E. D., & Roesky, H. W. (2019). Isolation of base stabilized fluoroborylene and its radical cation. Dalton Transactions, 48(24), Article 24. https://doi.org/10.1039/c9dt01899a
    6. Li, W., Kundu, S., Kohler, C., Li, J., Dutta, S., Yang, Z., Stalke, D., Herbst-Irmer, R., Stuckl, A. C., Schwederski, B., Koley, D., Kaim, W., & Roesky, H. W. (2019). Cyclic Alkyl(amino) Carbene-Stabilized Monoradicals of Organosilicon(IV) Compounds with Small Substituents. Organometallics, 38(9), Article 9. https://doi.org/10.1021/acs.organomet.9b00041
    7. Siddiqui, M. M., Sarkar, S. K., Sinhababu, S., Ruth, P. N., Herbst-Irmer, R., Stalke, D., Ghosh, M., Fu, M., Zhao, L., Casanova, D., Frenking, G., Schwederski, B., Kaim, W., & Roesky, H. W. (2019). Isolation of Transient Acyclic Germanium(I) Radicals Stabilized by Cyclic Alkyl(amino) Carbenes. Journal of the American Chemical Society, 141(5), Article 5. https://doi.org/10.1021/jacs.8b13434
    8. Kaim, Wolfgang. (2019). Materials with electronic transitions in the near-infrared. Journal of Chemical Sciences (Berlin, Germany), 131(9), Article 9. https://doi.org/10.1007/s12039-019-1664-z
  3. 2018

    1. Kaim, W., Beyer, K., Filippou, V., & Zalis, Stanislav. (2018). Charge and spin coupling in copper compounds with hemilabile noninnocent ligands - Ambivalence in three dimensions. Coordination Chemistry Reviews, 355, 173--179. https://doi.org/10.1016/j.ccr.2017.08.006
    2. Mondal, S., Schwederski, B., Frey, W., Fiedler, J., Zalis, S., & Kaim, Wolfgang. (2018). At the Borderline between Metal-Metal Mixed Valency and a Radical Bridge Situation: Four Charge States of a Diruthenium Complex with a Redox-Active Bis(mer-tridentate) Ligand. Inorganic Chemistry, 57(7), Article 7. https://doi.org/10.1021/acs.inorgchem.8b00173
    3. Chatterjee, M., Mondal, S., Ghosh, P., Kaim, W., & Lahiri, G. Kumar. (2018). Mononuclear and Dinuclear Ruthenium Complexes of cis- and trans-Thioindigo: Geometrical and Electronic Structure Analyses. Inorganic Chemistry, 57(19), Article 19. https://doi.org/10.1021/acs.inorgchem.8b01829
    4. Sinhababu, S., Kundu, S., Paesch, A. N., Herbst-Irmer, R., Stalke, D., Fernandez, I., Frenking, G., Stueckl, A. C., Schwederski, B., Kaim, W., & Roesky, H. W. (2018). A Route to Base Coordinate Silicon Difluoride and the Silicon Trifluoride Radical. Chemistry - A European Journal, 24(6), Article 6. https://doi.org/10.1002/chem.201705773
    5. Hazari, A. S., Ghosh, P., Beyer, K., Schwederski, B., Kaim, W., & Lahiri, G. Kumar. (2018). Effect of positional isomerism on the spectroelectrochemical response of 3,6-bis(2-pyridyl)-diketopyrrolopyrrolate bridged bis(carbonylhydridoruthenium) compounds. Dalton Transactions, 47(39), Article 39. https://doi.org/10.1039/c8dt02806k
    6. Bubrin, M., Kvapilova, H., Fiedler, J., Ehret, F., Zalis, S., & Kaim, Wolfgang. (2018). Hybrid a-Diimine/Bis(chalcogenoether) Ligands for Copper(I) and Copper(II) Complexes. Zeitschrift fuer Anorganische und Allgemeine Chemie, 644(14), Article 14. https://doi.org/10.1002/zaac.201800073
    7. Chatterjee, M., Ghosh, P., Beyer, K., Paretzki, A., Fiedler, J., Kaim, W., & Lahiri, G. Kumar. (2018). Isomeric Diruthenium Complexes Bridged by Deprotonated Indigo in cis and trans Configuration. Chemistry - An Asian Journal, 13(1), Article 1. https://doi.org/10.1002/asia.201701562
    8. Ansari, Mohd. A., Beyer, K., Schwederski, B., Kaim, W., & Lahiri, G. Kumar. (2018). Diruthenium Complexes of p-Benzoquinone-Imidazole Hybrid Ligands: Innocent or Noninnocent Behavior of the Quinone Moiety. Chemistry - An Asian Journal, 13(19), Article 19. https://doi.org/10.1002/asia.201801101
  4. 2017

    1. Arslan Bicer, F., Yildirim, S., Kaim, W., & Bubrin, Martina. (2017). New saccharinate complexes with 3,3’-azobispyridine ligand: Synthesis, characterization, and spectroscopic properties. Journal of Coordination Chemistry, 70(16), Article 16. https://doi.org/10.1080/00958972.2017.1360489
    2. Bubrin, M., Paretzki, A., Huebner, R., Beyer, K., Schwederski, B., Neugebauer, P., Zalis, S., & Kaim, Wolfgang. (2017). Probing the Intramolecular Metal-Selenoether Interaction in a Bis(iminosemiquinone)copper(II) Compound. Zeitschrift fuer Anorganische und Allgemeine Chemie, 643(21), Article 21. https://doi.org/10.1002/zaac.201700282
    3. Romero, R., Contreras, D., Segura, C., Schwederski, B., & Kaim, Wolfgang. (2017). Hydroxyl radical production by a heterogeneous Fenton reaction supported in insoluble tannin from bark of Pinus radiata. Environmental Science and Pollution Research, 24(7), Article 7. https://doi.org/10.1007/s11356-016-7532-1
    4. Kamatchi, T. S., Mondal, S., Scherer, T., Bubrin, M., Natarajan, K., & Kaim, Wolfgang. (2017). Near-Infrared-Absorbing Organometallic Diruthenium Complex Intermediates: Evidence for Bridging Anthrasemiquinone Formation and against Mixed Valency. Chemistry - A European Journal, 23(70), Article 70. https://doi.org/10.1002/chem.201703888
    5. Loew, I., Bubrin, M., Paretzki, A., Fiedler, J., Zalis, S., & Kaim, Wolfgang. (2017). The BIAN ligand 1,2-bis(2,6-diisopropylphenyl)iminoacenaphthene: An electron sponge or a \dqnormal\dq a-diimine ligand? Inorganica Chimica Acta, 455(Part\_2), Article Part\_2. https://doi.org/10.1016/j.ica.2016.05.054
    6. Ringenberg, M. R., Wittkamp, F., Apfel, U.-P., & Kaim, Wolfgang. (2017). Redox Induced Configurational Isomerization of Bisphosphine-Tricarbonyliron(I) Complexes and the Difference a Ferrocene Makes. Inorganic Chemistry, 56(13), Article 13. https://doi.org/10.1021/acs.inorgchem.7b00957
    7. Chatterjee, M., Mondal, P., Beyer, K., Paretzki, A., Kaim, W., & Lahiri, G. Kumar. (2017). A structurally characterised redox pair involving an indigo radical: Indigo based redox activity in complexes with one or two Ru(bpy)2 fragments. Dalton Transactions, 46(15), Article 15. https://doi.org/10.1039/C7DT00055C
    8. Ringenberg, M. R., Schwilk, M., Wittkamp, F., Apfel, U.-P., & Kaim, Wolfgang. (2017). Organometallic Fe-Fe Interactions: Beyond Common Metal-Metal Bonds and Inverse Mixed-Valent Charge Transfer. Chemistry - A European Journal, 23(8), Article 8. https://doi.org/10.1002/chem.201605527
    9. Plebst, S., Bubrin, M., Schweinfurth, D., Zalis, S., & Kaim, Wolfgang. (2017). Metal carbonyl complexes of potentially ambidentate 2,1,3-benzothiadiazole and 2,1,3-benzoselenadiazole acceptors. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 72(11), Article 11. https://doi.org/10.1515/znb-2017-0100
    10. Kundu, S., Sinhababu, S., Dutta, S., Mondal, T., Koley, D., Dittrich, B., Schwederski, B., Kaim, W., Stueckl, A. C., & Roesky, H. W. (2017). Synthesis and characterization of Lewis base stabilized mono- and di-organo aluminum radicals. Chemical Communications (Cambridge, United Kingdom), 53(76), Article 76. https://doi.org/10.1039/C7CC06358J
    11. Krafft, M. J., Lissner, F., Fiedler, J., & Kaim, Wolfgang. (2017). Cobalt Carbonyl Hydrides with 1,1’-Diphosphinylferrocene Ligands - Structural and Electrochemical Diversity. Zeitschrift fuer Anorganische und Allgemeine Chemie, 643(23), Article 23. https://doi.org/10.1002/zaac.201700312
    12. Singha Hazari, A., Mandal, A., Beyer, K., Paretzki, A., Kaim, W., & Lahiri, G. Kumar. (2017). Metal-Metal Bridging Using the DPPP Dye System: Electronic Configurations within Multiple Redox Series. Inorganic Chemistry, 56(5), Article 5. https://doi.org/10.1021/acs.inorgchem.6b03112
    13. Ansari, Mohd. A., Mandal, A., Beyer, K., Paretzki, A., Schwederski, B., Kaim, W., & Lahiri, G. Kumar. (2017). Non-innocence and mixed valency in tri- and tetranuclear ruthenium complexes of a heteroquinone bridging ligand. Dalton Transactions, 46(44), Article 44. https://doi.org/10.1039/C7DT03509H
    14. Kundu, S., Samuel, P. P., Sinhababu, S., Luebben, A. V., Dittrich, B., Andrada, D. M., Frenking, G., Stueckl, A. C., Schwederski, B., Paretzki, A., Kaim, W., & Roesky, H. W. (2017). Organosilicon Radicals with Si-H and Si-Me Bonds from Commodity Precursors. Journal of the American Chemical Society, 139(32), Article 32. https://doi.org/10.1021/jacs.7b06610
    15. Li, B., Kundu, S., Stueckl, A. C., Zhu, H., Keil, H., Herbst-Irmer, R., Stalke, D., Schwederski, B., Kaim, W., Andrada, D. M., Frenking, G., & Roesky, H. W. (2017). A Stable Neutral Radical in the Coordination Sphere of Aluminum. Angewandte Chemie, International Edition, 56(1), Article 1. https://doi.org/10.1002/anie.201609101
    16. Kaim, W., & Paretzki, Alexa. (2017). Interacting metal and ligand based open shell systems: Challenges for experiment and theory. Coordination Chemistry Reviews, 344, 345--354. https://doi.org/10.1016/j.ccr.2016.12.008
  5. 2016

    1. Ansari, Mohd. A., Mandal, A., Paretzki, A., Beyer, K., Fiedler, J., Kaim, W., & Lahiri, G. Kumar. (2016). 1,5-Diamido-9,10-anthraquinone, a Centrosymmetric Redox-Active Bridge with Two Coupled b-Ketiminato Chelate Functions: Symmetric and Asymmetric Diruthenium Complexes. Inorganic Chemistry, 55(11), Article 11. https://doi.org/10.1021/acs.inorgchem.6b00726
    2. Kluwer, A. M., Krafft, M. J., Hartenbach, I., de Bruin, B., & Kaim, Wolfgang. (2016). Hydroformylation of 1-Octene Mediated by the Cobalt Complex CoH(dchpf)(CO)2. Topics in Catalysis, 59(19–20), Article 19–20. https://doi.org/10.1007/s11244-016-0699-3
    3. Hazari, A. S., Paretzki, A., Fiedler, J., Zalis, S., Kaim, W., & Lahiri, G. Kumar. (2016). Different manifestations of enhanced p-acceptor ligation at every redox level of Os(9-OP)L2n, n = 2+, +, 0, - (9-OP- = 9-oxidophenalenone and L = bpy or pap). Dalton Transactions, 45(45), Article 45. https://doi.org/10.1039/C6DT03764J
    4. Mandal, A., Hoque, M. A., Grupp, A., Paretzki, A., Kaim, W., & Lahiri, G. Kumar. (2016). Analysis of Redox Series of Unsymmetrical 1,4-Diamido-9,10-anthraquinone-Bridged Diruthenium Compounds. Inorganic Chemistry, 55(5), Article 5. https://doi.org/10.1021/acs.inorgchem.5b02541
    5. Mondal, P., Chatterjee, M., Paretzki, A., Beyer, K., Kaim, W., & Lahiri, G. Kumar. (2016). Noninnocence of Indigo: Dehydroindigo Anions as Bridging Electron-Donor Ligands in Diruthenium Complexes. Inorganic Chemistry, 55(6), Article 6. https://doi.org/10.1021/acs.inorgchem.6b00038
    6. Kaim, Wolfgang. (2016). Electron Transfer Reactivity of Organometallic Compounds Involving Radical-Forming Noninnocent Ligands. Proceedings of the National Academy of Sciences, India, Section A: Physical Sciences, 86(4), Article 4. https://doi.org/10.1007/s40010-016-0304-y
    7. Melin, V., Henriquez, A., Radojkovic, C., Schwederski, B., Kaim, W., Freer, J., & Contreras, David. (2016). Reduction reactivity of catecholamines and their ability to promote a Fenton reaction. Inorganica Chimica Acta, 453, 1--7. https://doi.org/10.1016/j.ica.2016.07.044
    8. Ansari, Mohd. A., Mandal, A., Paretzki, A., Beyer, K., Kaim, W., & Lahiri, G. Kumar. (2016). Isomeric Diruthenium Complexes of a Heterocyclic and Quinonoid Bridging Ligand: Valence and Spin Alternatives for the Metal/Ligand/Metal Arrangement. Inorganic Chemistry, 55(23), Article 23. https://doi.org/10.1021/acs.inorgchem.6b02245
    9. Paluru, D. K., Dey, S., Wadawale, A. P., Bhuvanesh, N., Grupp, A., Kaim, W., & Jain, V. K. (2016). Coordination Polymers of Palladium Bridged by Carboxylate and Dimethylaminoalkylselenolate Ligands. Chemistry - An Asian Journal, 11(3), Article 3. https://doi.org/10.1002/asia.201501087
  6. 2015

    1. Jana, R., Lissner, F., & Kaim, Wolfgang. (2015). Coordinative Saturation of the Pterin Heterocycle by Ferrocenylcopper(I) Complex Fragments. Zeitschrift fuer Anorganische und Allgemeine Chemie, 641(2), Article 2. https://doi.org/10.1002/zaac.201400529
    2. Samuel, P. P., Neufeld, R., Chandra Mondal, K., Roesky, H. W., Herbst-Irmer, R., Stalke, D., Demeshko, S., Meyer, F., Rojisha, V. C., De, S., Parameswaran, P., Stueckl, A. C., Kaim, W., Christian, J. H., Bindra, J. K., & Dalal, N. S. (2015). Cr(I)Cl as well as Cr+ are stabilised between two cyclic alkyl amino carbenes. Chemical Science, 6(5), Article 5. https://doi.org/10.1039/C5SC00646E
    3. Mandal, A., Schwederski, B., Fiedler, J., Kaim, W., & Lahiri, G. Kumar. (2015). Evidence for Bidirectional Noninnocent Behavior of a Formazanate Ligand in Ruthenium Complexes. Inorganic Chemistry, 54(16), Article 16. https://doi.org/10.1021/acs.inorgchem.5b01408
    4. Ehret, F., Bubrin, M., Zalis, S., & Kaim, Wolfgang. (2015). Metal-Chelating N,N’-Bis(4-dimethylaminophenyl)acetamidinyl Radical: A New Chromophore for the Near-Infrared Region. Chemistry - A European Journal, 21(35), Article 35. https://doi.org/10.1002/chem.201501875
    5. Ehret, F., Bubrin, M., Zalis, S., Priego, J. L., Jimenez-Aparicio, R., & Kaim, Wolfgang. (2015). Metal-Induced Thiophene Ring Opening and C-C Bond Formation To Produce Unique Hexa-1,3,5-trienediyl-Coupled Non-Innocent Ligand Chelates. Chemistry - A European Journal, 21(43), Article 43. https://doi.org/10.1002/chem.201502748
    6. Mandal, A., Grupp, A., Schwederski, B., Kaim, W., & Lahiri, G. Kumar. (2015). Varying Electronic Structures of Diosmium Complexes from Noninnocently Behaving Anthraquinone-Derived Bis-chelate Ligands. Inorganic Chemistry, 54(16), Article 16. https://doi.org/10.1021/acs.inorgchem.5b01017
    7. Roy, S., Dittrich, B., Mondal, T., Koley, D., Stueckl, A. C., Schwederski, B., Kaim, W., John, M., Vasa, S. K., Linser, R., & Roesky, H. W. (2015). Carbene Supported Dimer of Heavier Ketenimine Analogue with P and Si Atoms. Journal of the American Chemical Society, 137(19), Article 19. https://doi.org/10.1021/jacs.5b03407
    8. Grupp, A., Fiedler, J., & Kaim, Wolfgang. (2015). UV-Vis-NIR spectroelectrochemical study of tetrathiorhenate-bridged diruthenium complexes. Polyhedron, 86, 71--75. https://doi.org/10.1016/j.poly.2014.05.016
    9. Das, A., Ghosh, P., Plebst, S., Schwederski, B., Mobin, S. M., Kaim, W., & Lahiri, G. Kumar. (2015). Ancillary Ligand Control of Electronic Structure in o-Benzoquinonediimine-Ruthenium Complex Redox Series: Structures, Electron Paramagnetic Resonance (EPR), and Ultraviolet-Visible-Near-Infrared (UV-vis-NIR) Spectroelectrochemistry. Inorganic Chemistry, 54(7), Article 7. https://doi.org/10.1021/ic503070j
    10. Jana, R., Blickle, S., Lissner, F., Hartenbach, I., Bubrin, M., Schwederski, B., & Kaim, Wolfgang. (2015). Organometal coordination by purines: Semi-chelate bonding of modified guanine and isocaffeine with bis(diorganylphosphino)ferrocene-copper. Journal of Organometallic Chemistry, 782, 62--68. https://doi.org/10.1016/j.jorganchem.2014.10.043
    11. Choudhuri, M. M. R., Behzad, M., Al-Noaimi, M., Yap, G. P. A., Kaim, W., Sarkar, B., & Crutchley, R. J. (2015). Variable Noninnocence of Substituted Azobis(phenylcyanamido)diruthenium Complexes. Inorganic Chemistry, 54(4), Article 4. https://doi.org/10.1021/ic502487x
    12. Mandal, A., Grupp, A., Schwederski, B., Kaim, W., & Lahiri, G. Kumar. (2015). Noninnocently Behaving Bridging Anions of the Widely Distributed Antioxidant Ellagic Acid in Diruthenium Complexes. Inorganic Chemistry, 54(20), Article 20. https://doi.org/10.1021/acs.inorgchem.5b01868
    13. Paretzki, A., Huebner, R., Ye, S., Bubrin, M., Kaemper, S., & Kaim, Wolfgang. (2015). Electronic, charge and magnetic interactions in three-centre systems. Journal of Materials Chemistry C: Materials for Optical and Electronic Devices, 3(18), Article 18. https://doi.org/10.1039/C5TC00658A
    14. Kaim, Wolfgang. (2015). Complete and partial electron transfer involving coordinated NOx. Advances in Inorganic Chemistry, 67, 295--313. https://doi.org/10.1016/bs.adioch.2014.10.007
    15. Bach, M., Roy, S., Sarkar, B., Bubrin, M., Niemeyer, M., Fiedler, J., Duboc, C., & Kaim, Wolfgang. (2015). Heterotetranuclear Complexes of Reduced and Non-reduced Bridging 1,2,4,5-Tetrazine Ligands with 1,1’-Bis(diphenylphosphanyl)-ferrocene-copper(I). Zeitschrift fuer Anorganische und Allgemeine Chemie, 641(2), Article 2. https://doi.org/10.1002/zaac.201400564
    16. Roy, S., Stueckl, A. C., Demeshko, S., Dittrich, B., Meyer, J., Maity, B., Koley, D., Schwederski, B., Kaim, W., & Roesky, H. W. (2015). Stable Radicals from Commonly Used Precursors Trichlorosilane and Diphenylchlorophosphine. Journal of the American Chemical Society, 137(14), Article 14. https://doi.org/10.1021/jacs.5b02403
  7. 2014

    1. Mondal, K. C., Roy, S., De, S., Parameswaran, P., Dittrich, B., Ehret, F., Kaim, W., & Roesky, H. W. (2014). Stabilization of a Two-Coordinate Mononuclear Cobalt(0) Compound. Chemistry - A European Journal, 20(37), Article 37. https://doi.org/10.1002/chem.201403525
    2. Grupp, A., Bubrin, M., Ehret, F., Zeng, Q., Hartl, F., Kvapilova, H., Zalis, S., & Kaim, Wolfgang. (2014). RuII(a-diimine) or RuIII(a-diimine·-)? Structural, Spectroscopic, and Theoretical Evidence for the Stabilization of a Prominent Metal-to-Ligand Charge-Transfer Excited-State Configuration in the Ground State. European Journal of Inorganic Chemistry, 2014(1), Article 1. https://doi.org/10.1002/ejic.201301206
    3. Jana, R., Sarkar, B., Strobel, S., Mobin, S. M., Kaim, W., & Fiedler, Jan. (2014). Electrochemical Evidence for Hemilabile Coordination of 1,3-Dimethyllumazine to 1,1’-Bis(diorganophosphino)ferrocenecopper(I). Organometallics, 33(18), Article 18. https://doi.org/10.1021/om500039a
    4. Bubrin, M., Schweinfurth, D., Ehret, F., Zalis, S., Kvapilova, H., Fiedler, J., Zeng, Q., Hartl, F., & Kaim, Wolfgang. (2014). Structure and Spectroelectrochemical Response of Arene-Ruthenium and Arene-Osmium Complexes with Potentially Hemilabile Noninnocent Ligands. Organometallics, 33(18), Article 18. https://doi.org/10.1021/om5002815
    5. Agarwala, H., Scherer, T. M., Mobin, S. M., Kaim, W., & Lahiri, G. Kumar. (2014). Bidirectional non-innocence of the b-diketonato ligand 9-oxidophenalenone (L-) in Ru(9aneS3)(L)(dmso)n, 9aneS3 = 1,4,7-trithiacyclononane. Dalton Transactions, 43(10), Article 10. https://doi.org/10.1039/c3dt53069h
    6. Mondal, P., Agarwala, H., Jana, R. D., Plebst, S., Grupp, A., Ehret, F., Mobin, S. M., Kaim, W., & Lahiri, G. Kumar. (2014). Sensitivity of a Strained C-C Single Bond to Charge Transfer: Redox Activity in Mononuclear and Dinuclear Ruthenium Complexes of Bis(arylimino)acenaphthene (BIAN) Ligands. Inorganic Chemistry, 53(14), Article 14. https://doi.org/10.1021/ic500730m
    7. Mondal, K. C., Samuel, P. P., Roesky, H. W., Carl, E., Herbst-Irmer, R., Stalke, D., Schwederski, B., Kaim, W., Ungur, L., Chibotaru, L. F., Hermann, M., & Frenking, Gernot. (2014). Stabilization of a Cobalt-Cobalt Bond by Two Cyclic Alkyl Amino Carbenes. Journal of the American Chemical Society, 136(5), Article 5. https://doi.org/10.1021/ja4123285
    8. Mondal, P., Plebst, S., Ray, R., Mobin, S. M., Kaim, W., & Lahiri, G. Kumar. (2014). Uncommon cis Configuration of a Metal-Metal Bridging Noninnocent Nindigo Ligand. Inorganic Chemistry, 53(17), Article 17. https://doi.org/10.1021/ic501460d
    9. Mondal, K. C., Samuel, P. P., Roesky, H. W., Niepoetter, B., Herbst-Irmer, R., Stalke, D., Ehret, F., Kaim, W., Maity, B., & Koley, Debasis. (2014). Synthesis and Characterization of a Triphenyl-Substituted Radical and an Unprecedented Formation of a Carbene-Functionalized Quinodimethane. Chemistry - A European Journal, 20(30), Article 30. https://doi.org/10.1002/chem.201400393
    10. Weinberger, D. S., Amin SK, N., Mondal, K. C., Melaimi, M., Bertrand, G., Stuckl, A. C., Roesky, H. W., Dittrich, B., Demeshko, S., Schwederski, B., Kaim, W., Jerabek, P., & Frenking, Gernot. (2014). Isolation of Neutral Mononuclear Copper Complexes Stabilized by Two Cyclic (Alkyl)(amino)carbenes. Journal of the American Chemical Society, 136(17), Article 17. https://doi.org/10.1021/ja502521b
    11. Grupp, A., Bubrin, M., Ehret, F., Kvapilova, H., Zalis, S., & Kaim, Wolfgang. (2014). Oxidation and reduction response of a-diimine complexes with tricarbonylrhenium halides and pseudohalides. Journal of Organometallic Chemistry, 751, 678--685. https://doi.org/10.1016/j.jorganchem.2013.08.030
    12. Kaim, W., Bubrin, M., & Huebner, Ralph. (Hrsg.). (2014). Electron transfer-induced coordination changes in organometallic complexes with noninnocent hemilabile ligands: Adv. Organomet. Chem. Catal. John Wiley & Sons, Inc. https://doi.org/10.1002/9781118742952.ch49
    13. Ehret, F., Bubrin, M., Zalis, S., & Kaim, Wolfgang. (2014). Non-innocent Redox Behavior of Amidinato Ligands: Spectroscopic Evidence for Amidinyl Complexes. Zeitschrift fuer Anorganische und Allgemeine Chemie, 640(14), Article 14. https://doi.org/10.1002/zaac.201400306
    14. Paretzki, A., Bubrin, M., Fiedler, J., Zalis, S., & Kaim, Wolfgang. (2014). Correlated Coordination and Redox Activity of a Hemilabile Noninnocent Ligand in Nickel Complexes. Chemistry - A European Journal, 20(18), Article 18. https://doi.org/10.1002/chem.201304316
    15. Mandal, A., Agarwala, H., Ray, R., Plebst, S., Mobin, S. M., Priego, J. L., Jimenez-Aparicio, R., Kaim, W., & Lahiri, G. Kumar. (2014). Sensitivity of the Valence Structure in Diruthenium Complexes As a Function of Terminal and Bridging Ligands. Inorganic Chemistry, 53(12), Article 12. https://doi.org/10.1021/ic500452h
    16. Mandal, A., Kundu, T., Ehret, F., Bubrin, M., Mobin, S. M., Kaim, W., & Lahiri, G. Kumar. (2014). Varying electronic structural forms of ruthenium complexes of non-innocent 9,10-phenanthrenequinonoid ligands. Dalton Transactions, 43(6), Article 6. https://doi.org/10.1039/C3DT53104J
    17. Li, Y., Mondal, K. C., Samuel, P. P., Zhu, H., Orben, C. M., Panneerselvam, S., Dittrich, B., Schwederski, B., Kaim, W., Mondal, T., Koley, D., & Roesky, H. W. (2014). C4 Cumulene and the Corresponding Air-Stable Radical Cation and Dication. Angewandte Chemie, International Edition, 53(16), Article 16. https://doi.org/10.1002/anie.201310975
  8. 2013

    1. Krafft, M. J., Bubrin, M., Paretzki, A., Lissner, F., Fiedler, J., Zalis, S., & Kaim, Wolfgang. (2013). Identifying intermediates of sequential electron and hydrogen loss from a dicarbonylcobalt hydride complex. Angewandte Chemie, International Edition, 52(26), Article 26. https://doi.org/10.1002/anie.201301706
    2. Jana, R., Lissner, F., Schwederski, B., Fiedler, J., & Kaim, Wolfgang. (2013). A Ligand-Bridged Heterotetranuclear (Fe2Cu2) Redox System with Fc/Fc+ and Radical Ion Intermediates. Organometallics, 32(20), Article 20. https://doi.org/10.1021/om400466u
    3. Ehret, F., Bubrin, M., Zalis, S., & Kaim, Wolfgang. (2013). Discovering More Non-Innocence: Triazenido versus Triazenyl Radical Ligand Function, and a Comment on NO2n as a \dqSuspect\dq Ligand. Angewandte Chemie, International Edition, 52(17), Article 17. https://doi.org/10.1002/anie.201209260
    4. Dreher, A., Meyer, S., Naether, C., Westphal, A., Broda, H., Sarkar, B., Kaim, W., Kurz, P., & Tuczek, Felix. (2013). Reduction and Protonation of Mo(IV) Imido Complexes with depe Coligands: Generation and Reactivity of a S = 1/2 Mo(III) Alkylnitrene Intermediate. Inorganic Chemistry, 52(5), Article 5. https://doi.org/10.1021/ic301828e
    5. Das, D., Agarwala, H., Chowdhury, A. D., Patra, T., Mobin, S. M., Sarkar, B., Kaim, W., & Lahiri, G. Kumar. (2013). Four-Center Oxidation State Combinations and Near-Infrared Absorption in Ru(pap)(Q)2n (Q = 3,5-Di-tert-butyl-N-aryl-1,2-benzoquinonemonoimine, pap = 2-Phenylazopyridine). Chemistry - A European Journal, 19(23), Article 23. https://doi.org/10.1002/chem.201204620
    6. Choudhuri, M. M. R., Kaim, W., Sarkar, B., & Crutchley, R. J. (2013). Non-Innocence of 1,4-Dicyanamidobenzene Bridging Ligands in Dinuclear Ruthenium Complexes. Inorganic Chemistry, 52(19), Article 19. https://doi.org/10.1021/ic401316g
    7. Kaim, W., & Sarkar, Biprajit. (2013). Mixed valency of a 5d element: The osmium example. Coordination Chemistry Reviews, 257(9–10), Article 9–10. https://doi.org/10.1016/j.ccr.2012.08.026
    8. Mondal, P., Ehret, F., Bubrin, M., Das, A., Mobin, S. M., Kaim, W., & Lahiri, G. Kumar. (2013). A Diruthenium Complex of a \dqNindigo\dq Ligand. Inorganic Chemistry, 52(15), Article 15. https://doi.org/10.1021/ic400390b
    9. Jana, R., Mobin, S. M., Schwederski, B., Fiedler, J., & Kaim, Wolfgang. (2013). Variable coordination of redox-active TCNB in discrete and polymeric ferrocenylcopper(i) complexes: Structures and spectroelectrochemical behaviour. Dalton Transactions, 42(45), Article 45. https://doi.org/10.1039/c3dt51360b
    10. Mondal, K. C., Roesky, H. W., Stueckl, A. C., Ehret, F., Kaim, W., Dittrich, B., Maity, B., & Koley, Debasis. (2013). Formation of Trichlorosilyl-Substituted Carbon-Centered Stable Radicals through the Use of p-Accepting Carbenes. Angewandte Chemie, International Edition, 52(45), Article 45. https://doi.org/10.1002/anie.201300668
    11. Wang, D., Unold, J., Bubrin, M., Elser, I., Frey, W., Kaim, W., Xu, G., & Buchmeiser, M. R. (2013). Ruthenium-triazene complexes as latent catalysts for UV-induced ROMP. European Journal of Inorganic Chemistry, 2013(31), Article 31. https://doi.org/10.1002/ejic.201301048
    12. Roduner, E., Kaim, W., Sarkar, B., Urlacher, V. B., Pleiss, J., Glaeser, R., Einicke, W.-D., Sprenger, G. A., Beifuss, U., Klemm, E., Liebner, C., Hieronymus, H., Hsu, S.-F., Plietker, B., & Laschat, Sabine. (2013). Selective Catalytic Oxidation of C-H Bonds with Molecular Oxygen. ChemCatChem, 5(1), Article 1. https://doi.org/10.1002/cctc.201200266
    13. Agarwala, H., Ehret, F., Chowdhury, A. D., Maji, S., Mobin, S. M., Kaim, W., & Lahiri, G. Kumar. (2013). Electronic structure and catalytic aspects of Ru(tpm)(bqdi)(Cl/H2O)n, tpm = tris(1-pyrazolyl)methane and bqdi = o-benzoquinonediimine. Dalton Transactions, 42(10), Article 10. https://doi.org/10.1039/c2dt32402d
  9. 2012

    1. Roy, S., Sarkar, B., Imrich, H.-G., Fiedler, J., Zalis, S., Jimenez-Aparicio, R., Urbanos, F. A., Mobin, S. M., Lahiri, G. K., & Kaim, Wolfgang. (2012). Charged, but Found \dqNot Guilty\dq: Innocence of the Suspect Bridging Ligands RO(O)CNNC(O)OR2- = L2- in (acac)2Ru(m-L)Ru(acac)2n, n = +,0,-,2-. Inorganic Chemistry, 51(17), Article 17. https://doi.org/10.1021/ic300809w
    2. Kaim, Wolfgang. (2012). The Shrinking World of Innocent Ligands: Conventional and Non-Conventional Redox-Active Ligands. European Journal of Inorganic Chemistry, 2012(3), Article 3. https://doi.org/10.1002/ejic.201101359
    3. Agarwala, H., Scherer, T. M., Maji, S., Mondal, T. K., Mobin, S. M., Fiedler, J., Urbanos, F. A., Jimenez-Aparicio, R., Kaim, W., & Lahiri, G. Kumar. (2012). Correspondence of RuIIIRuII and RuIVRuIII Mixed Valent States in a Small Dinuclear Complex. Chemistry - A European Journal, 18(18), Article 18. https://doi.org/10.1002/chem.201103618
    4. Naklicki, M. L., Gorelsky, S. I., Kaim, W., Sarkar, B., & Crutchley, R. J. (2012). 1H NMR, Electron Paramagnetic Resonance, and Density Functional Theory Study of Dinuclear Pentaammineruthenium Dicyanamidobenzene Complexes. Inorganic Chemistry, 51(3), Article 3. https://doi.org/10.1021/ic2016403
    5. Das, A., Scherer, T. M., Mondal, P., Mobin, S. M., Kaim, W., & Lahiri, G. K. (2012). Experimental and DFT evidence for the fractional non-innocence of a b-diketonate ligand. Chemistry (Weinheim an der Bergstrasse, Germany), 18(45), Article 45.
    6. Ehret, F., Bubrin, M., Huebner, R., Schweinfurth, D., Hartenbach, I., Zalis, S., & Kaim, Wolfgang. (2012). Filling Gaps in the Series of Noninnocent Hetero-1,3-diene Chelate Ligands: Ruthenium Complexes of Redox-Active a-Azocarbonyl and a-Azothiocarbonyl Ligands RNNC(R’)E, E = O or S. Inorganic Chemistry, 51(11), Article 11. https://doi.org/10.1021/ic300439h
    7. Das, A., Scherer, T. M., Chowdhury, A. D., Mobin, S. M., Kaim, W., & Lahiri, G. Kumar. (2012). Asymmetrical Diruthenium Complex Bridged by a Redox-Active Ligand. Inorganic Chemistry, 51(3), Article 3. https://doi.org/10.1021/ic201975h
    8. Das, A. K., Huebner, R., Sarkar, B., Fiedler, J., Zalis, S., Lahiri, G. K., & Kaim, Wolfgang. (2012). UV-vis-NIR and EPR characterization of the redox series MQ32+,+,0,-,2-, M = Ru or Os, and Q = o-quinone derivative. Dalton Transactions, 41(29), Article 29. https://doi.org/10.1039/c2dt30846k
    9. Kaemper, S., Paretzki, A., Fiedler, J., Zalis, S., & Kaim, Wolfgang. (2012). Solar Cell Sensitizer Models Ru(bpy-R)2(NCS)2 Probed by Spectroelectrochemistry. Inorganic Chemistry, 51(4), Article 4. https://doi.org/10.1021/ic201825h
    10. Das, A., Scherer, T. M., Mobin, S. M., Kaim, W., & Lahiri, G. Kumar. (2012). Application of a Structure/Oxidation-State Correlation to Complexes of Bridging Azo Ligands. Chemistry - A European Journal, 18(35), Article 35. https://doi.org/10.1002/chem.201201049
    11. Kundu, T., Schweinfurth, D., Sarkar, B., Mondal, T. K., Fiedler, J., Mobin, S. M., Puranik, V. G., Kaim, W., & Lahiri, G. Kumar. (2012). Strong metal-metal coupling in mixed-valent intermediates Cl(L)Ru(m-tppz)Ru(L)Cl+, L = b-diketonato ligands, tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine. Dalton Transactions, 41(43), Article 43. https://doi.org/10.1039/c2dt31763j
    12. Bubrin, M., Krafft, M. J., Steudle, L., Huebner, R., Field, J. S., Zalis, S., & Kaim, Wolfgang. (2012). Structural Reassessment of W(CO)5(TCNE): N (s) Coordination Instead of an Olefin (p) Complex. Organometallics, 31(17), Article 17. https://doi.org/10.1021/om300565q
    13. Das, D., Scherer, T. M., Das, A., Mondal, T. K., Mobin, S. M., Fiedler, J., Priego, J. L., Jimenez-Aparicio, R., Kaim, W., & Lahiri, G. Kumar. (2012). The intricate paramagnetic state of Os(Q)2(bpy)+, Q = 4,6-di-tert-butyl-o-iminobenzoquinone. Dalton Transactions, 41(38), Article 38. https://doi.org/10.1039/c2dt30903c
    14. Das, A., Scherer, T. M., Mobin, S. M., Kaim, W., & Lahiri, G. Kumar. (2012). 9-Oxidophenalenone: A Noninnocent b-Diketonate Ligand? Inorganic Chemistry, 51(7), Article 7. https://doi.org/10.1021/ic300207d
    15. Drozdz, A., Bubrin, M., Fiedler, J., Zalis, S., & Kaim, Wolfgang. (2012). (a-Diimine)tricarbonylhalorhenium complexes: The oxidation side. Dalton Transactions, 41(3), Article 3. https://doi.org/10.1039/C1DT11449B
    16. Jana, R., Schwederski, B., Fiedler, J., & Kaim, Wolfgang. (2012). Facilitated reduction and oxidation of Ru(NH3)54(μ4-TCNX)8+ by changing from TCNX = TCNQ to TCNQF4. Polyhedron, 44(1), Article 1. https://doi.org/10.1016/j.poly.2012.06.066
    17. Huebner, R., Sarkar, B., Fiedler, J., Zalis, S., & Kaim, Wolfgang. (2012). Metal(IV) Complexes M(LN,O,S)2n (M = Ru, Os) of a Redox-Active o-Amidophenolate Ligand (LN,O,S)2- with Coordinating Thioether Appendix. European Journal of Inorganic Chemistry, 2012(22), Article 22. https://doi.org/10.1002/ejic.201200225
    18. Wang, D., Unold, J., Bubrin, M., Frey, W., Kaim, W., & Buchmeiser, M. R. (2012). Ruthenium(IV)-Bis(methallyl) Complexes as UV-Latent Initiators for Ring-Opening Metathesis Polymerization. ChemCatChem, 4(11), Article 11. https://doi.org/10.1002/cctc.201200183
    19. Roeser, S., Ertem, M. Z., Cady, C., Lomoth, R., Benet-Buchholz, J., Hammarstrom, L., Sarkar, B., Kaim, W., Cramer, C. J., & Llobet, Antoni. (2012). Synthesis, Structure, and Electronic Properties of RuN6 Dinuclear Ru-Hbpp Complexes. Inorganic Chemistry, 51(1), Article 1. https://doi.org/10.1021/ic201668r
  10. 2011

    1. Prabhakaran, R., Palaniappan, K., Huang, R., Sieger, M., Kaim, W., Viswanathamurthi, P., Dallemer, F., & Natarajan, Karuppannan. (2011). Can geometry control the coordination behaviour of 2-hydroxy-1-naphthaldehyde-N(4)-phenylthiosemicarbazone? A study towards its origin. Inorganica Chimica Acta, 376(1), Article 1. https://doi.org/10.1016/j.ica.2011.06.045
    2. Mahmoud, L., Gorelsky, S. I., Kaim, W., Sarkar, B., & Crutchley, R. J. (2011). EPR and 1H NMR spectroscopy and DFT study of pentaammineruthenium(III)phenylcyanamide complexes. Inorganica Chimica Acta, 374(1), Article 1. https://doi.org/10.1016/j.ica.2011.01.105
    3. Bulak, E., Varnali, T., Schwederski, B., Sarkar, B., Hartenbach, I., Fiedler, J., & Kaim, Wolfgang. (2011). 2,3-Bis(1-methylimidazol-2-yl)quinoxaline (bmiq), a new ligand with decoupled electron transfer and metal coordination sites: The very different redox behaviour of isoelectronic complexes with PtCl2 and AuCl2+. Dalton Transactions, 40(12), Article 12. https://doi.org/10.1039/c0dt01282c
    4. Kundu, T., Sarkar, B., Mondal, T. K., Mobin, S. M., Urbanos, F. A., Fiedler, J., Jimenez-Aparicio, R., Kaim, W., & Lahiri, G. Kumar. (2011). Redox-Rich Spin-Spin-Coupled Semiquinoneruthenium Dimers with Intense Near-IR Absorption. Inorganic Chemistry, 50(11), Article 11. https://doi.org/10.1021/ic102280q
    5. Schnoedt, J., Sieger, M., Sarkar, B., Fiedler, J., Manzur, J. S., Su, C.-Y., & Kaim, Wolfgang. (2011). Copper(I) Chelation by Tetradentate NSSN Donor Ligands: Reversible Oxidation but no Oxygenation. Zeitschrift fuer Anorganische und Allgemeine Chemie, 637(7–8), Article 7–8. https://doi.org/10.1002/zaac.201100026
    6. Bulak, E., Varnali, T., Schwederski, B., Bubrin, D., Fiedler, J., & Kaim, Wolfgang. (2011). Separation of Metal Binding and Electron Transfer Sites as a Strategy To Stabilize the Ligand-Reduced and Metal-Oxidized Form of Mo(CO)4L. Organometallics, 30(23), Article 23. https://doi.org/10.1021/om2007858
    7. Schnoedt, J., Manzur, J., Garcia, A.-M., Hartenbach, I., Su, C.-Y., Fiedler, J., & Kaim, Wolfgang. (2011). Coordination of a Hemilabile N,N,S Donor Ligand in the Redox System CuL2+/2+, L = 2-Pyridyl-N-(2’-alkylthio-phenyl)methyleneimine. European Journal of Inorganic Chemistry, 9, Article 9. https://doi.org/10.1002/ejic.201001183
    8. Das, D., Sarkar, B., Mondal, T. K., Mobin, S. M., Fiedler, J., Kaim, W., & Lahiri, G. Kumar. (2011). Oxidation State Analysis of a Four-Component Redox Series Os(pap)2(Q)n Involving Two Different Non-Innocent Ligands on a Redox-Active Transition Metal. Inorganic Chemistry, 50(15), Article 15. https://doi.org/10.1021/ic200615s
    9. Pellegrino, J., Huebner, R., Doctorovich, F., & Kaim, Wolfgang. (2011). Spectroelectrochemical Evidence for the Nitrosyl Redox Siblings NO+, NO., and NO- Coordinated to a Strongly Electron-Accepting FeII Porphyrin: DFT Calculations Suggest the Presence of High-Spin States after Reduction of the FeII-NO- Complex. Chemistry - A European Journal, 17(28), Article 28. https://doi.org/10.1002/chem.201003516
    10. Zhang, F., Goetz, G., Mena-Osteritz, E., Weil, M., Sarkar, B., Kaim, W., & Baeuerle, Peter. (2011). Molecular and electronic structure of cyclo10thiophene in various oxidation states: Polaron pair vs. bipolaron. Chemical Science, 2(4), Article 4. https://doi.org/10.1039/c0sc00560f
    11. Das, D., Sarkar, B., Kumbhakar, D., Mondal, T. K., Mobin, S. M., Fiedler, J., Urbanos, F. A., Jimenez-Aparicio, R., Kaim, W., & Lahiri, G. K. (2011). Bis(acetylacetonato)ruthenium complexes of noninnocent 1,2-dioxolene ligands: Qualitatively different bonding in relation to monoimino and diimino analogues. Chemistry (Weinheim an der Bergstrasse, Germany), 17(39), Article 39.
    12. Fekl, U., Sarkar, B., Kaim, W., Zimmer-De Iuliis, M., & Nguyen, Neilson. (2011). Tuning of the Spin Distribution between Ligand- and Metal-Based Spin: Electron Paramagnetic Resonance of Mixed-Ligand Molybdenum Tris(dithiolene) Complex Anions. Inorganic Chemistry, 50(18), Article 18. https://doi.org/10.1021/ic201047k
    13. Rivas, B. L., Maureira, A., Guzman, C., Contreras, D., Kaim, W., & Geckeler, K. E. (2011). Poly(L-lysine) as a polychelatogen to remove toxic metals using ultrafiltration and bactericide properties of poly(L-lysine)-Cu2+ complexes. Polymer Bulletin (Heidelberg, Germany), 67(5), Article 5. https://doi.org/10.1007/s00289-010-0418-3
    14. Kaim, Wolfgang. (2011). Manifestations of Noninnocent Ligand Behavior. Inorganic Chemistry, 50(20), Article 20. https://doi.org/10.1021/ic2003832
    15. Pellegrino, J., Hubner, R., Doctorovich, F., & Kaim, W. (2011). Spectroelectrochemical evidence for the nitrosyl redox siblings NO+, NO*, and NO- coordinated to a strongly electron-accepting Fe(II) porphyrin: DFT calculations suggest the presence of high-spin states after reduction of the Fe(II)-NO- complex. Chemistry (Weinheim an der Bergstrasse, Germany), 17(28), Article 28.
    16. Huebner, R., Weber, S., Strobel, S., Sarkar, B., Zalis, S., & Kaim, Wolfgang. (2011). Reversible Intramolecular Single-Electron Oxidative Addition Involving a Hemilabile Noninnocent Ligand. Organometallics, 30(6), Article 6. https://doi.org/10.1021/om100969q
    17. Das, A., Scherer, T., Maji, S., Mondal, T. K., Mobin, S. M., Urbanos, F. A., Jimenez-Aparicio, R., Kaim, W., & Lahiri, G. Kumar. (2011). Reductive Approach to Mixed Valency (n = 1-) in the Pyrazine Ligand-Bridged (acac)2Ru(m-L2-)Ru(acac)2n (L2- = 2,5-Pyrazine-dicarboxylate) through Experiment and Theory. Inorganic Chemistry, 50(15), Article 15. https://doi.org/10.1021/ic200530u
    18. Kaim, Wolfgang. (2011). Concepts for metal complex chromophores absorbing in the near infrared. Coordination Chemistry Reviews, 255(21–22), Article 21–22. https://doi.org/10.1016/j.ccr.2011.01.014
    19. Kaim, Wolfgang. (2011). \dqGuilty\dq Verdict - Evidence for the Noninnocence of Cyanide. Angewandte Chemie, International Edition, 50(45), Article 45. https://doi.org/10.1002/anie.201105767
    20. Schmidt, R., Moya, S. A., Aguirre, P., Fuentealba, M., Leboschka, M., Sieger, M., Niemeyer, M., & Kaim, Wolfgang. (2011). Synthesis, characterization and structure of tribromo(2-phenyl-1,8-naphthyridine)gold(III). Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 66(7), Article 7. https://doi.org/10.1515/znb-2011-0704
  11. 2010

    1. Zhang, J.-A., Pan, M., Yang, R., She, Z.-G., Kaim, W., Fan, Z.-J., & Su, C.-Yong. (2010). Structure, biological and electrochemical studies of transition metal complexes from N,S,N’ donor ligand 8-(2-pyridinylmethylthio)quinoline. Polyhedron, 29(1), Article 1. https://doi.org/10.1016/j.poly.2009.07.024
    2. Kundu, T., Sarkar, B., Mondal, T. K., Fiedler, J., Mobin, S. M., Kaim, W., & Lahiri, G. Kumar. (2010). Carboxylate Tolerance of the Redox-Active Platform Ru(m-tppz)Run, where tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine, in the Electron-Transfer Series (L)ClRu(m-tppz)RuCl(L)n, n = 2+, +, 0, -, and 2-, with 2-Picolinato, Quinaldato, and 8-Quinolinecarboxylato Ligands (L-). Inorganic Chemistry, 49(14), Article 14. https://doi.org/10.1021/ic100500p
    3. Kaim, W., Sieger, M., Greulich, S., Sarkar, B., Fiedler, J., & Zalis, Stanislav. (2010). The 1,4-diazabutadiene/1,2-enediamido non-innocent ligand system in the formation of iridaheteroaromatic compounds: Spectroelectrochemistry and electronic structure. Journal of Organometallic Chemistry, 695(7), Article 7. https://doi.org/10.1016/j.jorganchem.2009.11.042
    4. Jana, R., Sarkar, B., Bubrin, D., Fiedler, J., & Kaim, Wolfgang. (2010). Structure, electrochemistry and spectroscopy of a new diacylhydrazido-bridged diruthenium complex with a strongly near-infrared absorbing RuIIIRuII intermediate. Inorganic Chemistry Communications, 13(10), Article 10. https://doi.org/10.1016/j.inoche.2010.06.038
    5. Kumbhare, L. B., Wadawale, A. P., Jain, V. K., Sieger, M., & Kaim, Wolfgang. (2010). Binuclear rhodium(III) and iridium(III) monoselenocarboxylates: Synthesis, spectroscopy and structure of an ortho-metalated iridium complex featuring an IrCCC(m-Se) chelate ring. Inorganic Chemistry Communications, 13(4), Article 4. https://doi.org/10.1016/j.inoche.2010.01.012
    6. Mansell, S. M., Adams, C. J., Bramham, G., Haddow, M. F., Kaim, W., Norman, N. C., McGrady, J. E., Russell, C. A., & Udeen, S. J. (2010). Synthesis and characterization of the persistent radical BCl2(bipy). Chemical Communications (Cambridge, United Kingdom), 46(28), Article 28. https://doi.org/10.1039/c0cc00187b
    7. Zalis, S., Winter, R. F., & Kaim, Wolfgang. (2010). Quantum chemical interpretation of redox properties of ruthenium complexes with vinyl and TCNX type non-innocent ligands. Coordination Chemistry Reviews, 254(13–14), Article 13–14. https://doi.org/10.1016/j.ccr.2010.02.020
    8. Kaim, W., & Schwederski, Brigitte. (2010). Non-innocent ligands in bioinorganic chemistry: An overview. Coordination Chemistry Reviews, 254(13–14), Article 13–14. https://doi.org/10.1016/j.ccr.2010.01.009
    9. Chauhan, R. S., Kedarnath, G., Wadawale, A., Munoz-Castro, A., Arratia-Perez, R., Jain, V. K., & Kaim, Wolfgang. (2010). Tellurium(0) as a Ligand: Synthesis and Characterization of 2-Pyridyltellurolates of Platinum(II) and Structures of Pt2-Te-3-(R)C5H3N2Te(PR’3) (R = H or Me). Inorganic Chemistry, 49(9), Article 9. https://doi.org/10.1021/ic902347s
    10. Kaim, W., & Hosmane, N. S. (2010). Multidimensional potential of boron-containing molecules in functional materials. Journal of Chemical Sciences (Bangalore, India), 122(1), Article 1. https://doi.org/10.1007/s12039-010-0008-9
    11. Kavakli, C., Schwederski, B., Fiedler, J., Gudat, D., & Kaim, Wolfgang. (2010). Ligand-based Reduction in a Molecular Rectangle with Four Organoplatinum(IV) Vertices. Zeitschrift fuer Anorganische und Allgemeine Chemie, 636(1), Article 1. https://doi.org/10.1002/zaac.200900445
    12. van Nguyen, Tiritiris, I., Winter, R. F., Sarkar, B., Singh, P., Duboc, C., Munoz-Castro, A., Arratia-Perez, R., Kaim, W., & Schleid, Thomas. (2010). Oxidative perhydroxylation of closo-B12H122- to the stable inorganic cluster redox system B12(OH)122-/·-: Experiment and theory. Chemistry - A European Journal, 16(37), Article 37. https://doi.org/10.1002/chem.201001374
    13. Sarper, O., Sarkar, B., Fiedler, J., Lissner, F., & Kaim, Wolfgang. (2010). Organoosmium complexes of imidazole-containing chelate acceptor ligands. Inorganica Chimica Acta, 363(12), Article 12. https://doi.org/10.1016/j.ica.2010.04.007
    14. Sixt, T., Sieger, M., Krafft, M. J., Bubrin, D., Fiedler, J., & Kaim, Wolfgang. (2010). Ambi-Valence Taken Literally: Ruthenium vs Iron Oxidation in (1,1’-Diphosphinoferrocene)ruthenium(II) Hydride and Chloride Complexes as Deduced from Spectroelectrochemistry of the Heterodimetallic \dqMixed-Valent\dq Intermediates. Organometallics, 29(21), Article 21. https://doi.org/10.1021/om1004258
    15. Hartenbach, I., Strobel, S., Schleid, T., Sarkar, B., Kaim, W., Nockemann, P., Binnemans, K., & Dorhout, P. K. (2010). Synthesis, Structure, and Spectroscopic Properties of the New Lanthanum(III) Fluoride Oxomolybdate(VI) La3FMo4O16. European Journal of Inorganic Chemistry, 11, Article 11. https://doi.org/10.1002/ejic.200901052
    16. Schnoedt, J., Sieger, M., Schleid, T., Hartenbach, I., & Kaim, Wolfgang. (2010). Chelation and Bridging of Zinc(II) by Tetradentate N2S2 Donor Ligands: Similarities and Differences to Copper(I) and Copper(II) Systems. Zeitschrift fuer Anorganische und Allgemeine Chemie, 636(2), Article 2. https://doi.org/10.1002/zaac.200900373
    17. Van, N., Tiritiris, I., Winter, R. F., Sarkar, B., Singh, P., Duboc, C., Munoz-Castro, A., Arratia-Perez, R., Kaim, W., & Schleid, T. (2010). Oxidative perhydroxylation of closo-B12H122- to the stable inorganic cluster redox system B12(OH)12(2-/*-): Experiment and theory. Chemistry (Weinheim an der Bergstrasse, Germany), 16(37), Article 37.
    18. Lahiri, G. K., & Kaim, Wolfgang. (2010). Electronic structure alternatives in nitrosylruthenium complexes. Dalton Transactions, 39(19), Article 19. https://doi.org/10.1039/c002173c
  12. 2009

    1. Zalis, S., Sarkar, B., Duboc, C., & Kaim, Wolfgang. (2009). Evidence for the dimer-of-(mixed-valent dimers) configuration in tetranuclear (μ4-TCNX)Ru(NH3)548+, TCNX = TCNE and TCNQ, from DFT calculations. Monatshefte fuer Chemie, 140(7), Article 7. https://doi.org/10.1007/s00706-009-0129-3
    2. Frantz, S., Sieger, M., Hartenbach, I., Lissner, F., Schleid, T., Fiedler, J., Duboc, C., & Kaim, Wolfgang. (2009). Structure, electrochemistry, spectroscopy, and magnetic resonance, including high-field EPR, of (μ-abpy)Re(CO)3X2o/·-, where abpy = 2,2’-azobispyridine and X = F, Cl, Br, I. Journal of Organometallic Chemistry, 694(7–8), Article 7–8. https://doi.org/10.1016/j.jorganchem.2008.09.034
    3. De, P., Sarkar, B., Maji, S., Das, A. K., Bulak, E., Mobin, S. M., Kaim, W., & Lahiri, G. Kumar. (2009). Stabilization of RuNO6 and RuNO7 States in RuII(trpy)(bik)(NO)n+ trpy = 2,2’:6’,2’’-terpyridine, bik = 2,2’-bis(1-methylimidazolyl) ketone - Formation, Reactivity, and Photorelease of Metal-Bound Nitrosyl. European Journal of Inorganic Chemistry, 18, Article 18. https://doi.org/10.1002/ejic.200900021
    4. Das, A. K., Sarkar, B., Duboc, C., Strobel, S., Fiedler, J., Zalis, S., Lahiri, G. K., & Kaim, Wolfgang. (2009). An Odd-Electron Complex Ruk(NOm)(Qn)(terpy)2+ with Two Prototypical Non-Innocent Ligands. Angewandte Chemie, International Edition, 48(23), Article 23. https://doi.org/10.1002/anie.200900767
    5. Vergara, M. M., Garcia Posse, M. E., Fagalde, F., Katz, N. E., Fiedler, J., Sarkar, B., Sieger, M., & Kaim, Wolfgang. (2009). Mixed-valency with cyanides as terminal ligands: Diruthenium(III,II) complexes with the 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine bridge and variable co-ligands (CN- vs. bpy or NH3). Inorganica Chimica Acta, 363(1), Article 1. https://doi.org/10.1016/j.ica.2009.09.018
    6. de Candia, A. G., Singh, P., Kaim, W., & Slep, L. D. (2009). All-trans-ClRuII(py)4(NC)RuII(py)4(CN)RuII(py)4(NO)(PF6)4: A Redox-Active 2-Donor/1-Acceptor System Based on the Electrophilic RuNO6 Motif. Inorganic Chemistry, 48(2), Article 2. https://doi.org/10.1021/ic801347d
    7. Leboschka, M., Sieger, M., Sarkar, B., Niemeyer, M., Schurr, T., Fiedler, J., Zalis, S., & Kaim, Wolfgang. (2009). Silver(I), copper(I) and copper(II) complex of the new N,Se-chelate ligand 2-phenylselenomethyl-1H-benzimidazole: Electrochemistry and structure. Zeitschrift fuer Anorganische und Allgemeine Chemie, 635(6–7), Article 6–7. https://doi.org/10.1002/zaac.200900098
    8. Chatterjee, S., Singh, P., Fiedler, J., Bakova, R., Zalis, S., Kaim, W., & Goswami, Sreebrata. (2009). Effect of metal exchange (Os vs. Ru) and co-ligand variation (Cl- vs. acac-) on the oxidation state distribution in complexes of an o-phenylenediamido(2-)/o-quinonediimine redox system. Dalton Transactions, 37, Article 37. https://doi.org/10.1039/b906913e
    9. Leboschka, M., Sieger, M., Sarkar, B., Heck, J., Niemeyer, M., Bubrin, D., Lissner, F., Schleid, T., Zalis, S., Su, C.-Y., & Kaim, Wolfgang. (2009). 2-Organoselenomethyl-1H-benzimidazole Complexes of Copper(II) and Copper(I). Zeitschrift fuer Anorganische und Allgemeine Chemie, 635(13–14), Article 13–14. https://doi.org/10.1002/zaac.200900265
    10. Roy, S., Sarkar, B., Duboc, C., Fiedler, J., Sarper, O., Lissner, F., Mobin, S. M., Lahiri, G. K., & Kaim, W. (2009). Heterohexanuclear (Cu3Fe3) complexes of substituted hexaazatrinaphthylene (HATN) ligands: Twofold BF4(-) association in the solid and stepwise oxidation (3e) or reduction (2e) to spectroelectrochemically characterized species. Chemistry (Weinheim an der Bergstrasse, Germany), 15(28), Article 28.
    11. Kumbhakar, D., Sarkar, B., Das, A., Das, A. K., Mobin, S. M., Fiedler, J., Kaim, W., & Lahiri, G. Kumar. (2009). Valence structures of the diastereomeric complexes meso- and rac-Ru2(acac)4(m-Q)n (n = 2-, 1-, 0, 1+, 2+) with the multiple quinonoid bridging ligand Q = 1,2,4,5-tetraimino-3,6-diketocyclohexane. Dalton Transactions, 43, Article 43. https://doi.org/10.1039/b906900c
    12. Das, A. K., Sarkar, B., Fiedler, J., Zalis, S., Hartenbach, I., Strobel, S., Lahiri, G. K., & Kaim, Wolfgang. (2009). A Five-Center Redox System: Molecular Coupling of Two Noninnocent Imino-o-benzoquinonato-Ruthenium Functions through a p Acceptor Bridge. Journal of the American Chemical Society, 131(25), Article 25. https://doi.org/10.1021/ja901746x
    13. Kaim, W., & Sarkar, Biprajit. (2009). N2.3-: Filling a Gap in the N2n- Series. Angewandte Chemie, International Edition, 48(50), Article 50. https://doi.org/10.1002/anie.200904968
    14. Kowalski, K., Linseis, M., Winter, R. F., Zabel, M., Zalis, S., Kelm, H., Kruger, H.-J., Sarkar, B., & Kaim, Wolfgang. (2009). Charge delocalization in a heterobimetallic ferrocene-(vinyl)Ru(CO)Cl(PiPr3)2 system. Organometallics, 28(14), Article 14. https://doi.org/10.1021/om9002945
    15. Das, D., Das, A. K., Sarkar, B., Mondal, T. K., Mobin, S. M., Fiedler, J., Zalis, S., Urbanos, F. A., Jimenez-Aparicio, R., Kaim, W., & Lahiri, G. Kumar. (2009). The Semiquinone-Ruthenium Combination as a Remarkably Invariant Feature in the Redox and Substitution Series Ru(Q)n(acac)3-nm, n = 1-3; m = (-2), -1, 0, +1, (+2); Q = 4,6-Di-tert-butyl-N-phenyl-o-iminobenzoquinone. Inorganic Chemistry, 48(24), Article 24. https://doi.org/10.1021/ic901900g
    16. Kaim, W., Hosmane, N. S., Zalis, S., Maguire, J. A., & Lipscomb, W. N. (2009). Boron Atoms as Spin Carriers in Two- and Three-Dimensional Systems. Angewandte Chemie, International Edition, 48(28), Article 28. https://doi.org/10.1002/anie.200803493
    17. Hosmane, N. S., Zhu, Y., Maguire, J. A., Kaim, W., & Takagaki, Masao. (2009). Nano and dendritic structured carboranes and metallacarboranes: From materials to cancer therapy. Journal of Organometallic Chemistry, 694(11), Article 11. https://doi.org/10.1016/j.jorganchem.2008.11.059
    18. Kaim, W., & Fiedler, Jan. (2009). Spectroelectrochemistry: The best of two worlds. Chemical Society Reviews, 38(12), Article 12. https://doi.org/10.1039/b504286k
  13. 2008

    1. Kaim, Wolfgang. (2008). Metal compounds of the TCNX redox systems - from electron transfer to spin distribution and magnetism. Journal of the Chilean Chemical Society, 53(1), Article 1. https://doi.org/10.4067/S0717-97072008000100002
    2. Sarkar, B., Patra, S., Fiedler, J., Sunoj, R. B., Janardanan, D., Lahiri, G. K., & Kaim, Wolfgang. (2008). Mixed-Valent Metals Bridged by a Radical Ligand: Fact or Fiction Based on Structure-Oxidation State Correlations. Journal of the American Chemical Society, 130(11), Article 11. https://doi.org/10.1021/ja077676f
    3. Maji, S., Sarkar, B., Mobin, S. M., Fiedler, J., Urbanos, F. A., Jimenez-Aparicio, R., Kaim, W., & Lahiri, G. Kumar. (2008). Valence-State Alternatives in Diastereoisomeric Complexes (acac)2Ru(m-QL)Ru(acac)2n (QL2- = 1,4-Dioxido-9,10-anthraquinone, n = +2, +1, 0, -1, -2). Inorganic Chemistry, 47(12), Article 12. https://doi.org/10.1021/ic800115q
    4. Sarkar, B., Schurr, T., Hartenbach, I., Schleid, T., Fiedler, J., & Kaim, Wolfgang. (2008). Double cyclometalation of bridging 3,6-bis(2-thienyl)-1,2,4,5-tetrazine in a dinuclear mesityl(dimethylsulfoxide)platinum(II) complex: Structure and properties. Journal of Organometallic Chemistry, 693(8–9), Article 8–9. https://doi.org/10.1016/j.jorganchem.2007.10.045
    5. Sarkar, B., Frantz, S., Roy, S., Sieger, M., Duboc, C., Denninger, G., Kuemmerer, H.-J., & Kaim, Wolfgang. (2008). High-frequency EPR and structural data as complementary information on stable radical complexes containing the semi-reduced azo function. Journal of Molecular Structure, 890(1–3), Article 1–3. https://doi.org/10.1016/j.molstruc.2008.04.048
    6. Kaim, W., Sarkar, B., & Lahiri, G. Kumar. (Hrsg.). (2008). Mixed-valence intermediates as ideal targets for spectroelectrochemistry (SEC): Spectroelectrochem. Royal Society of Chemistry. https://doi.org/10.1039/9781847558404-00068
    7. Singh, P., Das, A. K., Sarkar, B., Niemeyer, M., Roncaroli, F., Olabe, J. A., Fiedler, J., Zalis, S., & Kaim, Wolfgang. (2008). Redox Properties of Ruthenium Nitrosyl Porphyrin Complexes with Different Axial Ligation: Structural, Spectroelectrochemical (IR, UV-Visible, and EPR), and Theoretical Studies. Inorganic Chemistry, 47(16), Article 16. https://doi.org/10.1021/ic702371t
    8. Roy, S., Sarkar, B., Bubrin, D., Niemeyer, M., Zalis, S., Lahiri, G. K., & Kaim, Wolfgang. (2008). Stabilizing the elusive ortho-quinone/copper(I) oxidation state combination through p/p interaction in an isolated complex. Journal of the American Chemical Society, 130(46), Article 46. https://doi.org/10.1021/ja804429v
    9. Samanta, S., Singh, P., Fiedler, J., Zalis, S., Kaim, W., & Goswami, Sreebrata. (2008). Singlet Diradical Complexes of Ruthenium and Osmium: Geometrical and Electronic Structures and their Unexpected Changes on Oxidation. Inorganic Chemistry, 47(5), Article 5. https://doi.org/10.1021/ic702301a
    10. Subat, M., Woinaroschy, K., Gerstl, C., Sarkar, B., Kaim, W., & Koenig, Burkhard. (2008). 1,4,7,10-Tetraazacyclododecane metal complexes as potent promoters of phosphodiester hydrolysis under physiological conditions. Inorganic Chemistry, 47(11), Article 11. https://doi.org/10.1021/ic702413q
    11. Salsman, J. C., & Kubiak, C. P. (Hrsg.). (2008). Infrared spectroelectrochemical investigations of ultrafast electron transfer in mixed-valence complexes: Spectroelectrochem. Royal Society of Chemistry. https://doi.org/10.1039/9781847558404-00123
    12. Dogan, A., Kavakli, C., Sieger, M., Niemeyer, M., Sarkar, B., & Kaim, Wolfgang. (2008). Structural and spectroscopic evidence for marginal metal-to-ligand charge transfer in complexes Pt(abpy)Me3X, abpy = 2,2’-azobispyridine, X = Cl, Br, I. Zeitschrift fuer Anorganische und Allgemeine Chemie, 634(14), Article 14. https://doi.org/10.1002/zaac.200800353
    13. Maji, S., Sarkar, B., Patra, M., Das, A. K., Mobin, S. M., Kaim, W., & Lahiri, G. Kumar. (2008). Formation, reactivity, and photorelease of metal bound nitrosyl in Ru(trpy)(L)(NO)n+ (trpy = 2,2’:6’,2’’-terpyridine, L = 2-phenylimidazo4,5-f1,10-phenanthroline). Inorganic Chemistry, 47(8), Article 8. https://doi.org/10.1021/ic702160w
    14. Roy, S., Sieger, M., Singh, P., Niemeyer, M., Fiedler, J., Duboc, C., & Kaim, Wolfgang. (2008). A radical-bridged bis(ferrocenylcopper(I)) complex: Structural identity, multifrequency EPR, and spectroelectrochemistry. Inorganica Chimica Acta, 361(6), Article 6. https://doi.org/10.1016/j.ica.2007.02.006
    15. Kumbhakar, D., Sarkar, B., Maji, S., Mobin, S. M., Fiedler, J., Urbanos, F. A., Jimenez-Aparicio, R., Kaim, W., & Lahiri, G. Kumar. (2008). Intramolecular Valence and Spin Interaction in meso and rac Diastereomers of a p-Quinonoid-Bridged Diruthenium Complex. Journal of the American Chemical Society, 130(51), Article 51. https://doi.org/10.1021/ja807043s
    16. Roy, S., Sieger, M., Sarkar, B., Schwederski, B., Lissner, F., Schleid, T., Fiedler, J., & Kaim, Wolfgang. (2008). Establishing the chelating a-azocarbonyl function in p-acceptor ligands. Angewandte Chemie, International Edition, 47(33), Article 33. https://doi.org/10.1002/anie.200801328
    17. Murray, P. R., & Yellowlees, L. J. (Hrsg.). (2008). EPR spectroelectrochemistry: Spectroelectrochem. Royal Society of Chemistry. https://doi.org/10.1039/9781847558404-00207
    18. Ghumaan, S., Sarkar, B., Maji, S., Puranik, V. G., Fiedler, J., Urbanos, F. A., Jimenez-Aparicio, R., Kaim, W., & Lahiri, G. Kumar. (2008). Valence-state analysis through spectroelectrochemistry in a series of quinonoid-bridged diruthenium complexes (acac)2Ru(m-L)Ru(acac)2n (n = +2, +1, 0, -1, -2). Chemistry - A European Journal, 14(34), Article 34. https://doi.org/10.1002/chem.200800976
    19. Best, S. P., Borg, S. J., & Vincent, K. A. (Hrsg.). (2008). Infrared spectroelectrochemistry: Spectroelectrochem. Royal Society of Chemistry. https://doi.org/10.1039/9781847558404-00001
    20. Maurer, J., Linseis, M., Sarkar, B., Schwederski, B., Niemeyer, M., Kaim, W., Zalis, S., Anson, C., Zabel, M., & Winter, R. F. (2008). Ruthenium complexes with vinyl, styryl, and vinylpyrenyl ligands: A case of non-innocence in organometallic chemistry. Journal of the American Chemical Society, 130(1), Article 1. https://doi.org/10.1021/ja075547t
    21. Klein, Axel. (Hrsg.). (2008). Spectroelectrochemistry of metalloporphyrins: Spectroelectrochem. Royal Society of Chemistry. https://doi.org/10.1039/9781847558404-00091
    22. Maity, A. N., Sarkar, B., Niemeyer, M., Sieger, M., Duboc, C., Zalis, S., & Kaim, Wolfgang. (2008). A tetranuclear organorhenium(I) complex of the 2,3,5,6-tetrafluoro-7,7,8,8-tetracyano-p-quinodimethane radical anion, TCNQF4-. Dalton Transactions, 42, Article 42. https://doi.org/10.1039/b807977c
    23. Kaim, Wolfgang. (2008). Hans Bock(1928-2008). Angewandte Chemie, International Edition, 47(16), Article 16. https://doi.org/10.1002/anie.200800607
    24. Leboschka, M., Siegera, M., Niemeyer, M., Zalis, S., & Kaim, Wolfgang. (2008). Dimerization of the 2-(methylselenomethyl)benzimidazole-silver(I) cation involving a AgI-AgI interaction. Zeitschrift fuer Anorganische und Allgemeine Chemie, 634(12–13), Article 12–13. https://doi.org/10.1002/zaac.200800283
    25. Singh, P., Sieger, M., Fiedler, J., Su, C.-Y., & Kaim, Wolfgang. (2008). Pseudo-base formation in the attempted synthesis of a conjugatively coupled bis(nitrosylruthenium) complex and spectroelectrochemistry of bipyrimidine-bridged dinuclear Ru(terpy)X precursor compounds (X = Cl, NO2). Dalton Transactions, 7, Article 7. https://doi.org/10.1039/B716307J
    26. Winter, R. F. (Hrsg.). (2008). Spectroelectrochemical investigations on carbon-rich organometallic complexes: Spectroelectrochem. Royal Society of Chemistry. https://doi.org/10.1039/9781847558404-00145
    27. Das, A. K., Bulak, E., Sarkar, B., Lissner, F., Schleid, T., Niemeyer, M., Fiedler, J., & Kaim, Wolfgang. (2008). Structures and redox properties of metal complexes of the electron-deficient diphosphine chelate ligand R,R-quinoxP. Organometallics, 27(2), Article 2. https://doi.org/10.1021/om700755y
    28. Khusniyarov, M. M., Harms, K., Burghaus, O., Sundermeyer, J., Sarkar, B., Kaim, W., van Slageren, J., Duboc, C., & Fiedler, Jan. (2008). A series of metal complexes with the non-innocent N,N’-bis(pentafluorophenyl)-o-phenylenediamido ligand: Twisted geometry for tuning the electronic structure. Dalton Transactions, 10, Article 10. https://doi.org/10.1039/b714974c
    29. Linseis, M., Winter, R. F., Sarkar, B., Kaim, W., & Zalis, Stanislav. (2008). Ligand-Centered Oxidations and Electron Delocalization in a Tetranuclear Complex of a Tetradonor-Substituted Olefin. Organometallics, 27(14), Article 14. https://doi.org/10.1021/om8003338
  14. 2007

    1. Maity, A. N., Schwederski, B., Sarkar, B., Zalis, S., Fiedler, J., Kar, S., Lahiri, G. K., Duboc, C., Grunert, M., Guetlich, P., & Kaim, Wolfgang. (2007). Tetranuclear Complexes of Fe(CO)2(C5H5)+ with TCNX Ligands (TCNX = TCNE, TCNQ, TCNB): Intramolecular Electron Transfer Alternatives in Compounds (m4-TCNX)MLn4. Inorganic Chemistry, 46(18), Article 18. https://doi.org/10.1021/ic062253k
    2. Singh, P., Fiedler, J., Zalis, S., Duboc, C., Niemeyer, M., Lissner, F., Schleid, T., & Kaim, Wolfgang. (2007). Spectroelectrochemistry and DFT Analysis of a New RuNOn Redox System with Multifrequency EPR Suggesting Conformational Isomerism in the RuNO7 State. Inorganic Chemistry, 46(22), Article 22. https://doi.org/10.1021/ic701206a
    3. Kaim, Wolfgang. (2007). The shortest metal-metal bond yet: Molecular and electronic structure of a dinuclear chromium diazadiene complex. Chemtracts, 20(7), Article 7.
    4. Bulak, E., Leboschka, M., Schwederski, B., Sarper, O., Varnali, T., Fiedler, J., Lissner, F., Schleid, T., & Kaim, Wolfgang. (2007). Reversibly Reducible cis-Dichloroplatinum(II) and cis-Dichloropalladium(II) Complexes of Bis(1-methylimidazol-2-yl)glyoxal. Inorganic Chemistry, 46(14), Article 14. https://doi.org/10.1021/ic070185b
    5. Kaim, W., & Lahiri, G. Kumar. (2007). Unconventional mixed-valent complexes of ruthenium and osmium. Angewandte Chemie, International Edition, 46(11), Article 11. https://doi.org/10.1002/anie.200602737
    6. Kavakli, C., Gabrielsson, A., Sieger, M., Schwederski, B., Niemeyer, M., & Kaim, Wolfgang. (2007). Reversible radical complex formation of an organometallic diplatinum(IV) compound. Journal of Organometallic Chemistry, 692(15), Article 15. https://doi.org/10.1016/j.jorganchem.2007.01.017
    7. Kaim, W., & Sarkar, Biprajit. (2007). Mixed valency in ruthenium complexes - Coordinative aspects. Coordination Chemistry Reviews, 251(3+4), Article 3+4. https://doi.org/10.1016/j.ccr.2006.06.003
    8. Koley, M., Sarkar, B., Ghumaan, S., Bulak, E., Fiedler, J., Kaim, W., & Lahiri, G. Kumar. (2007). Probing Mixed Valence in a New tppz-Bridged Diruthenium(III,II) Complex (μ-tppz)Ru(bik)Cl23+ (tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine, bik = 2,2’-Bis(1-methylimidazolyl)ketone): EPR Silence, Intervalence Absorption, and nCO Line Broadening. Inorganic Chemistry, 46(9), Article 9. https://doi.org/10.1021/ic0700102
    9. Sanyal, A., Chatterjee, S., Castineiras, A., Sarkar, B., Singh, P., Fiedler, J., Zalis, S., Kaim, W., & Goswami, Sreebrata. (2007). Singlet Diradical Complexes of Chromium, Molybdenum, and Tungsten with Azo Anion Radical Ligands from M(CO)6 Precursors. Inorganic Chemistry, 46(21), Article 21. https://doi.org/10.1021/ic700584x
    10. Kar, S., Sarkar, B., Ghumaan, S., Leboschka, M., Fiedler, J., Kaim, W., & Lahiri, G. Kumar. (2007). Ancillary ligand determination of the spin location in both oxidised and reduced forms of diruthenium complexes bridged by bis-bidentate 1,4-bis(2-phenolato)-1,4-diazabutadiene. Dalton Transactions, 19, Article 19. https://doi.org/10.1039/b617468j
    11. Contreras, D., Rodriguez, J., Freer, J., Schwederski, B., & Kaim, Wolfgang. (2007). Enhanced hydroxyl radical production by dihydroxybenzene-driven Fenton reactions: Implications for wood biodegradation. JBIC, Journal of Biological Inorganic Chemistry, 12(7), Article 7. https://doi.org/10.1007/s00775-007-0274-2
    12. Maurer, J., Sarkar, B., Kaim, W., Winter, R. F., & Zalis, Stanislav. (2007). Towards new organometallic wires: Tetraruthenium complexes bridged by phenylenevinylene and vinylpyridine ligands. Chemistry - A European Journal, 13(36), Article 36. https://doi.org/10.1002/chem.200700459
    13. Manzur, J., Vega, A., Garcia, A. M., Acuna, C., Sieger, M., Sarkar, B., Niemeyer, M., Lissner, F., Schleid, T., & Kaim, Wolfgang. (2007). Coordination alternatives in dinuclear bis(pyridin-2-ylalkyl)benzylamine copper(II) complexes with OH-, RO-, F-, or Cl- bridges: Experimental structures and DFT preferences. European Journal of Inorganic Chemistry, 35, Article 35. https://doi.org/10.1002/ejic.200700637
    14. Ghumaan, S., Sarkar, B., Patil, M. P., Fiedler, J., Sunoj, R. B., Kaim, W., & Lahiri, G. Kumar. (2007). Multiple one-electron oxidation and reduction of trinuclear bis(2,4-pentanedionato)ruthenium complexes with substituted diquinoxalino2,3-a:2’,3’-cphenazine ligands. Polyhedron, 26(13), Article 13. https://doi.org/10.1016/j.poly.2007.03.030
    15. Maji, S., Sarkar, B., Mobin, S. M., Fiedler, J., Kaim, W., & Lahiri, G. Kumar. (2007). Non-innocent behaviour of ancillary and bridging ligands in homovalent and mixed-valent ruthenium complexes A2Ru(m-L)RuA2n, A = 2,4-pentanedionato or 2-phenylazopyridine, L2- = 2,5-bis(2-oxidophenyl)pyrazine. Dalton Transactions, 23, Article 23. https://doi.org/10.1039/B701511A
  15. 2006

    1. Gabrielsson, A., van Leeuwen, P., & Kaim, Wolfgang. (2006). Acidic iridium hydrides: Implications for aerobic and Oppenauer oxidation of alcohols. Chemical Communications (Cambridge, United Kingdom), 47, Article 47. https://doi.org/10.1039/b610857a
    2. Dey, S., Jain, V. K., Varghese, B., Schurr, T., Niemeyer, M., Kaim, W., & Butcher, R. J. (2006). 3-Dimethylaminopropyl chalcogenolate complexes of palladium(II): Syntheses and characterization, including the crystal structures of Pd(OAc)(ECH2CH2CH2NMe2)2·H2O (E = S, Se) and PdCl(TeCH2CH2CH2NMe2)2. Inorganica Chimica Acta, 359(5), Article 5. https://doi.org/10.1016/j.ica.2005.09.019
    3. Moorlag, C., Sarkar, B., Sanrame, C. N., Baeuerle, P., Kaim, W., & Wolf, M. O. (2006). Conjugation Length Dependent Ground and Excited State Electronic Behavior in Oligothienyl Ru Complexes. Inorganic Chemistry, 45(18), Article 18. https://doi.org/10.1021/ic060912n
    4. Zalis, S., & Kaim, Wolfgang. (2006). Electronic structures of two kinds of oligoborane radical anions: Mixed-valence description of a reduced p-phenylenediborane and spin density distributions in distorted octahedral clusters B6Hal6.-, Hal = Cl, Br, I. Main Group Chemistry, 5(4), Article 4. https://doi.org/10.1080/10241220701562169
    5. Ghumaan, S., Sarkar, B., Chanda, N., Sieger, M., Fiedler, J., Kaim, W., & Lahiri, G. Kumar. (2006). 2,2’-Dipyridylketone (dpk) as Ancillary Acceptor and Reporter Ligand in Complexes (dpk)(Cl)Ru(m-tppz)Ru(Cl)(dpk)n+ where tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine. Inorganic Chemistry, 45(19), Article 19. https://doi.org/10.1021/ic060887l
    6. Maurer, J., Sarkar, B., Schwederski, B., Kaim, W., Winter, R. F., & Zalis, Stanislav. (2006). Divinylphenylene-Bridged Diruthenium Complexes Bearing Ru(CO)Cl(PiPr3)2 Entities. Organometallics, 25(15), Article 15. https://doi.org/10.1021/om0602660
    7. Singh, P., Sarkar, B., Sieger, M., Niemeyer, M., Fiedler, J., Zalis, S., & Kaim, Wolfgang. (2006). The Metal-NO Interaction in the Redox Systems Cl5Os(NO)n-, n = 1-3, and cis-(bpy)2ClOs(NO)2+/+: Calculations, Structural, Electrochemical, and Spectroscopic Results. Inorganic Chemistry, 45(12), Article 12. https://doi.org/10.1021/ic0517669
    8. Videla, M., Jacinto, J. S., Baggio, R., Garland, M. T., Singh, P., Kaim, W., Slep, L. D., & Olabe, J. A. (2006). New Ruthenium Nitrosyl Complexes with Tris(1-pyrazolyl)methane (tpm) and 2,2’-Bipyridine (bpy) Coligands. Structure, Spectroscopy, and Electrophilic and Nucleophilic Reactivities of Bound Nitrosyl. Inorganic Chemistry, 45(21), Article 21. https://doi.org/10.1021/ic061062e
    9. Bulak, E., Sarper, O., Dogan, A., Lissner, F., Schleid, T., & Kaim, Wolfgang. (2006). Dichlorogold(III) complexes of bis(1-methyl-2-imidazolyl)ketone and related ligands: Geometrical and electronic structures. Polyhedron, 25(13), Article 13. https://doi.org/10.1016/j.poly.2006.03.008
    10. Heilmann, M., Frantz, S., Kaim, W., Fiedler, J., & Duboc, Carole. (2006). Mixed-valent and radical states of complexes (bpy)2M(m-abpy)M’(bpy)2n+, M,M’ = Ru or Os, abpy = 2,2’-azobispyridine: Electron transfer vs. hole transfer mechanism in azo ligand-bridged complexes. Inorganica Chimica Acta, 359(3), Article 3. https://doi.org/10.1016/j.ica.2005.04.044
    11. Maji, S., Sarkar, B., Patra, S., Fiedler, J., Mobin, S. M., Puranik, V. G., Kaim, W., & Lahiri, G. Kumar. (2006). Metal-Induced Reductive Ring Opening of 1,2,4,5-Tetrazines: Three Resulting Coordination Alternatives, Including the New Non-Innocent 1,2-Diiminohydrazido(2-) Bridging Ligand System. Inorganic Chemistry, 45(3), Article 3. https://doi.org/10.1021/ic051532p
    12. Patra, S., Sarkar, B., Maji, S., Fiedler, J., Urbanos, F. A., Jimenez-Aparicio, R., Kaim, W., & Lahiri, G. Kumar. (2006). Controlling metal-ligand-metal oxidation state combinations by ancillary ligand (L) variation in the redox systems L2Ru(m-boptz)RuL2n, boptz = 3,6-bis(2-hydroxyphenyl)-1,2,4,5-tetrazine(2-), and L = acetylacetonate, 2,2’-bipyridine, or 2-phenylazopyridine. Chemistry - A European Journal, 12(2), Article 2. https://doi.org/10.1002/chem.200500295
    13. Sarper, O., Bulak, E., Kaim, W., & Varnali, T. (2006). Modelling bis-(1-methylimidazol-2-yl)glyoxal, „big“, in complex ions M(big)2+n, M = Au, Pt, Cu, Re, Zn: A DFT study. Molecular Physics, 104(5–7), Article 5–7. https://doi.org/10.1080/00268970500417432
    14. Sarper, O., Bulak, E., Kaim, W., & Varnali, Tereza. (2006). A DFT based assessment of coordination modes of the bis(1-methyl-2-imidazolyl)glyoxal ligand in mononuclear and dinuclear complexes. Journal of Molecular Structure: THEOCHEM, 773(1–3), Article 1–3. https://doi.org/10.1016/j.theochem.2006.06.039
  16. 2005

    1. Sieger, M., Vogler, C., Klein, A., Knoedler, A., Wanner, M., Fiedler, J., Zalis, S., Snoeck, T. L., & Kaim, Wolfgang. (2005). Geometrical and Electronic Structures of Dinuclear Complex Ions (μ-bpym)Cu(EAr3)222+ with Intramolecular \dqOrganic Sandwich\dq Formation (E = P or As; Ar = Aryl; bpym = 2,2’-Bipyrimidine). Inorganic Chemistry, 44(13), Article 13. https://doi.org/10.1021/ic050207z
    2. Ye, S., Sarkar, B., Lissner, F., Schleid, T., van Slageren, J., Fiedler, J., & Kaim, Wolfgang. (2005). Three-spin system with a twist: A bis(semiquinonato)copper complex with a nonplanar configuration at the copper(II) center. Angewandte Chemie, International Edition, 44(14), Article 14. https://doi.org/10.1002/anie.200462339
    3. Kar, S., Sarkar, B., Ghumaan, S., Janardanan, D., van Slageren, J., Fiedler, J., Puranik, V. G., Sunoj, R. B., Kaim, W., & Lahiri, G. Kumar. (2005). 2,5-Dioxido-1,4-benzoquinonediimine (H2L2-), a hydrogen-bonding noninnocent bridging ligand related to aminated topaquinone: Different oxidation state distributions in complexes (bpy)2Ru2(m-H2L)n (n = 0 , +, 2+, 3+, 4+) and (acac)2Ru2(m-H2L)m (m = 2-, -, 0, +, 2+). Chemistry - A European Journal, 11(17), Article 17. https://doi.org/10.1002/chem.200500202
    4. Ghumaan, S., Sarkar, B., Patra, S., van Slageren, J., Fiedler, J., Kaim, W., & Lahiri, G. Kumar. (2005). Sensitive Oxidation State Ambivalence in Unsymmetrical Three-Center (M/Q/M) Systems (acac)2Ru(m-Q)Ru(acac)2n, Q = 1,10-Phenanthroline-5,6-dione or 1,10-Phenanthroline-5,6-diimine (n = +, 0, -, 2-). Inorganic Chemistry, 44(9), Article 9. https://doi.org/10.1021/ic048309x
    5. Ghumaan, S., Sarkar, B., Patra, S., Parimal, K., van Slageren, J., Fiedler, J., Kaim, W., & Lahiri, G. Kumar. (2005). 3,6-Bis(2’-pyridyl)pyridazine (L) and its deprotonated form (L - H+)- as ligands for (acac)2Run+ or (bpy)2Rum+: Investigation of mixed valency in (acac)2Ru2(m-L - H+)0 and (bpy)2Ru2(m-L - H+)4+ by spectroelectrochemistry and EPR. Dalton Transactions, 4, Article 4. https://doi.org/10.1039/B417530A
    6. Sarkar, B., Patra, S., Fiedler, J., Sunoj, R. B., Janardanan, D., Mobin, S. M., Niemeyer, M., Lahiri, G. K., & Kaim, Wolfgang. (2005). Theoretical and experimental evidence for a new kind of spin-coupled singlet species: Isomeric mixed-valent complexes bridged by a radical anion ligand. Angewandte Chemie, International Edition, 44(35), Article 35. https://doi.org/10.1002/anie.200501075
    7. Ye, S., Kaim, W., Niemeyer, M., & Hosmane, N. S. (2005). Stereospecific Intramolecular S$\rightarrow$Pt Transmethylation from 8-(Methylthio)quinoline to Coordinated PtMe2: Formation of syn-fac-PtIVMe3(m-8-quinolinethiolato)2 with Stacked Quinoline Rings. Organometallics, 24(5), Article 5. https://doi.org/10.1021/om049247l
    8. Patra, S., Sarkar, B., Maji, S., Fiedler, J., Urbanos, F. A., Jimenez-Aparicio, R., Kaim, W., & Lahiri, G. K. (2005). Controlling metal-ligand-metal oxidation state combinations by ancillary ligand (L) variation in the redox systems L2Ru(mu-boptz)RuL2n, boptz = 3,6-bis(2-oxidophenyl)-1,2,4,5-tetrazine, and L = acetylacetonate, 2,2’-bipyridine, or 2-phenylazopyridine. Chemistry - A European Journal, 12(2), Article 2.
    9. Sarkar, S., Sarkar, B., Chanda, N., Kar, S., Mobin, S. M., Fiedler, J., Kaim, W., & Lahiri, G. Kumar. (2005). Complex Series Ru(tpy)(dpk)(X)n+ (tpy = 2,2’: 6’,2’’-Terpyridine; dpk = 2,2’-Dipyridyl Ketone; X = Cl-, CH3CN, NO2-, NO+, NO.bul., NO-): Substitution and Electron Transfer, Structure, and Spectroscopy. Inorganic Chemistry, 44(17), Article 17. https://doi.org/10.1021/ic050533e
    10. Tomlinson, S., Zheng, C., Hosmane, N. S., Yang, J., Wang, Y., Zhang, H., Gray, T. G., Demissie, T., Maguire, J. A., Baumann, F., Klein, A., Sarkar, B., Kaim, W., & Lipscomb, W. N. (2005). Chemistry of C-Trimethylsilyl-Substituted Heterocarboranes. 31. New Insights into Reaction Pathways of Carborane Ligand Systems: Synthetic, Structural, Spectroscopic, and Electrochemical Studies on Sandwich and Half-Sandwich Metallacarboranes of Iron, Cobalt, and Nickel. Organometallics, 24(9), Article 9. https://doi.org/10.1021/om048982u
    11. Kaim, W., Dogan, A., Klein, A., & Zalis, Stanislav. (2005). Complexes of 1,3-bis(diphenylphosphino)propane (dppp) with dichloroplatinum(II) and bis(chlorogold(I)): Intramolecular versus intermolecular AuI-AuI association of (m-dppp)(AuCl)2 in catena and cyclo forms. Zeitschrift fuer Anorganische und Allgemeine Chemie, 631(8), Article 8. https://doi.org/10.1002/zaac.200400514
    12. Kar, S., Sarkar, B., Ghumaan, S., Roy, D., Urbanos, F. A., Fiedler, J., Sunoj, R. B., Jimenez-Aparicio, R., Kaim, W., & Lahiri, G. Kumar. (2005). A New Coordination Mode of the Photometric Reagent Glyoxalbis(2-hydroxyanil) (H2gbha): Bis-Bidentate Bridging by gbha2- in the Redox Series (μ-gbha)Ru(acac)22n (n = -2, -1, 0, +1, +2), Including a Radical-Bridged Diruthenium(III) and a RuIII/RuIV Intermediate. Inorganic Chemistry, 44(24), Article 24. https://doi.org/10.1021/ic050950r
    13. Kaim, Wolfgang. (2005). Chemistry: Odd electron on nitrogen: A metal-stabilized aminyl radical. Science (Washington, DC, United States), 307(5707), Article 5707. https://doi.org/10.1126/science.1107345
    14. Patra, S., Sarkar, B., Ghumaan, S., Patil, M. P., Mobin, S. M., Sunoj, R. B., Kaim, W., & Lahiri, G. Kumar. (2005). Isomeric ruthenium terpyridine complexes Ru(trpy)(L)Cln+ containing the unsymmetrically bidentate acceptor L = 3-amino-6-(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine. Synthesis, structures, electrochemistry, spectroscopy and DFT calculations. Dalton Transactions, 7, Article 7. https://doi.org/10.1039/b500152h
    15. Ye, S., Sarkar, B., Duboc, C., Fiedler, J., & Kaim, Wolfgang. (2005). The Redox Series M(bpy)2(Q)n+, M = Ru or Os, Q = 3,5-Di-tert-butyl-N-phenyl-1,2-benzoquinonemonoimine. Isolation and a Complete X and W Band EPR Study of the Semiquinone States (n = 1). Inorganic Chemistry, 44(8), Article 8. https://doi.org/10.1021/ic048407i
    16. Kaim, W., Titze, C., Schurr, T., Sieger, M., Lawson, M., Jordanov, J., Rojas, D., Garcia, A. M., & Manzur, Jorge. (2005). Reactivity of copper(I) complexes with tripodal ligands towards O2: Structures of a precursor L3CuI(NCCH3)(BF4), L3 = tris(3-isopropyl-4,5-trimethylenepyrazolyl)methane and of its oxidation product L3CuII(m-OH)2CuIIL3(BF4)2 with strong antiferromagnetic spin-spin coupling. Zeitschrift fuer Anorganische und Allgemeine Chemie, 631(13–14), Article 13–14. https://doi.org/10.1002/zaac.200500053
    17. Phadnis, P. P., Jain, V. K., Schurr, T., Klein, A., Lissner, F., Schleid, T., & Kaim, Wolfgang. (2005). Synthesis, spectroscopy, structure and photophysical properties of dinaphthylmethylarsine complexes of palladium(II) and platinum(II). Inorganica Chimica Acta, 358(9), Article 9. https://doi.org/10.1016/j.ica.2005.03.026
    18. Klein, A., Schurr, T., Knoedler, A., Gudat, D., Klinkhammer, K.-W., Jain, V. K., Zalis, S., & Kaim, Wolfgang. (2005). Multiple Isomerism (cis/trans; syn/anti) in (dmso)2Pt(aryl)2 Complexes: A Combined Structural, Spectroscopic, and Theoretical Investigation. Organometallics, 24(17), Article 17. https://doi.org/10.1021/om050076
    19. Stange, A., Schurr, T., Klein, A., & Kaim, Wolfgang. (2005). Copper complexes of the new chelate ligand 1-methyl-2-(2-thiophenyl)-1H-benzimidazole (mtpb) and of its oxidation products. Zeitschrift fuer Anorganische und Allgemeine Chemie, 631(4), Article 4. https://doi.org/10.1002/zaac.200400343
    20. Baumann, F., Kaim, W., Denninger, G., Kuemmerer, H.-J., & Fiedler, Jan. (2005). Widely Separated Reduction Processes of abpy-Coupled Areneosmium(II) Reaction Centers (abpy = 2,2’-Azobispyridine): Stabilization of the Radical Intermediate and of the Os0OsII State. Organometallics, 24(8), Article 8. https://doi.org/10.1021/om049085t
    21. Knoedler, A., & Kaim, Wolfgang. (2005). Cis/trans-isomerism of complexes RuCl2(S-dmso)tpy), tpy = terpyridine ligand. Zeitschrift fuer Anorganische und Allgemeine Chemie, 631(2–3), Article 2–3. https://doi.org/10.1002/zaac.200400330
    22. Das, N., Arif, A. M., Stang, P. J., Sieger, M., Sarkar, B., Kaim, W., & Fiedler, Jan. (2005). Self-Assembly of Heterobimetallic Neutral Macrocycles Incorporating Ferrocene Spacer Groups: Spectroelectrochemical Analysis of the Double Two-Electron Oxidation of a Molecular Rectangle. Inorganic Chemistry, 44(16), Article 16. https://doi.org/10.1021/ic0481834
    23. Nayak, A., Patra, S., Sarkar, B., Ghumaan, S., Puranik, V. G., Kaim, W., & Lahiri, G. Kumar. (2005). Tetrazine derived mononuclear RuII(acac)2(L) (1), RuII(bpy)2(L)(ClO4)2 (2) and RuII(bpy)(L)2(ClO4)2 (3) (L = 3-amino-6-(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine, acac = acetylacetonate, bpy = 2,2’-bipyridine): Syntheses, structures, spectra and redox properties. Polyhedron, 24(2), Article 2. https://doi.org/10.1016/j.poly.2004.11.019
    24. Ye, S., Sarkar, B., Niemeyer, M., & Kaim, Wolfgang. (2005). Mixed-ligand copper complexes with 8-methylthioquinoline and triphenylphosphane or the o-semiquinone/catecholate redox system. European Journal of Inorganic Chemistry, 23, Article 23. https://doi.org/10.1002/ejic.200500567
    25. Maity, A. N., Schwederski, B., & Kaim, Wolfgang. (2005). The redox pair (μ4-TCNE)Fe(CO)2(C5H5)44+/3+: Surprisingly small metal-ligand interaction and the first resolved EPR hyperfine structure (13C, 14N, 57Fe) of a tetranuclear complex with TCNE-. Inorganic Chemistry Communications, 8(7), Article 7. https://doi.org/10.1016/j.inoche.2005.03.026
  17. 2004

    1. Dogan, A., Schwederski, B., Schleid, T., Lissner, F., Fiedler, J., & Kaim, Wolfgang. (2004). The complex (m,h2:h2-L)AuCl22, L2- = N,N’-bis(a-picolinoyl)hydrazido(2-), as obtained directly or through ring-opening reaction of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine. Inorganic Chemistry Communications, 7(2), Article 2. https://doi.org/10.1016/j.inoche.2003.11.006
    2. Frantz, S., Kaim, W., Fiedler, J., & Duboc, Carole. (2004). Complexes of Re(CO)3Cl with different oxidation states of the polyfunctional bmtz/H2bmtz ligand system (bmtz = 3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazine). Inorganica Chimica Acta, 357(12), Article 12. https://doi.org/10.1016/j.ica.2004.03.056
    3. Frantz, S., Sarkar, B., Sieger, M., Kaim, W., Roncaroli, F., Olabe, J. A., & Zalis, Stanislav. (2004). EPR insensitivity of the metal-nitrosyl spin-bearing moiety in complexes LnRuII-NO.bul.k. European Journal of Inorganic Chemistry, 14, Article 14. https://doi.org/10.1002/ejic.200400042
    4. Dey, S., Jain, V. K., Knoedler, A., & Kaim, Wolfgang. (2004). Synthesis and crystal structure of cis-dichlorobis(N,N-dimethylaminoethyl)tellurium-κ2N,Tepalladium(II). X-Ray Structure Analysis Online, 20(July-Sept), Article July-Sept.
    5. Sarkar, B., Kaim, W., Fiedler, J., & Duboc, Carole. (2004). Molecule-Bridged Mixed-Valent Intermediates Involving the RuI Oxidation State. Journal of the American Chemical Society, 126(45), Article 45. https://doi.org/10.1021/ja046397e
    6. Dey, S., Kumbhare, L. B., Jain, V. K., Schurr, T., Kaim, W., Klein, A., & Belaj, Ferdinand. (2004). Structural variety and multiple isomerism in 1-(dimethylamino)propyl-2-chalcogenolate and 2-(dimethylamino)propyl-1-chalcogenolate complexes of palladium(II) and platinum(II): Synthesis, spectroscopy and structures. European Journal of Inorganic Chemistry, 22, Article 22. https://doi.org/10.1002/ejic.200400524
    7. Sarkar, B., Frantz, S., Kaim, W., & Duboc, Carole. (2004). High-frequency EPR study of reduced diruthenium and dirhenium polypyridine complexes based on the 1,2,4,5-tetrazine radical bridge. Dalton Transactions, 21, Article 21. https://doi.org/10.1039/b407611g
    8. Dey, S., Jain, V. K., Klein, A., & Kaim, Wolfgang. (2004). Interconversion of structurally characterised complexes PdCl(Se-N)2 and Pd(Se-N)26 with the hemi-labile ligand Se-N = Me2NCH2CH2CH2Se-. Inorganic Chemistry Communications, 7(5), Article 5. https://doi.org/10.1016/j.inoche.2004.02.005
    9. Patra, S., Sarkar, B., Ghumaan, S., Fiedler, J., Kaim, W., & Lahiri, G. Kumar. (2004). Isovalent and Mixed-Valent Diruthenium Complexes (acac)2RuII(m-bpytz)RuII(acac)2 and (acac)2RuII(m-bpytz)RuIII(acac)2(ClO4) (acac = Acetylacetonate and bpytz = 3,6-Bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): Synthesis, Spectroelectrochemical, and EPR Investigation. Inorganic Chemistry, 43(19), Article 19. https://doi.org/10.1021/ic049346r
    10. Kaim, W., & Schwederski, Brigitte. (2004). Cooperation of metals with electroactive ligands of biochemical relevance: Beyond metalloporphyrins. Pure and Applied Chemistry, 76(2), Article 2. https://doi.org/10.1351/pac200476020351
    11. Singhal, A., Jain, V. K., Klein, A., Niemeyer, M., & Kaim, Wolfgang. (2004). Thiolato-bridged \dqLinear\dq trinuclear platinum complexes Pt3(m-SR)4(dppm)22+. Inorganica Chimica Acta, 357(7), Article 7. https://doi.org/10.1016/j.ica.2003.12.024
    12. Wang, J., Li, S., Zheng, C., Li, A., Hosmane, N. S., Maguire, J. A., Roesky, H. W., Cummins, C. C., & Kaim, Wolfgang. (2004). Chemistry of C-Trimethylsilyl-Substituted Heterocarboranes. 30. Synthetic and Structural Studies on Oxide Ion Encapsulating Tetralanthanide Tetrahedra Surrounded by \dqCarbons Apart\dq C2B4-Carborane Ligands (Ln(III) = La, Nd, Gd, Tb, Ho, Lu). Organometallics, 23(20), Article 20. https://doi.org/10.1021/om0496176
    13. Kaim, W., Scheiring, T., Weber, M., & Fiedler, Jan. (2004). The conjugative bridging of organometallic reaction centers in heterodinuclear complexes (OC)3ClRe(m-L)MCl(C5Me5)+, M = Rh or Ir - Spectroscopic consequences of reductive activation. Zeitschrift fuer Anorganische und Allgemeine Chemie, 630(12), Article 12. https://doi.org/10.1002/zaac.200400174
    14. Dogan, A., Sarkar, B., Klein, A., Lissner, F., Schleid, T., Fiedler, J., Zalis, S., Jain, V. K., & Kaim, Wolfgang. (2004). Complex Reduction Chemistry of (abpy)PtCl2, abpy = 2,2’-Azobispyridine: Formation of Cyclic (m,h2:h1-abpy)PtCl22+ with a New Coordination Mode for abpy and a Near-Infrared Ligand-to-Ligand Intervalence Charge Transfer Absorption of the One-Electron Reduced State. Inorganic Chemistry, 43(19), Article 19. https://doi.org/10.1021/ic049941t
    15. Patra, S., Sarkar, B., Ghumaan, S., Fiedler, J., Zalis, S., Kaim, W., & Lahiri, G. Kumar. (2004). (μ-L)RuII(acac)22n, n = 2+, +, 0, -, 2-, with L = 3,3’,4,4’-tetraimino-3,3’,4,4’-tetrahydrobiphenyl. EPR-supported assignment of NIR absorptions for the paramagnetic intermediates. Dalton Transactions, 5, Article 5. https://doi.org/10.1039/B315927M
    16. Ye, S., Kaim, W., Albrecht, M., Lissner, F., & Schleid, Thomas. (2004). Complexes of the imine/thioether mixed-donor ligand 8-methylthioquinoline with d6-configurated transition metal centers: Synthesis, structures and comparison with complexes of 1-methyl-2-(methylthiomethyl)-1H-benzimidazole. Inorganica Chimica Acta, 357(11), Article 11. https://doi.org/10.1016/j.ica.2004.03.040
    17. Sieger, M., Kaim, W., Stufkens, D. J., Snoeck, T. L., Stoll, H., & Zalis, Stanislav. (2004). Reduced and excited states of the intermediates (a-diimine)(C5R5)Rh in hydride transfer catalysis schemes: EPR and resonance Raman spectroscopy, and comparative DFT calculations of Co, Rh and Ir analogues. Dalton Transactions, 22, Article 22. https://doi.org/10.1039/B411892H
    18. Berger, S., Fiedler, J., Reinhardt, R., & Kaim, Wolfgang. (2004). Metal vs. Ligand Reduction in Complexes of Dipyrido3,2-a: 2’,3’-cphenazine and Related Ligands with (C5Me5)ClM+ (M = Rh or Ir): Evidence for Potential Rather Than Orbital Control in the Reductive Cleavage of the Metal-Chloride Bond. Inorganic Chemistry, 43(4), Article 4. https://doi.org/10.1021/ic0351388
    19. Gudat, D., Dogan, A., Kaim, W., & Klein, Axel. (2004). Multinuclear NMR study of some organoplatinum complexes containing multifunctional azines as chelating ligands. Magnetic Resonance in Chemistry, 42(9), Article 9. https://doi.org/10.1002/mrc.1407
    20. Wang, J., Li, S., Zheng, C., Hosmane, N. S., Maguire, J. A., Roesky, H. W., Cummins, C. C., & Kaim, Wolfgang. (2004). An oxide ion encapsulating tetraholmium tetrahedron stabilized by complexation with the \dqcarbons apart\dq C2B4-carborane ligands. Erratum to document cited in CA139:381606. Organometallics, 23(10), Article 10. https://doi.org/10.1021/om040048b
    21. Knoedler, A., Fiedler, J., & Kaim, Wolfgang. (2004). Characterization of the mixed-valent intermediate (n = 3) of the complex series (μ,η3:η3-L)Ru(terpy)2n+ with the unsaturated bridging ligand N,N’-bis(a-picolinoyl)hydrazido(2-) = L2-. Polyhedron, 23(4), Article 4. https://doi.org/10.1016/j.poly.2003.11.043
    22. Frantz, S., Fiedler, J., Hartenbach, I., Schleid, T., & Kaim, Wolfgang. (2004). A complete series of tricarbonylhalidorhenium(I) complexes (abpy)Re(CO)3(Hal), Hal = F, Cl, Br, I; abpy = 2,2’-azobispyridine: Structures, spectroelectrochemistry and EPR of reduced forms. Journal of Organometallic Chemistry, 689(19), Article 19. https://doi.org/10.1016/j.jorganchem.2004.06.047
    23. Frantz, S., Weber, M., Scheiring, T., Fiedler, J., Duboc, C., & Kaim, Wolfgang. (2004). Mechanism and product characterization from the electroreduction of heterodinuclear complexes (C5Me5)ClM(m-L)Re(CO)3X(PF6), M = Rh or Ir, L = 2,2’-azobispyridine or 2,2’-azobis(5-chloropyrimidine), X = halide. Inorganica Chimica Acta, 357(10), Article 10. https://doi.org/10.1016/j.ica.2004.02.031
    24. Sieger, M., Sarkar, B., Zalis, S., Fiedler, J., Escola, N., Doctorovich, F., Olabe, J. A., & Kaim, Wolfgang. (2004). Establishing the NO oxidation state in complexes Cl5(NO)Mn-, M = Ru or Ir, through experiments and DFT calculations. Dalton Transactions, 12, Article 12. https://doi.org/10.1039/B404121F
    25. Berger, S., Scheiring, T., Fiedler, J., & Kaim, Wolfgang. (2004). Coupling of organometallic reaction centers through the non-planar bridging ligand 2,3-bis(2-pyridyl)pyrazine. Zeitschrift fuer Anorganische und Allgemeine Chemie, 630(13–14), Article 13–14. https://doi.org/10.1002/zaac.200400133
    26. Chanda, N., Sarkar, B., Kar, S., Fiedler, J., Kaim, W., & Lahiri, G. Kumar. (2004). Mixed Valence Aspects of Diruthenium Complexes (L)ClRu2(m-tppz)n+ Incorporating 2-(2-Pyridyl)azoles (L) as Ancillary Functions and 2,3,5,6-Tetrakis(2-pyridyl)pyrazine (Tppz) as Bis-Tridentate Bridging Ligand. Inorganic Chemistry, 43(16), Article 16. https://doi.org/10.1021/ic049605c
    27. Kaim, Wolfgang. (Hrsg.). (2004). From electron transfer to chemistry: Electrochemical analysis of organometallic reaction center and of their interaction across ligand bridges: Trends Mol. Electrochem. FontisMedia S.A.
    28. Frantz, S., Rall, J., Hartenbach, I., Schleid, T., Zalis, S., & Kaim, Wolfgang. (2004). Metal-induced tautomerization of p- to o-quinone compounds: Experimental evidence from CuI and ReI complexes of azophenine and DFT studies. Chemistry - A European Journal, 10(1), Article 1. https://doi.org/10.1002/chem.200305369
    29. Patra, S., Sarkar, B., Ghumaan, S., Fiedler, J., Kaim, W., & Lahiri, G. Kumar. (2004). The triruthenium complex (acac)2RuII3(L) containing a conjugated diquinoxaline2,3-f:2’,3’-hphenazine (L) bridge and acetylacetonate (acac) as ancillary ligands. Synthesis, spectroelectrochemical and EPR investigation. Dalton Transactions, 5, Article 5. https://doi.org/10.1039/B316007F
    30. Wismach, C., Du Mont, W.-W., Jones, P. G., Ernst, L., Papke, U., Mugesh, G., Kaim, W., Wanner, M., & Becker, K. D. (2004). Selenol nitrosation and Se-nitrososelenol homolysis: A reaction path with possible biochemical implications. Angewandte Chemie, International Edition, 43(30), Article 30. https://doi.org/10.1002/anie.200453872
  18. 2003

    1. Haga, M., Ishizuya, M., Kanesugi, T., Yutaka, T., Sakiyama, D., Fees, J., & Kaim, Wolfgang. (2003). Synthesis and formation of dinuclear mixed-valent complexes of ruthenium and osmium bridged by 2-(2-pyrimidyl)benzimidazolate. Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry, 42A(9), Article 9.
    2. Kaim, W., Reinhardt, R., Greulich, S., & Fiedler, Jan. (2003). Resolving the Two-Electron Process for the Couple (C5Me5)M(NN̂)Cl+/(C5Me5)M(NN̂) (M = Rh, Ir) into Two One-Electron Steps Using the 2,2’-Azobis(pyridine) NN̂ Ligand, Fast Scan Cyclovoltammetry, and Spectroelectrochemistry: Detection of Radicals instead of MII Intermediates. Organometallics, 22(11), Article 11. https://doi.org/10.1021/om020860j
    3. Su, C.-Y., Cai, Y.-P., Chen, C.-L., Smith, M. D., Kaim, W., & Zur Loye, H.-Conrad. (2003). Ligand-Directed Molecular Architectures: Self-Assembly of Two-Dimensional Rectangular Metallacycles and Three-Dimensional Trigonal or Tetragonal Prisms. Journal of the American Chemical Society, 125(28), Article 28. https://doi.org/10.1021/ja034267k
    4. Cai, Y.-P., Su, C.-Y., Chen, C.-L., Li, Y.-M., Kang, B.-S., Chan, A. S. C., & Kaim, Wolfgang. (2003). Formation of Racemate and Mesocate Complexes from an Achiral Tripodal Ligand Containing Three Benzimidazole Groups. Inorganic Chemistry, 42(1), Article 1. https://doi.org/10.1021/ic025934y
    5. Patra, S., Sarkar, B., Mobin, S. M., Kaim, W., & Lahiri, G. Kumar. (2003). Separating Innocence and Non-Innocence of Ligands and Metals in Complexes (L)Ru(acac)2n (n = -1, 0, +1; L = o-Iminoquinone or o-Iminothioquinone). Inorganic Chemistry, 42(20), Article 20. https://doi.org/10.1021/ic034469h
    6. Phadnis, P. P., Jain, V. K., Klein, A., Weber, M., & Kaim, Wolfgang. (2003). Configurational selectivity in benzyldimethylarsine complexes of palladium(II) and platinum(II): Synthesis, spectroscopy and structures. Inorganica Chimica Acta, 346, 119--128. https://doi.org/10.1016/S0020-1693(02)01375-0
    7. Sieger, M., Wanner, M., Kaim, W., Stufkens, D. J., Snoeck, T. L., & Zalis, Stanislav. (2003). Low-Valent Cobalt Complexes with Three Different p Acceptor Ligands: Experimental and DFT Studies of the Reduced and the Low-Lying Excited States of (R-DAB)Co(NO)(CO), R-DAB = Substituted 1,4-Diaza-1,4-butadiene. Inorganic Chemistry, 42(10), Article 10. https://doi.org/10.1021/ic026078t
    8. Kaim, W., Doslik, N., Frantz, S., Sixt, T., Wanner, M., Baumann, F., Denninger, G., Kummerer, H.-J., Duboc-Toia, C., Fiedler, J., & Zalis, Stanislav. (2003). Azo compounds as electron acceptor or radical ligands in transition metal species: Spectroelectrochemistry and high-field EPR studies of ruthenium, rhodium and copper complexes of 2,2’-azobis(5-chloropyrimidine). Journal of Molecular Structure, 656(1–3), Article 1–3. https://doi.org/10.1016/S0022-2860(03)00339-9
    9. Sarkar, B., Kaim, W., Schleid, T., Hartenbach, I., & Fiedler, Jan. (2003). 3,4-Bis(2-pyrazinyl)-1,2,4,5-tetrazine. A new multifunctional ligand and its syn,fac-configurated bis(tricarbonylchlororhenium) complex. Zeitschrift fuer Anorganische und Allgemeine Chemie, 629(7–8), Article 7–8.
    10. Hartmann, H., Kaim, W., Wanner, M., Klein, A., Frantz, S., Duboc-Toia, C., Fiedler, J., & Zalis, Stanislav. (2003). Proof of Innocence for the Quintessential Noninnocent Ligand TCNQ in Its Tetranuclear Complex with Four fac-Re(CO)3(bpy)+ Groups: Unusually Different Reactivity of the TCNX Ligands (TCNX = TCNE, TCNQ, TCNB). Inorganic Chemistry, 42(22), Article 22. https://doi.org/10.1021/ic034232l
    11. Uhl, W., Cuypers, L., Kaim, W., Schwederski, B., & Koch, Rainer. (2003). Ga9(CMe3)9.bul.--a persistent cluster radical anion, boron-analogous chemistry with the heavier homologue gallium. Angewandte Chemie, International Edition, 42(21), Article 21. https://doi.org/10.1002/anie.200351123
    12. Sarkar, B., Kaim, W., Klein, A., Schwederski, B., Fiedler, J., Duboc-Toia, C., & Lahiri, G. K. (2003). What a Difference Ancillary Thienyl Makes: Unexpected Additional Stabilization of the Diruthenium(III,II) but Not the Diosmium(III,II) Mixed-Valent State in Tetrazine Ligand-Bridged Complexes. Inorganic Chemistry, 42(20), Article 20. https://doi.org/10.1021/ic034105p
    13. Kaim, Wolfgang. (2003). The chemistry and biochemistry of the copper-radical interaction. Dalton Transactions, 5, Article 5. https://doi.org/10.1039/b210193a
    14. Wang, J., Li, S., Zheng, C., Maguire, J. A., Sarkar, B., Kaim, W., & Hosmane, N. S. (2003). Chemistry of C-Trimethylsilyl-Substituted Heterocarboranes. 29. Synthetic and Structural Studies on Lanthanacarboranes with Two and Three \dqCarbons Apart\dq Carborane Cages Bonding to Ln(III) Metal (Ln(III) = Nd, Gd, Dy, Ho, Er, Tb, Lu). Organometallics, 22(21), Article 21. https://doi.org/10.1021/om030426x
    15. Wang, J., Li, S., Zheng, C., Hosmane, N. S., Maguire, J. A., Roesky, H. W., Cummins, C. C., & Kaim, Wolfgang. (2003). An Oxide Ion Encapsulating Tetraholmium Tetrahedron Stabilized by Complexation with the \dqCarbons Apart\dq C2B4-Carborane Ligands. Organometallics, 22(22), Article 22. https://doi.org/10.1021/om034019x
    16. Hartmann, H., Sarkar, B., Kaim, W., & Fiedler, Jan. (2003). Electron transfer reactions of (C5R5)2(CO)2Ti (R = H or Me) with TCNE or TCNQ spectroelectrochemical assignment of metal and ligand oxidation states in (C5Me5)2(CO)Ti(TCNX)2-/-/o/+. Journal of Organometallic Chemistry, 687(1), Article 1. https://doi.org/10.1016/j.jorganchem.2003.07.014
    17. Dey, S., Jain, V. K., Knoedler, A., & Kaim, Wolfgang. (2003). Synthesis and characterization of 3-dimethylaminopropyl selenolate complexes of palladium(II) and platinum(II). Inorganica Chimica Acta, 349, 104--110. https://doi.org/10.1016/S0020-1693(03)00080-X
    18. Fujino, T., Hoshino, Y., Eto, M., Yukawa, Y., Fiedler, J., & Kaim, Wolfgang. (2003). Synthesis and spectroelectrochemical characterization of a novel oxalate-bridged binuclear ruthenium(III) complex. Chemistry Letters, 32(3), Article 3. https://doi.org/10.1246/cl.2003.274
    19. Ye, S., Kaim, W., Sarkar, B., Schwederski, B., Lissner, F., Schleid, T., Duboc-Toia, C., & Fiedler, Jan. (2003). First crystal structure determination and high-frequency EPR study of an organoarsanecopper radical complex. Inorganic Chemistry Communications, 6(9), Article 9. https://doi.org/10.1016/S1387-7003(03)00216-8
    20. Dey, S., Jain, V. K., Knoedler, A., & Kaim, Wolfgang. (2003). Synthesis and characterization of 2-dimethylaminoethyl thiolate complexes of palladium(II) and platinum(II). Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry, 42A(9), Article 9.
    21. Wang, J., Li, S., Zheng, C., Maguire, J. A., Kaim, W., & Hosmane, N. S. (2003). Unsolvated \dqcarbons apart\dq neodymacarborane sandwich stabilized by bis(h6-benzene)potassium cation: A unique dimeric mixed-metal sandwiched ion-pair. Inorganic Chemistry Communications, 6(9), Article 9. https://doi.org/10.1016/S1387-7003(03)00227-2
    22. Zalis, S., Sieger, M., Greulich, S., Stoll, H., & Kaim, Wolfgang. (2003). Replacement of 2,2’-Bipyridine by 1,4-Diazabutadiene Acceptor Ligands: Why the Bathochromic Shift for (NN̂)IrCl(C5Me5)+ Complexes but the Hypsochromic Shift for (NN̂)Ir(C5Me5)? Inorganic Chemistry, 42(17), Article 17. https://doi.org/10.1021/ic034464k
    23. Hoshino, Y., Higuchi, S., Fiedler, J., Su, C.-Y., Knodler, A., Schwederski, B., Sarkar, B., Hartmann, H., & Kaim, Wolfgang. (2003). Long-range electronic coupling in various oxidation states of a C4-linked tris(b-diketonato)ruthenium dimer. Angewandte Chemie, International Edition, 42(6), Article 6. https://doi.org/10.1002/anie.200390186
    24. Su, C.-Y., Liao, S., Wanner, M., Fiedler, J., Zhang, C., Kang, B.-S., & Kaim, Wolfgang. (2003). The copper(I)/copper(II) transition in complexes with 8-alkylthioquinoline based multidentate ligands. Dalton Transactions, 2, Article 2. https://doi.org/10.1039/b208120m
    25. Frantz, S., Reinhardt, R., Greulich, S., Wanner, M., Fiedler, J., Duboc-Toia, C., & Kaim, Wolfgang. (2003). Multistep redox sequences of azopyridyl (L) bridged reaction centers in stable radical complex ions (μ-L)MCl(η5-C5Me5)2$\surd$+, M = Rh or Ir: Spectroelectrochemistry and high-frequency EPR spectroscopy. Dalton Transactions, 17, Article 17. https://doi.org/10.1039/B305311C
    26. Phadnis, P. P., Jain, V. K., Klein, A., Schurr, T., & Kaim, Wolfgang. (2003). Tri(allyl)- and tri(methylallyl)arsine complexes of palladium(ii) and platinum(ii): Synthesis, spectroscopy, photochemistry and structures. New Journal of Chemistry, 27(11), Article 11. https://doi.org/10.1039/b303990k
    27. Chanda, N., Sarkar, B., Fiedler, J., Kaim, W., & Lahiri, G. Kumar. (2003). Synthesis and mixed valence aspects of (L)ClRu2(m-tppz)n+ incorporating 2,2’-dipyridylamine (L) as ancillary and 2,3,5,6-tetrakis(2-pyridyl)pyrazine (tppz) as bridging ligand. Dalton Transactions, 18, Article 18. https://doi.org/10.1039/B306065A
    28. Dey, S., Jain, V. K., Chaudhury, S., Knoedler, A., & Kaim, Wolfgang. (2003). Synthesis and structure of bis(2-N,N-dimethylaminoethylselenolato)zinc and its transformation to ZnSe. Polyhedron, 22(4), Article 4. https://doi.org/10.1016/S0277-5387(02)01379-7
  19. 2002

    1. Knoedler, A., Wanner, M., Kaim, W., & Fiedler, Jan. (2002). Organometallic 5d6 transition metal complexes of 1-methyl-(2-alkylthiomethyl)-1H-benzimidazole ligands: Structures and electrochemical oxidation. Zeitschrift fuer Anorganische und Allgemeine Chemie, 628(5), Article 5.
    2. Kaim, W., Schwederski, B., Dogan, A., Fiedler, J., Kuehl, C. J., & Stang, P. J. (2002). Metalla-Supramolecular Rectangles as Electron Reservoirs for Multielectron Reduction and Oxidation. Inorganic Chemistry, 41(15), Article 15. https://doi.org/10.1021/ic020122n
    3. Pott, T., Jutzi, P., Kaim, W., Schoeller, W. W., Neumann, B., Stammler, A., Stammler, H.-G., & Wanner, Matthias. (2002). Reactivity of \dqGaI\dq Toward N-Substituted 1,4-Diazabuta-1,3-dienes: Synthesis and Characterization of Gallium Heterocycles Containing Paramagnetic Diazabutadiene Monoanions. Organometallics, 21(15), Article 15. https://doi.org/10.1021/om0200510
    4. Greulich, S., Klein, A., Knoedler, A., & Kaim, Wolfgang. (2002). Qualitatively Different Reactivities of Hydride Reagents toward (a-diimine)(h5-C5Me5)ClIr+ Cations: Substitution, Electron Transfer (Reduction), or Stepwise Hydrogenation. Organometallics, 21(4), Article 4. https://doi.org/10.1021/om010529k
    5. Dey, S., Jain, V. K., Knoedler, A., Klein, A., Kaim, W., & Zalis, Stanislav. (2002). Structural Basis for Unusually Long Wavelength Charge Transfer Transitions in Complexes MCl(ECH2CH2NMe2)(PR3) (E = Te, Se; M = Pt, Pd): Experimental Results and TD-DFT Calculations. Inorganic Chemistry, 41(11), Article 11. https://doi.org/10.1021/ic011210v
    6. Frantz, S., Hartmann, H., Doslik, N., Wanner, M., Kaim, W., Kuemmerer, H.-J., Denninger, G., Barra, A.-L., Duboc-Toia, C., Fiedler, J., Ciofini, I., Urban, C., & Kaupp, Martin. (2002). Multifrequency EPR Study and Density Functional g-Tensor Calculations of Persistent Organorhenium Radical Complexes. Journal of the American Chemical Society, 124(35), Article 35. https://doi.org/10.1021/ja025829n
    7. Kaim, Wolfgang. (2002). The coordination chemistry of 1,2,4,5-tetrazines. Coordination Chemistry Reviews, 230(1–2), Article 1–2. https://doi.org/10.1016/S0010-8545(02)00044-9
    8. Dutta, D. P., Jain, V. K., Knoedler, A., & Kaim, Wolfgang. (2002). Dithiocarbamates of gallium(III) and indium(III): Syntheses, spectroscopy, and structures. Polyhedron, 21(2), Article 2. https://doi.org/10.1016/S0277-5387(01)00990-1
    9. Sieger, M., Hubler, K., Scheiring, T., Sixt, T., Zalis, S., & Kaim, Wolfgang. (2002). Geometrical and ground state electronic structures of nitrosylcobalt complexes (RNCHCHNR)Co(NO)(CO) (R = isopropyl, 2,6-diisopropylphenyl or p-tolyl) from experiment and DFT-calculations. Zeitschrift fuer Anorganische und Allgemeine Chemie, 628(11), Article 11. https://doi.org/10.1002/1521-3749(200211)628:11\textless2360::AID-ZAAC2360\textgreater3.0.CO;2-L
    10. Kaim, W., Wanner, M., Knodler, A., & Zalis, Stanislav. (2002). Copper complexes with non-innocent ligands: Probing CuII/catecholato-CuI/o-semiquinonato redox isomer equilibria with EPR spectroscopy. Inorganica Chimica Acta, 337, 163--172. https://doi.org/10.1016/S0020-1693(02)01081-2
    11. Su, C.-Y., Cai, Y.-P., Chen, C.-L., Lissner, F., Kang, B.-S., & Kaim, Wolfgang. (2002). Self-assembly of trigonal-prismatic metallocages encapsulating BF4- or CuI32- as anionic guests: Structures and mechanism of formation. Angewandte Chemie, International Edition, 41(18), Article 18. https://doi.org/10.1002/1521-3773(20020916)41:18\textless3371::AID-ANIE3371\textgreater3.0.CO;2-4
    12. Phadnis, P. P., Jain, V. K., Knodler, A., & Kaim, Wolfgang. (2002). Tripropylarsane complexes of palladium(II) and platinum(II) - syntheses, spectroscopy, and structures. Zeitschrift fuer Anorganische und Allgemeine Chemie, 628(6), Article 6. https://doi.org/10.1002/1521-3749(200206)628:6\textless1332::AID-ZAAC1332\textgreater3.0.CO;2-T
    13. Klein, A., McInnes, E. J. L., & Kaim, Wolfgang. (2002). Organometallic platinum(ii) complexes of methyl-substituted phenanthrolines. Journal of the Chemical Society, Dalton Transactions, 11, Article 11. https://doi.org/10.1039/b201419j
    14. Knodler, A., Kaim, W., Jain, V. K., & Zalis, Stanislav. (2002). Dimethylplatinum(II) and tetramethylplatinum(IV) complexes of 1-methyl-(2-alkylthiomethyl)-1H-benzimidazoles: Experimental and DFT-calculated structures and NMR spectra. Journal of Organometallic Chemistry, 655(1–2), Article 1–2. https://doi.org/10.1016/S0022-328X(02)01564-4
    15. Knoedler, A., Wanner, M., Fiedler, J., & Kaim, Wolfgang. (2002). Coordination ambivalence of the electroactive bis-chelate ligand bis(1-methyl-2-imidazolyl)glyoxal (BIG) in mononuclear and dinuclear complexes with Re(CO)3Cl. Journal of the Chemical Society, Dalton Transactions, 15, Article 15. https://doi.org/10.1039/b202636h
    16. Glockle, M., Katz, N. E., Ketterle, M., & Kaim, Wolfgang. (2002). Qualitatively and quantitatively different solvatochromism of the MLCT and MMCT absorption bands of centrosymmetric acceptor-bridged diiron(II,II) and diiron(III,II) cyanide complexes. Inorganica Chimica Acta, 336, 55--60. https://doi.org/10.1016/S0020-1693(02)00846-0
    17. Kaim, W., Dogan, A., Wanner, M., Klein, A., Tiritiris, I., Schleid, T., Stufkens, D. J., Snoeck, T. L., McInnes, E. J. L., Fiedler, J., & Zalis, Stanislav. (2002). Reduced and Excited States of (bpym)PtCl2n (bpym = 2,2’-Bipyrimidine; n = 1, 2): Experiments and DFT Calculations. Inorganic Chemistry, 41(16), Article 16. https://doi.org/10.1021/ic020158f
  20. 2001

    1. Farrell, I. R., Hartl, F., Zalis, S., Wanner, M., Kaim, W., & Vlcek, A. (2001). Electrochemical oxidation of Cr(CO)4(tmp) to the low-spin Cr(I) species Cr(CO)4(tmp)+ (tmp=3,4,7,8-tetramethyl-1,10-phenanthroline): An IR, UV-Vis, and EPR spectroelectrochemical and DFT computational study of the accompanying changes in molecular and electronic structure. Inorganica Chimica Acta, 318(1,2), Article 1,2. https://doi.org/10.1016/S0020-1693(01)00421-2
    2. Berger, S., Hartmann, H., Wanner, M., Fiedler, J., & Kaim, W. (2001). Tetranuclear complexes (μ4-TCNX)Cu(Me3TACN)4(BF4)4 with TCNX = TCNE, TCNQ or TCNB (1,2,4,5-tetracyanobenzene) and Me3TACN = 1,4,7-trimethyl-1,4,7-triazacyclononane. Inorganica Chimica Acta, 314(1–2), Article 1–2. https://doi.org/10.1016/S0020-1693(00)00368-6
    3. Kaim, W., Titze, C., Klein, A., Knodler, A., & Zalis, Stanislav. (2001). Experimental and DFT calculated structure of the diruthenium(2.5) complex (Me3TACN)Ru(m-Cl)3Ru(Me3TACN)(PF6)2. Israel Journal of Chemistry, 41(3), Article 3. https://doi.org/10.1560/J8Q3-0DE1-A30K-XBGL
    4. Scheiring, T., Fiedler, J., & Kaim, Wolfgang. (2001). Structure and spectroelectrochemistry (UV/vis, IR, EPR) of the acceptor-bridged heterodinuclear complex (h5-C5Me5)ClRh(m-bptz)Re(CO)3Cl(PF6), bptz = 3,6-Bis(2-pyridyl)-1,2,4,5-tetrazine). Erratum to document cited in CA134:367020. Organometallics, 20(14), Article 14. https://doi.org/10.1021/om0103660
    5. Dey, S., Jain, V. K., Chaudhury, S., Knoedler, A., Lissner, F., & Kaim, Wolfgang. (2001). 2-(Dimethylamino)ethaneselenolates of palladium(II): Synthesis, structure, spectroscopy and transformation into palladium selenide. Journal of the Chemical Society, Dalton Transactions, 5, Article 5. https://doi.org/10.1039/b008310k
    6. Berger, S., Baumann, F., Scheiring, T., & Kaim, Wolfgang. (2001). Organometallic complex cations (hn-CnR’n)M(RN:CHCH:NR)Cl+ of 1,4-diazabutadienes (M = Os and n = 6 or M = Rh, Ir and n = 5, R = 2,6-dialkylphenyl). Structures and reduction to neutral compounds (hn-CnR’n)M(RNCH:CHNR). Zeitschrift fuer Anorganische und Allgemeine Chemie, 627(4), Article 4.
    7. Kaim, W., & Knoedler, Axel. (2001). Novel polydentate bridging ligands for the study of metal-metal communication: 1,2-bis(2-pyridylcarbonyl)hydrazine. Abstracts of Papers, 221st ACS National Meeting, San Diego, CA, United States, April 1-5, 2001, INOR-345.
    8. Kaim, W. (2001). Complexes with 2,2’-azobis(pyridine) and related „S-frame“ bridging ligands containing the azo function. Coordination Chemistry Reviews, 219–221, 463--488. https://doi.org/10.1016/S0010-8545(01)00347-2
    9. Kaim, W., Sixt, T., Weber, M., & Fiedler, Jan. (2001). Iron(II) versus osmium(II) oxidation in 1,1’-bis(diorganophosphino)ferrocene-osmium(II) complexes. Journal of Organometallic Chemistry, 637–639, 167--171. https://doi.org/10.1016/S0022-328X(01)00898-1
    10. Jimenez-Pulido, S. B., Sieger, M., Knodler, A., Heilmann, O., Wanner, M., Schwederski, B., Fiedler, J., Moreno-Carretero, M. N., & Kaim, Wolfgang. (2001). Rhenium(I) coordinated lumazine and pterin derivatives: Structure and spectroelectrochemistry of reversibly reducible (6-ATML)Re(CO)3Cl (6-ATML = 6-acetyl-1,3,7-trimethyllumazine). Inorganica Chimica Acta, 325(1,2), Article 1,2. https://doi.org/10.1016/S0020-1693(01)00646-6
    11. Gloeckle, M., Kaim, W., Klein, A., Roduner, E., Huebner, G., Zalis, S., van Slageren, J., Renz, F., & Guetlich, Philipp. (2001). The Stable Diiron(2.5) Complex Ion (NC)5Fe(m-tz)Fe(CN)55-, tz = 1,2,4,5-Tetrazine, and Its Neighboring Oxidation States. Inorganic Chemistry, 40(10), Article 10. https://doi.org/10.1021/ic001229i
    12. Glockle, M., Kaim, W., & Fiedler, Jan. (2001). Stepwise and chemically reversible reduction of (μ-bmtz)MCl(η6-cym)2PF62 (M = Ru, Os; bmtz = 3,6-bis(2’-pyrimidyl)-1,2,4,5-tetrazine) with up to six electrons. Zeitschrift fuer Anorganische und Allgemeine Chemie, 627(7), Article 7.
    13. Wiberg, N., Blank, T., Amelunxen, K., Noth, H., Knizek, J., Habereder, T., Kaim, W., & Wanner, Matthias. (2001). Compounds of silicon and homologues, 145. - Supersilyl Compounds of boron and homologues, 14. On the gallanyls R*3Ga2.bul. and R*4Ga3.bul. as well as gallanides R*3Ga2- and R*4Ga3- (R* = SitBu3) - syntheses, characterization, structures. European Journal of Inorganic Chemistry, 7, Article 7. https://doi.org/10.1002/1099-0682(200107)2001:7\textless1719::AID-EJIC1719\textgreater3.0.CO;2-Q
    14. Scheiring, T., Fiedler, J., & Kaim, Wolfgang. (2001). Structure and Spectroelectrochemistry (UV/Vis, IR, EPR) of the Acceptor-Bridged Heterodinuclear Complex (h5-C5Me5)ClRh(m-bptz)Re(CO)3Cl(PF6), bptz = 3,6-Bis(2-pyridyl)-1,2,4,5-tetrazine. Organometallics, 20(7), Article 7. https://doi.org/10.1021/om000892b
    15. Stange, A. F., Klein, A., Klinkhammer, K.-W., & Kaim, Wolfgang. (2001). Aggregation control of copper(I) thiolates through substituent size and ancillary chelate ligands: Closely related mono-, di-, tri- and tetranuclear complexes. Inorganica Chimica Acta, 324(1,2), Article 1,2. https://doi.org/10.1016/S0020-1693(01)00535-7
    16. Hartmann, H., Kaim, W., Hartenbach, I., Schleid, T., Wanner, M., & Fiedler, Jan. (2001). A fully characterized complex ion with unreduced TCNQ as fourfold bridging ligand. (m4-TCNQ)fac-Re(CO)3(bpy)44+. Angewandte Chemie, International Edition, 40(15), Article 15. https://doi.org/10.1002/1521-3773(20010803)40:15\textless2842::AID-ANIE2842\textgreater3.0.CO;2-R
    17. Hornung, F., Wanner, M., Klinkhammer, K. W., Kaim, W., & Fiedler, Jan. (2001). Heterocubane cluster compounds (NEt4)Y:M(μ3-S)Re(CO)33(μ3-E) (M = W or Mo, Y = O or S, E = S or Se). Structures, spectroscopy, and electrochemistry. Zeitschrift fuer Anorganische und Allgemeine Chemie, 627(10), Article 10.
    18. Kaim, W., Reinhardt, R., Greulich, S., Sieger, M., Klein, A., & Fiedler, Jan. (2001). Coupling of electron transfer and bond dissociation processes in dinuclear complexes with rhodium and iridium reaction centres bridged by 2,2’-bipyrimidine. Collection of Czechoslovak Chemical Communications, 66(2), Article 2. https://doi.org/10.1135/cccc20010291
    19. Uhl, W., Cuypers, L., Harms, K., Kaim, W., Wanner, M., Winter, R., Koch, R., & Saak, Wolfgang. (2001). Ga9(CMe3)9, an important new building block in the structural chemistry of the alkylelement(I) compounds EnRn (E = B-In). Angewandte Chemie, International Edition, 40(3), Article 3. https://doi.org/10.1002/1521-3773(20010202)40:3\textless566::AID-ANIE566\textgreater3.0.CO;2-T
    20. Kaim, Wolfgang. (Hrsg.). (2001). ESR spectroscopy of inorganic and organometallic radicals: Electron Transfer Chem (Bd. 2). Wiley-VCH Verlag GmbH. https://doi.org/10.1002/9783527618248.ch32
    21. Dey, S., Jain, V. K., Knoedler, A., Kaim, W., & Zalis, Stanislav. (2001). Platinum(II) complexes of 2-(dimethylamino)ethylselenolate - donor-acceptor inter-ligand interactions as evident from experimental and TD-DFT computational analysis. European Journal of Inorganic Chemistry, 11, Article 11. https://doi.org/10.1002/1099-0682(200111)2001:11\textless2965::AID-EJIC2965\textgreater3.0.CO;2-7
    22. Wanner, M., Scheiring, T., Kaim, W., Slep, L. D., Baraldo, L. M., Olabe, J. A., Zalis, S., & Baerends, E. Jan. (2001). EPR Characteristics of the (NC)5M(NO)3- Ions (M = Fe, Ru, Os). Experimental and DFT Study Establishing NO.bul. as a Ligand. Inorganic Chemistry, 40(22), Article 22. https://doi.org/10.1021/ic010452s
    23. Wanner, M., Hartenbach, I., Fiedler, J., Schleid, T., & Kaim, Wolfgang. (2001). Dinuclear and trinuclear organometallic complexes (ReS4)MCl(C5Me5), M = Rh, Ir, and (m-WS4)IrCl(C5Me5)2. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 56(9), Article 9. https://doi.org/10.1515/znb-2001-0913
    24. Gloeckle, M., Huebler, K., Kuemmerer, H.-J., Denninger, G., & Kaim, Wolfgang. (2001). Dicopper(I) Complexes with Reduced States of 3,6-Bis(2’-pyrimidyl)-1,2,4,5-tetrazine: Crystal Structures and Spectroscopic Properties of the Free Ligand, a Radical Species, and a Complex of the 1,4-Dihydro Form. Inorganic Chemistry, 40(10), Article 10. https://doi.org/10.1021/ic001228q
  21. 2000

    1. Hartmann, H., Scheiring, T., Fiedler, J., & Kaim, W. (2000). Structures and spectroelectrochemistry (UV-vis, IR, EPR) of complexes (OC)3ClRen(abpy), n = 1, 2; abpy = 2,2’-azobispyridine. Journal of Organometallic Chemistry, 604(2), Article 2. https://doi.org/10.1016/S0022-328X(00)00282-5
    2. Scheiring, T., Kaim, W., Olabe, J. A., Parise, A. R., & Fiedler, J. (2000). The valence-localized decacyanodiruthenium(III,II) analogue of the Creutz-Taube ion. Completing the full d5/d6 triad (NC)5M(m-pz)M(CN)55-, M = Fe, Ru, Os; pz = pyrazine. Inorganica Chimica Acta, 300–302, 125--130. https://doi.org/10.1016/S0020-1693(99)00456-9
    3. Wiberg, N., Blank, T., Kaim, W., Schwederski, B., & Linti, Gerald. (2000). Compounds of silicon and homologues, 134. Supersilyl compounds of boron and homologues, 10. Tri(supersilyl)dialanyl (tBu3Si)3Al2· and tetra(supersilyl)cyclotrialanyl (tBu3Si)4Al3· - new stable radicals of a group 13 element from thermolysis of (tBu3Si)4Al2. European Journal of Inorganic Chemistry, 7, Article 7. https://doi.org/10.1002/1099-0682(200007)2000:7\textless1475::AID-EJIC1475\textgreater3.0.CO;2-N
    4. Kaim, Wolfgang. (2000). Inorganic Electronic Structure and Spectroscopy. Vol. I+II. Edited by Edward I. Solomon and Alfred B. P. Lever. Angewandte Chemie, International Edition, 39(23), Article 23.
    5. Albrecht, M., Hubler, K., & Kaim, Wolfgang. (2000). Syntheses, structures, and properties of the complexes Ag(N-S)n(X), N-S = 1-methyl-2-(alkylthiomethyl)-1H-benzimidazoles, X = PF6 (n = 2) or PO2F2 (n = 1). Zeitschrift fuer Anorganische und Allgemeine Chemie, 626(5), Article 5. https://doi.org/10.1002/(SICI)1521-3749(200005)626:5\textless1033::AID-ZAAC1033\textgreater3.0.CO;2-A
    6. Hosmane, N. S., Zhang, H., Maguire, J. A., Wang, Y., Demissie, T., Colacot, T. J., Ezhova, M. B., Lu, K.-J., Zhu, D., Gray, T. G., Helfert, S. C., Hosmane, S. N., Collins, J. D., Baumann, F., Kaim, W., & Lipscomb, W. N. (2000). Chemistry of C-Trimethylsilyl-Substituted Heterocarboranes. 28. Selective Alkylation and Reactivity of \dqCarbons Adjacent\dq and \dqCarbons Apart\dq Tetracarba-nido-dodecaborane(12) Derivatives toward Group 1 and Group 2 Metals. Synthetic, Spectroscopic, and Structural Investigations on Lithium-, Sodium-, Potassium-, Cesium-, and Magnesium-Complexed C4B8 Carboranes. Organometallics, 19(4), Article 4. https://doi.org/10.1021/om990677z
    7. Scheiring, T., Kaim, W., & Fiedler, J. (2000). Geometrical and electronic structures of the acetyl complex Re(bpy)(CO)3(COCH3) and of M(bpy)(CO)4(OTf), M = Mn, Re. Journal of Organometallic Chemistry, 598(1), Article 1. https://doi.org/10.1016/S0022-328X(99)00691-9
    8. Sixt, T., Fiedler, J., & Kaim, W. (2000). Iron versus ruthenium oxidation in 1,1’-bis(diphenylphosphino)ferrocene-ruthenium(II) complexes: EPR and spectroelectrochemical evidence. Inorganic Chemistry Communications, 3(2), Article 2. https://doi.org/10.1016/S1387-7003(00)00009-5
    9. Albrecht, M., & Kaim, Wolfgang. (2000). Coordination of rhodium(III), iridium(III), and copper(II) with the potentially tetradentate acceptor ligand bis(1-methylimidazol-2-yl)glyoxal (big). Zeitschrift fuer Anorganische und Allgemeine Chemie, 626(6), Article 6.
    10. Elbe, F., Keck, J., Fluegge, A. P., Kramer, H. E. A., Fischer, P., Hayoz, P., Leppard, D., Rytz, G., Kaim, W., & Ketterle, Michael. (2000). Photochemical and Photophysical Deactivation of 2,4,6-Triaryl-1,3,5-triazines. Journal of Physical Chemistry A, 104(35), Article 35. https://doi.org/10.1021/jp000086i
    11. Berger, S., Klein, A., Wanner, M., Kaim, W., & Fiedler, Jan. (2000). Electron Paramagnetic Resonance and Spectroscopic Characteristics of Electrogenerated Mixed-Valent Systems (h5-C5Me5)M(m-L)M(h5-C5Me5)+ (M = Rh, Ir; L = 2,5-Diiminopyrazines) in Relation to the Radicals (h5-C5Me5)ClM(m-L)MCl(h5-C5Me5)+ and (h5-C5Me5)M(m-L)MCl(h5-C5Me5)2+. Inorganic Chemistry, 39(12), Article 12. https://doi.org/10.1021/ic991110d
    12. Hornung, F. M., Heilmann, O., Kaim, W., Zalis, S., & Fiedler, Jan. (2000). Metal vs. Ligand Reduction in Complexes of 1,3-Dimethylalloxazine (DMA) with Copper(I), Ruthenium(II), and Tungsten(VI). Crystal Structures of (DMA)WO2Cl2 and (Bis(1-methylimidazol-2-yl)ketone)WO2Cl2. Inorganic Chemistry, 39(18), Article 18. https://doi.org/10.1021/ic0001816
    13. Sixt, T., & Kaim, W. (2000). Copper(I) complexes with N,O-donor Schiff base ligands related to intermediate forms of the TPQ cofactor in amine oxidases. Inorganica Chimica Acta, 300–302, 762--768. https://doi.org/10.1016/S0020-1693(99)00612-X
    14. Albrecht, M., Huebler, K., Zalis, S., & Kaim, Wolfgang. (2000). Crucial Role of Cu-S Bonding for Structural Changes Accompanying the Reversible CuI/CuII Transition in an Unrestrained Cu(N$\cap$S)2 Coordination Arrangement. An Experimental and DFT Study. Inorganic Chemistry, 39(21), Article 21. https://doi.org/10.1021/ic000021u
    15. Hartmann, H., Berger, S., Winter, R., Fiedler, J., & Kaim, Wolfgang. (2000). Reversible and Site-Specific Reduction of the Ligand Sides in a Molecular Rectangle with up to Eight Electrons. Inorganic Chemistry, 39(21), Article 21. https://doi.org/10.1021/ic0001006
    16. Knodler, A., Hubler, K., Sixt, T., & Kaim, W. (2000). A copper(I) dimer Cu(L)(CH3CN)2(BF4)2 with the new chelating and bridging tridentate ligand 1-(2-pyridylmethyl)-2-(2-pyridyl)benzimidazole (L). Inorganic Chemistry Communications, 3(4), Article 4. https://doi.org/10.1016/S1387-7003(00)00042-3
    17. Uhl, W., Spies, T., Haase, D., Winter, R., & Kaim, Wolfgang. (2000). Synthesis of a Large Organometallic Macrocycle Comprising Four Ga-Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands. Organometallics, 19(6), Article 6. https://doi.org/10.1021/om990875q
    18. Kaim, W., Klein, A., & Gloeckle, Markus. (2000). Exploration of Mixed-Valence Chemistry: Inventing New Analogues of the Creutz-Taube Ion. Accounts of Chemical Research, 33(11), Article 11. https://doi.org/10.1021/ar960067k
    19. Sixt, T., Kaim, W., & Preetz, Wilhelm. (2000). Characterization of the inorganic/organometallic osmium(IV) compound Cp*2OsIVCl2OsIVCl6 as formed by the reaction of OsCl3 with pentamethylcyclopentadiene in air. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 55(3/4), Article 3/4.
    20. Albrecht, M., Scheiring, T., Sixt, T., & Kaim, Wolfgang. (2000). Structures and properties of complexes MCl(C5Me5)(N-S)(PF6), M = Rh, Ir, with N-S = 1-methyl-2-(alkylthiomethyl)-1H-benzimidazole ligands. Journal of Organometallic Chemistry, 596(1–2), Article 1–2. https://doi.org/10.1016/S0022-328X(99)00544-6
  22. 1999

    1. Kaim, W., Schwederski, B., Heilmann, O., & Hornung, F. M. (1999). Coordination compounds of pteridine, alloxazine and flavin ligands: Structures and properties. Coordination Chemistry Reviews, 182(1), Article 1. https://doi.org/10.1016/S0010-8545(98)00193-3
    2. Albrecht, M., Hubler, K., & Kaim, Wolfgang. (1999). Coordination of the hetero(N,S)-bidentate ligand 1-methyl-2-(methylthiomethyl)-1H-benzimidazole to (Ph3P)Au+ exclusively through the imine nitrogen donor. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 54(12), Article 12. https://doi.org/10.1515/znb-1999-1221
    3. Klein, A., Scheiring, T., & Kaim, Wolfgang. (1999). Molecular and crystal structure of an organoplatinum(II) complex with dipyrido3,2-a:2’,3’-cphenazine (dppz). Zeitschrift fuer Anorganische und Allgemeine Chemie, 625(7), Article 7. https://doi.org/10.1002/(SICI)1521-3749(199907)625:7\textless1177::AID-ZAAC1177\textgreater3.0.CO;2-1
    4. Rall, J., Wanner, M., Albrecht, M., Hornung, F. M., & Kaim, Wolfgang. (1999). Sensitive valence tautomer equilibrium of paramagnetic complexes (L)Cun+(Qn-) (n = 1 or 2; Q = quinones) related to amine oxidase enzymes. Chemistry - A European Journal, 5(10), Article 10. https://doi.org/10.1002/(SICI)1521-3765(19991001)5:10\textless2802::AID-CHEM2802\textgreater3.0.CO;2-5
    5. Heilmann, O., Hornung, F. M., Fiedler, J., & Kaim, Wolfgang. (1999). Organometallic iridium(III) and rhenium(I) complexes with lumazine, alloxazine and pterin derivatives. Journal of Organometallic Chemistry, 589(1), Article 1. https://doi.org/10.1016/S0022-328X(99)00294-6
    6. Albrecht, M., Hubler, K., Scheiring, T., & Kaim, Wolfgang. (1999). Copper(I) and copper(II) complexes of the bidentate imidazole/thioether ligand 1-methyl-2-(methylthiomethyl)-1H-benzimidazole. Inorganica Chimica Acta, 287(2), Article 2. https://doi.org/10.1016/S0020-1693(99)00018-3
    7. Glockle, M., & Kaim, Wolfgang. (1999). An exceedingly stable diiron(II,III) complex ion (tz)Fe(CN)525- with comproportionation constants between 108 (in H2O) and 1019 (in CH3CN). Angewandte Chemie, International Edition, 38(20), Article 20. https://doi.org/10.1002/(SICI)1521-3773(19991018)38:20\textless3072::AID-ANIE3072\textgreater3.0.CO;2-2
    8. Ketterle, M., Kaim, W., Olabe, J. A., Parise, A. R., & Fiedler, Jan. (1999). Widely differing stabilities of molecule-bridged cyanodiiron(III,II) species in non-aqueous solvents. Inorganica Chimica Acta, 291(1–2), Article 1–2. https://doi.org/10.1016/S0020-1693(99)00039-0
    9. Baumann, F., Dormann, E., Ehleiter, Y., Kaim, W., Karcher, J., Kelemen, M., Krammer, R., Saurenz, D., Stalke, D., Wachter, C., Wolmershauser, G., & Sitzmann, H. (1999). Structure and reactivity of paramagnetic cyclopentadienyl cobalt complexes with bulky alkyl substituents. Journal of Organometallic Chemistry, 587(2), Article 2. https://doi.org/10.1016/S0022-328X(99)00332-0
    10. Binder, H., Kellner, R., Vaas, K., Hein, M., Baumann, F., Wanner, M., Winter, R., Kaim, W., Honle, W., Grin, Y., Wedig, U., Schultheiss, M., Kremer, R. K., von Schnering, H. G., Groeger, O., & Engelhardt, G. (1999). The closo-cluster triad. B9X9, B9X9.bul.-, and B9X92- with tricapped trigonal prisms (X = Cl, Br, I). Synthesis, crystal and electronic structures. Zeitschrift fuer Anorganische und Allgemeine Chemie, 625(7), Article 7. https://doi.org/10.1002/(SICI)1521-3749(199907)625:7\textless1059::AID-ZAAC1059\textgreater3.0.CO;2-\#
    11. Barra, A.-L., Brunel, L.-C., Baumann, F., Schwach, M., Moscherosch, M., & Kaim, Wolfgang. (1999). High-frequency (245 GHz) and X-band EPR study of stable dicopper radical complexes. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry, 21, Article 21.
    12. Binder, H., Kellner, R., Vaas, K., Hein, M., Baumann, F., Wanner, M., Kaim, W., Wedig, U., Honle, W., von Schering, H. G., Groeger, O., & Engelhardt, G. (1999). HB9X9 and H2B9X9 (X = Cl, Br, I): Neutral closo-nonaboranes in the novel series BnHn+1 and BnHn+2 syntheses, ab initio calculations, and electronic structures. Zeitschrift fuer Anorganische und Allgemeine Chemie, 625(10), Article 10. https://doi.org/10.1002/(SICI)1521-3749(199910)625:10\textless1638::AID-ZAAC1638\textgreater3.0.CO;2-V
    13. Klein, A., Kasack, V., Reinhardt, R., Sixt, T., Scheiring, T., Zalis, S., Fiedler, J., & Kaim, Wolfgang. (1999). 2,5-Bis(1-phenyliminoethyl)pyrazine (bpip): A conjugated metal-metal bridging acceptor ligand and its homodinuclear complexes with low-valent metal centers. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry, 4, Article 4.
    14. Baumann, F., Kaim, W., Baraldo, L. M., Slep, L. D., Olabe, J. A., & Fiedler, Jan. (1999). Reduction of the NO+ ligand in the pentacyanonitrosylosmate(II) ion. Inorganica Chimica Acta, 285(1), Article 1. https://doi.org/10.1016/S0020-1693(98)00254-0
    15. Schwach, M., Hausen, H.-D., & Kaim, Wolfgang. (1999). The First Crystal Structure of a Metal-Stabilized Tetrazine Anion Radical: Formation of a Dicopper Complex through Self-Assembly in a Comproportionation Reaction. Inorganic Chemistry, 38(10), Article 10. https://doi.org/10.1021/IC9814625
    16. Wanner, M., Sixt, T., Klinkhammer, K.-W., & Kaim, Wolfgang. (1999). First Experimental Structure of a 1:1 Metal Complex with a PQQ Cofactor Derivative outside Dehydrogenase Enzymes. Inorganic Chemistry, 38(11), Article 11. https://doi.org/10.1021/IC981390H
    17. Kaim, W., Berger, S., Greulich, S., Reinhardt, R., & Fiedler, Jan. (1999). Electronic coupling of two Cp*ClM+/Cp*M reaction centers via p conjugated bridging ligands: Similarities and differences between rhodium and iridium analogues. Journal of Organometallic Chemistry, 582(2), Article 2. https://doi.org/10.1016/S0022-328X(98)01027-4
    18. Gloeckle, M., Kaim, W., Katz, N. E., Posse, M. G., Cutin, E. H., & Fiedler, Jan. (1999). The FeIII/FeII vs. Fe22.5 Formulation in Mixed-Valent Species (NC)4Fe(BL)Fe(CN)43-, BL = 2,2’-Bipyrimidine and 3,6-Bis(2-pyridyl)-1,2,4,5-tetrazine. Distance and Size Do Not Always Matter. Inorganic Chemistry, 38(14), Article 14. https://doi.org/10.1021/IC990249L
    19. Zalis, S., Stoll, H., Baerends, E. J., & Kaim, Wolfgang. (1999). The d0, d1, and d2 Configurations in Known and Unknown Tetrathiometal Compounds MS4n- (M = Mo, Tc, Ru; W, Re, Os). A Quantum Chemical Study. Inorganic Chemistry, 38(26), Article 26. https://doi.org/10.1021/ic990891f
    20. Wanner, M., Kaim, W., Lorenzen, V., & Preetz, Wilhelm. (1999). Hexaborate cluster radical anions B6HalnHal’6-n.bul.- and B6Hal5R.bul.- (Hal, Hal’ = Cl, Br, I; R = H, alkyl). Chemical or electrochemical generation, vibrational, UV-Vis and EPR spectroscopy. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 54(9), Article 9. https://doi.org/10.1515/znb-1999-0902
    21. Fees, J., Ketterle, M., Klein, A., Fiedler, J., & Kaim, Wolfgang. (1999). Electrochemical, spectroscopic and EPR study of transition metal complexes of dipyrido3,2-a:2’,3’-cphenazine. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry, 15, Article 15.
  23. 1998

    1. Stange, A. F., Sixt, T., & Kaim, Wolfgang. (1998). Highly dissymmetric chelate coordination of 3,4,7,8-tetramethyl-1,10-phenanthroline to CuI(SR). Chemical Communications (Cambridge, United Kingdom), 4, Article 4. https://doi.org/10.1039/a708867a
    2. Pfitzner, A., Baumann, F., & Kaim, Wolfgang. (1998). TeS2·- radical anions in CuBrCu1.2TeS2. Angewandte Chemie, International Edition, 37(13/14), Article 13/14. https://doi.org/10.1002/(SICI)1521-3773(19980803)37:13/14\textless1955::AID-ANIE1955\textgreater3.0.CO;2-C
    3. Kaim, W., Klein, A., Hasenzahl, S., Stoll, H., Zalis, S., & Fiedler, Jan. (1998). Reactions of New Organoplatinum(II) and -(IV) Complexes of 1,4-Diaza-1,3-butadienes with Light and Electrons. Emission vs Photochemistry and the Electronic Structures of Ground, Reduced, Oxidized, and Low-Lying Charge-Transfer Excited States. Organometallics, 17(2), Article 2. https://doi.org/10.1021/OM970736D
    4. Vlcek, JR., A., Baumann, F., Kaim, W., Grevels, F.-W., & Hartl, Frantisek. (1998). Electron distribution in the Cr(CO)4(bpy).bul.- (bpy = 2,2’-bipyridine) radical anion as revealed by EPR spectroscopy and IR spectroelectrochemistry of 13CO-enriched species. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry, 2, Article 2.
    5. Baumann, F., Stange, A., & Kaim, Wolfgang. (1998). Interaction of two equivalent electron transfer/atom transfer centers via 2,2’-bipyrimidine as bridging ligand. Inorganic Chemistry Communications, 1(8), Article 8. https://doi.org/10.1016/S1387-7003(98)00082-3
    6. Gloeckle, M., Kaim, W., & Fiedler, Jan. (1998). Valence Delocalization despite Weak Metal-Metal Coupling in a Bis(organoosmium(III,II)) Complex with a Pyrazine Bridge. Organometallics, 17(23), Article 23. https://doi.org/10.1021/OM980586M
    7. Baumann, F., Kaim, W., Posse, M. G., & Katz, N. E. (1998). Spectroelectrochemistry of the Multistep Redox System (μ-bpym)Ru(NH3)42n+, n = 2-6, in a Nonaqueous Medium. Inorganic Chemistry, 37(4), Article 4. https://doi.org/10.1021/IC971143Y
    8. Doslik, N., Sixt, T., & Kaim, Wolfgang. (1998). The first structural characterization of an azoaromatic radical anion stabilized by dicopper(I) coordination. Angewandte Chemie, International Edition, 37(17), Article 17. https://doi.org/10.1002/(SICI)1521-3773(19980918)37:17\textless2403::AID-ANIE2403\textgreater3.0.CO;2-J
    9. Kaim, W., Hornung, F. M., Schaefer, R., Schwederski, B., & Fiedler, Jan. (1998). Di- and trinuclear complexes of WS42- with tricarbonylrhenium(I) and -manganese(I) fragments. Structure, spectroscopy, and electrochemistry. Zeitschrift fuer Anorganische und Allgemeine Chemie, 624(7), Article 7.
    10. Hosmane, N. S., Demissie, T., Zhang, H., Maguire, J. A., Lipscomb, W. N., Baumann, F., & Kaim, Wolfgang. (1998). Synthesis and Crystal Structure of the First Polymeric Cesium Compound of a Carborane Ligand System. Organometallics, 17(3), Article 3. https://doi.org/10.1021/OM970938
    11. Sixt, T., Hornung, F. M., Ehlend, A., & Kaim, Wolfgang. (Hrsg.). (1998). Products from multiple insertion reactions between diisocyanates and antiheteroaromatic 1,4-bis(trimethylsilyl)-1,4-dihydropyrazine: Organosilicon Chem. III, Muench. Silicontage, 3rd. Wiley-VCH Verlag GmbH.
    12. Rall, J., Stange, A. F., Hubler, K., & Kaim, Wolfgang. (1998). A coordination-induced 1,4 $\rightarrow$ 1,2-quinonediimine isomerization. Angewandte Chemie, International Edition, 37(19), Article 19. https://doi.org/10.1002/(SICI)1521-3773(19981016)37:19\textless2681::AID-ANIE2681\textgreater3.0.CO;2-9
    13. Lorenzen, V., Preetz, W., Baumann, F., & Kaim, Wolfgang. (1998). Paramagnetic Cluster Ions B6HalnHal’6-n.bul.- (Hal, Hal’ = Cl, Br, I). EPR Evidence for Radical Stabilization through Electronic Effects of the Halogen Substituents. Inorganic Chemistry, 37(16), Article 16. https://doi.org/10.1021/IC9802698
    14. Hornung, F. M., Baumann, F., Kaim, W., Olabe, J. A., Slep, L. D., & Fiedler, Jan. (1998). Spectroelectrochemical Characterization of the Two-Step Redox System (μ-pz)Os(CN)52n- (n = 4, 5, 6; pz = Pyrazine). Similarities and Differences in Relation to the Creutz-Taube System. Inorganic Chemistry, 37(2), Article 2. https://doi.org/10.1021/IC970804O
    15. Klein, A., Hasenzahl, S., Kaim, W., & Fiedler, Jan. (1998). On the Question of Mixed-Valent States in Ligand-Bridged Dinuclear Organoplatinum Compounds RkPt(m-L)PtRkn, k = 2 or 4. Organometallics, 17(16), Article 16. https://doi.org/10.1021/OM980107J
    16. Kaim, W., Hornung, F. M., Schafer, R., Fiedler, J., Krejcik, M., & Zalis, S. (1998). Charge transfer phenomena in transition metal sulfur chemistry. NATO ASI Series, Series 3: High Technology, 60(Transition Metal Sulphides), Article Transition Metal Sulphides.
    17. Hornung, F. M., Baumann, F., Kaim, W., Olabe, J. A., Slep, L. D., & Fiedler, Jan. (1998). Spectroelectrochemical Characterization of the Two-Step Redox System (μ-pz)Os(CN)52n- (n = 4, 5, 6; pz = Pyrazine). Similarities and Differences in Relation to the Creutz-Taube System. Erratum to document cited in CA128:56656. Inorganic Chemistry, 37(20), Article 20. https://doi.org/10.1021/IC980783D
    18. Berger, S., Klein, A., Kaim, W., & Fiedler, Jan. (1998). Variable Reduction Sequences for Axial (L) and Chelate Ligands (N$\cap$N) in Rhenium(I) Complexes (N$\cap$N)Re(CO)3(L)n. Inorganic Chemistry, 37(21), Article 21. https://doi.org/10.1021/IC980268F
    19. Ketterle, M., Kaim, W., & Fiedler, Jan. (1998). Valence delocalization in a strongly coupled (Kc = 1014) molecule-bridged cyanodiiron(III,II) species. Chemical Communications (Cambridge, United Kingdom), 16, Article 16. https://doi.org/10.1039/a804279i
    20. Hornung, F. M., Klinkhammer, K. W., & Kaim, Wolfgang. (1998). New sulfide-bridged heterocubanes MVI(S)ReI3(CO)9(m3-S)4-, M = Mo or W, with transition metals in very different oxidation states. Chemical Communications (Cambridge, United Kingdom), 18, Article 18. https://doi.org/10.1039/a805295f
  24. 1997

    1. Klein, A., Hasenzahl, S., & Kaim, Wolfgang. (1997). EPR study of electron transfer and group transfer in organoplatinum(II) and (IV) compounds. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 12, Article 12.
    2. Baumann, F., Livoreil, A., Kaim, W., & Sauvage, J.-Pierre. (1997). Changeover in a multimodal copper(II) catenate as monitored by EPR spectroscopy. Chemical Communications (Cambridge, United Kingdom), 1, Article 1. https://doi.org/10.1039/a606282b
    3. Rall, J., Waldhor, E., Schwederski, B., Schwach, M., Kohlmann, S., & Kaim, Wolfgang. (Hrsg.). (1997). Synthetic and spectroscopic approaches to the copper/quinone-coupled center in amine oxidases: Bioinorg. Chem. Wiley-VCH Verlag GmbH.
    4. Titze, C., Kaim, W., & Zalis, Stanislav. (1997). Structural Flexibility of the Hydrogen-Free Acceptor Ligand Octachloro-1,10-phenanthroline in Its Complexes with d10 Metal Ions. Inorganic Chemistry, 36(12), Article 12. https://doi.org/10.1021/IC960837O
    5. Wiberg, N., Amelunxen, K., Noth, H., Schwenk, H., Kaim, W., Klein, A., & Scheiring, Thomas. (1997). Compounds of silicon. 113. Sterically overloaded supersilyl compounds. 12. Tris(tri-tert-butylsilyl)digallanyl (tBu3Si)3Ga2: A new type of compound for a heavy Group 13 element. Angewandte Chemie, International Edition in English, 36(11), Article 11. https://doi.org/10.1002/anie.199712131
    6. Hosmane, N. S., Wang, Y., Zhang, H., Lu, K.-J., Maguire, J. A., Gray, T. G., Brooks, K. A., Waldhoer, E., Kaim, W., & Kremer, R. K. (1997). Chemistry of C-Trimethylsilyl-Substituted Heterocarboranes. 21. Syntheses, Structures, EPR Spectra, and Reactivities of Bent-Sandwich and Half-Sandwich Titanacarboranes. Full Analysis of Spin-Spin Coupling in Two Structurally Characterized Titanium(III)-Carborane Dimers. Organometallics, 16(7), Article 7. https://doi.org/10.1021/OM960890K
    7. Waldhoer, E., Kaim, W., Olabe, J. A., Slep, L. D., & Fiedler, Jan. (1997). The mpz+/mpz.bul. pair as organic analog of the NO+/NO.bul. ligand redox system (mpz = N-methylpyrazinium). A combined electrochemical and spectroscopic study (UV/Vis/NIR, IR, EPR) of complexes (mpz)M(CN)52-/3- (M = Fe, Ru, Os). Inorganic Chemistry, 36(14), Article 14. https://doi.org/10.1021/IC961426A
    8. Sitzmann, H., Dezember, T., Kaim, W., Baumann, F., Stalke, D., Kaercher, J., Dormann, E., Winter, H., wachter, C., & Kelemen, Marc. (1997). High-spin cyclopentadienyl complexes. 1. Synthesis and characterization of the stable dicarbonyl(cyclopentadienyl)iron radical (C5R5)Fe(CO)2 (R = CHMe2). Angewandte Chemie, International Edition in English, 35(23/24), Article 23/24. https://doi.org/10.1002/anie.199628721
    9. Scheiring, T., Klein, A., & Kaim, Wolfgang. (1997). EPR study of paramagnetic rhenium(I) complexes (bpy.-)Re(CO)3X relevant to the mechanism of electrocatalytic CO2 reduction. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 12, Article 12.
    10. Kaim, W., Reinhardt, R., & Fiedler, Jan. (1997). Ligand-mediated coupling of organometallic reaction centers. Angewandte Chemie, International Edition in English, 36(22), Article 22. https://doi.org/10.1002/anie.199724931
    11. Baumann, F., Kaim, W., Olabe, J. A., Parise, A. R., & Jordanov, Jeanne. (1997). Tetranuclear osmium complexes of tetracyanoquinodimethane TCNQ, 2,2’-(cyclohexa-2,5-diene-1,4-diylidene)bis(propane-1,3-dinitrile) and 1,2,4,5-tetracyanobenzene (TCNB). Synthesis, spectroelectrochemistry and magnetism. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry, 22, Article 22.
    12. Klein, A., Kaim, W., Hornung, F. M., Fiedler, J., & Zalis, Stanislav. (1997). Electronic and molecular structure of 2,2’-bipyrimidine-bridged bis(organoplatinum) complexes in various oxidation states. Radical-bridged diplatinum species and the absence of a Pt(III)/Pt(II) mixed-valent intermediate. Inorganica Chimica Acta, 264(1–2), Article 1–2. https://doi.org/10.1016/S0020-1693(97)05704-6
    13. Waldhoer, E., Kaim, W., Lawson, M., & Jordanov, Jeanne. (1997). Paramagnetism of Tetranuclear Complexes between TCNX Ligands (TCNE, TCNQ, TCNB) and Four Pentaammineruthenium or Dicarbonyl(pentamethylcyclopentadienyl)manganese Fragments. Inorganic Chemistry, 36(15), Article 15. https://doi.org/10.1021/IC960998S
  25. 1996

    1. Haaland, A., Martinsen, K.-G., Volden, H. V., Kaim, W., Waldhoer, E., Uhl, W., & Schuetz, Uwe. (1996). Gas-Phase Structure of the Monomeric Alkylgallium(I) Compound GaC(SiMe3)3 and the Electrochemical Behavior of Ga4C(SiMe3)34 and In4C(SiMe3)34 with EPR Evidence for a Ga4R4 Radical Anion. Organometallics, 15(4), Article 4. https://doi.org/10.1021/OM950755S
    2. Schwach, M., Hausen, H.-D., & Kaim, Wolfgang. (1996). Pulled molecular strings and stacked molecular decks: Chelate-ring formation vs. metal-metal bridging in dicopper(I) complexes of 2,2’-bipyrimidine with diphosphine ligands of variable polymethylene chain length. Chemistry - A European Journal, 2(4), Article 4. https://doi.org/10.1002/chem.19960020414
    3. Baumann, F., Heilmann, M., Matheis, W., Schulz, A., Kaim, W., & Jordanov, Jeanne. (1996). Ground state electron transfer between TCNE and one or more 16-electron species containing vanadium, osmium, ruthenium or cobalt. Inorganica Chimica Acta, 251(1–2), Article 1–2. https://doi.org/10.1016/S0020-1693(96)05276-0
    4. Fiedler, J., Zalis, S., Klein, A., Hornung, F., & Kaim, Wolfgang. (1996). Electronic Structure of p-Conjugated Redox Systems with Borane/Borataalkene End Groups. Inorganic Chemistry, 35(10), Article 10. https://doi.org/10.1021/IC951482W
    5. Hosmane, N. S., Kaim, W., Wang, Y., Lu, K.-J., Thomas, C. J., Ezhova, M., Helfert, S. C., Collins, J. D., Maguire, J. A., & Gray, T. G. (1996). Electron-Acceptor Behavior of 2,4,7,9-Tetracarba-nido-dodecaborane(12) with Group 1 and Group 2 Metals: Syntheses and Crystal Structures of (THF)4Li(SiMe3)4C4B8H9 and (THF)2Mg(SiMe3)4C4B8H8. Organometallics, 15(10), Article 10. https://doi.org/10.1021/OM9509249
    6. Kaim, W., Reinhardt, R., Waldhoer, E., & Fiedler, Jan. (1996). Electron transfer and chloride ligand dissociation in complexes (C5Me5)ClM(bpy)+/(C5Me5)M(bpy)n (M = Co, Rh, Ir; n = 2+, +, 0, -): A combined electrochemical and spectroscopic investigation. Journal of Organometallic Chemistry, 524(1–2), Article 1–2. https://doi.org/10.1016/S0022-328X(96)06426-1
    7. Binder, H., Riegel, B., Heckmann, G., Moscherosch, M., Kaim, W., von Schnering, H.-G., Hoenle, W., Flad, H.-J., & Savin, Andreas. (1996). Generation and Characterization of Diphosphene and Triphosphene Radical Anions. Computational Studies on the Structure and Stability of P3H3·-. Inorganic Chemistry, 35(7), Article 7. https://doi.org/10.1021/IC950661A
    8. Hilgers, F., Bruns, W., Fiedler, J., & Kaim, Wolfgang. (1996). UV-visible, IR and EPR spectroelectrochemical study of the EC redox transition (PR3)n(CO)3(R’-pz)M+·; M = Mo, W; R’-pz = N-alkylpyrazinium; R = isopropyl, cyclohexyl; n = 1 or 2. Journal of Organometallic Chemistry, 511(1–2), Article 1–2. https://doi.org/10.1016/0022-328X(95)05933-G
    9. Heilmann, O., Hornung, F. M., Kaim, W., & Fiedler, Jan. (1996). Structure, EPR and UV-VIS and IR spectroelectrochemistry of reversibly reducible compounds (C5Me5)IrCl(L)(PF6), L= 1,3-dimethyllumazine or 1,3-dimethylalloxazine. Journal of the Chemical Society, Faraday Transactions, 92(21), Article 21. https://doi.org/10.1039/FT9969204233
    10. Stange, A. F., Klinkhammer, K. W., & Kaim, Wolfgang. (1996). A Tetragonal Bisphenoidal Tetracopper(I) Arrangement Supported by a Potentially Tridentate Ligand Containing Thiolate, Secondary Amine, and 2-Pyridine Functions: Hydrogen-Bonded Instead of Cu(I)-Coordinated Pyridine Rings in an S4-Symmetric Compound. Inorganic Chemistry, 35(13), Article 13. https://doi.org/10.1021/IC951629J
    11. Greulich, S., Kaim, W., Stange, A. F., Stoll, H., Fiedler, J., & Zalis, Stanislav. (1996). CpIr(dab) (dab = 1,4-Bis(2,6-dimethylphenyl)-1,4-diazabutadiene): A Coordinatively Unsaturated Six-p-Electron Metallaheteroaromatic Compound? Inorganic Chemistry, 35(13), Article 13. https://doi.org/10.1021/IC9514814
    12. Kaim, W., & Rall, Jochen. (1996). Copper - A \dqmodern\dq bioelement. Angewandte Chemie, International Edition in English, 35(1), Article 1. https://doi.org/10.1002/anie.199600431
    13. Stange, A. F., & Kaim, Wolfgang. (1996). Bis(homoleptic) vs. heteroleptic copper(I) complexes: Electrosynthesis, spectroscopy, and crystal structure of Cu(BIK)2+2Cu4(SR)62-·3(CH3CN)·(RSH); BIK = bis(2-methylimidazol-2-yl)ketone, R = o-tolyl. Zeitschrift fuer Anorganische und Allgemeine Chemie, 622(7), Article 7. https://doi.org/10.1002/zaac.19966220703
    14. Kaim, Wolfgang. (1996). Transition Metal Chemistry by M. Gerloch and E. C. Constable. Angewandte Chemie, International Edition in English, 35(2), Article 2. https://doi.org/10.1002/anie.199602231
    15. Heilmann, M., Baumann, F., Kaim, W., & Fiedler, Jan. (1996). Configuration-dependent electron hopping between equivalent ligands in isomeric ruthenium(II) complexes. Journal of the Chemical Society, Faraday Transactions, 92(21), Article 21. https://doi.org/10.1039/ft9969204227
    16. Klein, A., Vogler, C., & Kaim, Wolfgang. (1996). The d in 18 + d Electron Complexes: Importance of the Metal/Ligand Interface for the Substitutional Reactivity of \dqRe(0)\dq Complexes (a-diimine-)ReI(CO)3(X). Organometallics, 15(1), Article 1. https://doi.org/10.1021/OM950500E
    17. Kaim, W., & Schwedrski, Brigette. (1996). Bioinorganic Chemistry: Inorganic Elements in the Chemistry of Life  Erratum for J. Am. Chem. Soc. 1995, 117, 11618. Journal of the American Chemical Society, 118(43), Article 43. https://doi.org/10.1021/JA965440Y
    18. Titze, C., & Kaim, Wolfgang. (1996). Polychlorinated biaryl heterocycles as potential ligands. Reactions between octachloro-1,10-phenanthroline and -2,2’-bipyridine with copper(I) and other metal ions. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 51(7), Article 7. https://doi.org/10.1515/znb-1996-0713
    19. Waldhoer, E., Zulu, M. M., Zalis, S., & Kaim, Wolfgang. (1996). Coordination-induced switch between the singly occupied and the lowest unoccupied molecular orbitals in two methylviologen-derived chromophores. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 6, Article 6.
    20. Ernst, S., Vogler, C., Klein, A., Kaim, W., & Zalis, Stanislav. (1996). The p* Molecular Orbital Crossing a2(q)/b1(y) in 1,10-Phenanthroline Derivatives. Ab Initio Calculations and EPR/ENDOR Studies of the 4,7-Diaza-1,10-phenanthroline Radical Anion and Its M(CO)4 Complexes (M = Cr, Mo, W). Inorganic Chemistry, 35(5), Article 5. https://doi.org/10.1021/IC950892H
  26. 1995

    1. Bertagnolli, H., & Kaim, Wolfgang. (1995). The dinuclear CuA center in cytochrome c oxidase and N2O reductase. A metal-metal bond in biology? Angewandte Chemie, International Edition in English, 34(7), Article 7. https://doi.org/10.1002/anie.199507711
    2. Lichtblau, A., Ehlend, A., Hausen, H.-D., & Kaim, Wolfgang. (1995). N,N’-Disilylated 1,4-dihydropyrazines: Organosilyl substitution reactions, structural effects of steric hindrance, and electron exchange with C60. Chemische Berichte, 128(8), Article 8. https://doi.org/10.1002/cber.19951280802
    3. Klein, A., Kaim, W., Waldhoer, E., & Hausen, H.-Dieter. (1995). Different orbital occupation by an added single electron in 1,10-phenanthroline and its 3,4,7,8-tetramethyl derivative. Evidence from electron paramagnetic resonance spectroscopy of the anion radicals and of their dimesitylplatinum(II) complexes. X-ray molecular structure of dimesityl(1,10-phenanthroline)platinum(II). Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 12, Article 12.
    4. Uhl, W., Schuetz, U., Kaim, W., & Waldhoer, Eberhard. (1995). Tetraalkyldigallane radical anions R2Ga.bul.-GaR2- R = CH(SiMe3)2 with long one-electron p-bond. Journal of Organometallic Chemistry, 501(1–2), Article 1–2.
    5. Kaim, W., & Fees, Joerg. (1995). The new tetrafunctional p acceptor ligand 3,6-bis(2’-pyrimidyl)-1,2,4,5-tetrazine (bmtz): Diruthenium complexes of bmtz and its 1,4-dihydro form. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 50(1), Article 1. https://doi.org/10.1515/znb-1995-0123
    6. Bruns, W., Kaim, W., Waldhoer, E., & Krejcik, Michael. (1995). Electronic Structure of the 16 Valence Electron Fragments M(CO)3(PR3)2 (M = Mo, W; R = iPr, Cy) in Their Complexes with H2, THF, and Three p-Conjugated Dinucleating Ligands: Electrochemistry and Spectroscopy of Different Oxidation States. Inorganic Chemistry, 34(3), Article 3. https://doi.org/10.1021/ic00107a021
    7. Fees, J., Hausen, H.-D., & Kaim, Wolfgang. (1995). Molecular and crystal structures of two mononuclear ruthenium(II) complexes with the strongly p accepting ligand 2,2’-azobis(pyridine) (abpy): mer-Ru(abpy)3(PF6)2 and Ru(abpy)2Cl2 (ctc isomer). Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 50(1), Article 1. https://doi.org/10.1515/znb-1995-0104
    8. Stange, A. F., Waldhoer, E., Moscherosch, M., & Kaim, Wolfgang. (1995). Variable structure of the Cu2S2 core in doubly thiolate-bridged dicopper(I) complexes. An x-ray crystallographic, electrochemical and EPR study of (dmp)2(o-CH3C6H4S)2Cu2, dmp = 2,9-dimethyl-1,10-phenanthroline, and a comment on the nature of phenanthroline-containing \dqCu(0)\dq complexes. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 50(1), Article 1. https://doi.org/10.1515/znb-1995-0122
    9. Armstrong, F. A., Kaim, W., & Schwederski, B. (1995). Bioinorganic Chemistry: Inorganic Chemistry in the Chemistry of Life. Natural Product Reports, 12(6), Article 6.
    10. Hasenzahl, S., Hausen, H.-D., & Kaim, Wolfgang. (1995). A tale of two complexes, PtMen(RN=CHCH=NR) (n = 2 and n = 4, R = cyclohexyl): Why do PtII and PtIV complexes exhibit virtually identical redox behavior and colors? Chemistry - A European Journal, 1(1), Article 1. https://doi.org/10.1002/chem.19950010114
    11. Ehlend, A., Hausen, H.-D., Kaim, W., Lichtblau, A., & Schwarz, Wolfgang. (1995). Insertion of CO2, COS and CS2 into the N-Si bond of extremely electron-rich 1,4-bis(trimethylsilyl)-1,4-dihydropyrazine and formation of a new poly(N,S) heterocyclic system by multiple cycloaddition. Journal of Organometallic Chemistry, 501(1–2), Article 1–2. https://doi.org/10.1016/0022-328X(95)05673-D
    12. Hosmane, N. S., Wang, Y., Zhang, H., Oki, A. R., Maguire, J. A., Waldhoer, E., Kaim, W., Binder, H., & Kremer, R. K. (1995). A Systematic Synthetic Approach to a Novel, Mixed 2,3-C2B4- and 2,4-C2B4-Erbium(III) Carborane Bent-Sandwich Complex. Organometallics, 14(3), Article 3. https://doi.org/10.1021/om00003a009
    13. Waldhoer, E., Poppe, J., Kaim, W., Cutin, E. H., Garcia Posse, M. E., & Katz, N. E. (1995). EPR Evidence for Low-Lying MLCT States in Tetracyanoiron and -ruthenium Complexes with Strongly p-Accepting Chelate Ligands. Comparison with Isoelectronic Tetracarbonylmetal Species. Inorganic Chemistry, 34(11), Article 11. https://doi.org/10.1021/ic00115a042
    14. Kasack, V., Kaim, W., Binder, H., Jordanov, J., & Roth, Eberhard. (1995). When Is an Odd-Electron Dinuclear Complex a Mixed-Valent Species? Tuning of Ligand-to-Metal Spin Shifts in Diruthenium(III,II) Complexes of Noninnocent Bridging Ligands OC(R)NNC(R)O. Inorganic Chemistry, 34(7), Article 7. https://doi.org/10.1021/ic00111a045
    15. Kaim, W., Bruns, W., Kohlmann, S., & Krejcik, Michael. (1995). Metal-metal interaction in ligand-bridged dimolybdenum(0,0) and -(I,0) complexes with very small frontier orbital gaps: Electrochemistry and spectroscopic properties of three neighboring oxidation states. Inorganica Chimica Acta, 229(1–2), Article 1–2. https://doi.org/10.1016/0020-1693(94)04239-R
    16. Moscherosch, M., Waldhoer, E., Binder, H., Kaim, W., & Fiedler, Jan. (1995). Tetranuclear Pentaammineruthenium Complexes Bridged by p-Conjugated Tetracyano Ligands Related to TCNE: Syntheses and Spectroscopy of Different Oxidation States. Inorganic Chemistry, 34(17), Article 17. https://doi.org/10.1021/ic00121a010
    17. Stahl, T., Kasack, V., & Kaim, Wolfgang. (1995). Conformational equilibria of 2,5-bis1-(phenylimino)ethylpyrazine anion radical (bpip·-). An electron paramagnetic resonance/electron-nuclear double resonance study of bpip·-, (bpip·-)(RMg+)2, and of the related anion radical of N-tert-butylpyridine-2-carbaldimine (But-pyca). Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 12, Article 12.
    18. Klein, A., & Kaim, Wolfgang. (1995). Axial Shielding of 5d8 and 5d7 Metal Centers in Dimesitylplatinum Complexes with Unsaturated Chelate Ligands: Spectroscopic and Spectroelectrochemical Studies of Four Different Oxidation States. Organometallics, 14(3), Article 3. https://doi.org/10.1021/om00003a019
  27. 1994

    1. Hasenzahl, S., Kaim, W., & Stahl, Thomas. (1994). Charge and electron transfer from metal-to-carbon bonds of Main Group organometallics MRn (M = Al, Ga, Zn) to aromatic N-heterocycles: Colored precursor compounds and radical complex formation. Inorganica Chimica Acta, 225(1–2), Article 1–2. https://doi.org/10.1016/0020-1693(94)04025-7
    2. Hilgers, F., Kaim, W., Schulz, A., & Zalis, Stanislav. (1994). Electronic absorption spectroscopy of some exceptionally stable 1,4-dialkyl-1,4-dihydro-1,4-diazinium radical cations: Assignment of transitions, vibrational structure and effects of p-p dimerization. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 1, Article 1.
    3. Hosmane, N. S., Wang, Y., Zhang, H., Maguire, J. A., Waldhoer, E., Kaim, W., Binder, H., & Kremer, R. K. (1994). Novel Bent-Sandwich Titanium(III) and Titanium(IV) Organometallics. Organometallics, 13(11), Article 11. https://doi.org/10.1021/om00023a012
    4. Matheis, W., Poppe, J., Kaim, W., & Zalis, Stanislav. (1994). Diquaternized heterocycles with strong electronic coupling between a metal-chelating site and a methylviologen-type redox function: EPR/ENDOR detected coordination of metal ions and complexes by radical cation intermediates. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 9, Article 9.
    5. Heilmann, O., Hausen, H. D., & Kaim, Wolfgang. (1994). Organometallic rhodium(III) and -(I) complexes with 1,3-dimethyllumazine (DML). The crystal structure of (h2-(O4,N5)-DML)(h5-C5Me5)ClRh(PF6). Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 49(11), Article 11. https://doi.org/10.1515/znb-1994-1117
    6. Kaim, W., & Moscherosch, Michael. (1994). The coordination chemistry of TCNE, TCNQ and related polynitrile p acceptors. Coordination Chemistry Reviews, 129(1–2), Article 1–2. https://doi.org/10.1016/0010-8545(94)85020-8
    7. Kaim, W., Reinhardt, R., & Sieger, Monika. (1994). Chemical and Electrochemical Generation of Hydride-Forming Catalytic Intermediates (bpy)M(CnRn): M = Rh, Ir (n = 5); M = Ru, Os (n = 6). Coordinatively Unsaturated Ground State Models of MLCT Excited States? Inorganic Chemistry, 33(20), Article 20. https://doi.org/10.1021/ic00098a009
    8. Kaim, Wolfgang. (1994). Thermal and light induced electron transfer reactions of Main Group metal hydrides and organometallics. Topics in Current Chemistry, 169(Electron Transfer I), Article Electron Transfer I.
  28. 1993

    1. Moscherosch, M., & Kaim, Wolfgang. (1993). A first robust complex of tetradentate TCNQ. Evidence for two weakly coupled diruthenium(II,III) subsystems in symmetrical tetranuclear complexes (μ4-TCNX)Ru(NH3)548+ (TCNX = TCNE, TCNQ). Inorganica Chimica Acta, 206(2), Article 2. https://doi.org/10.1016/S0020-1693(00)82872-8
    2. Kaim, W., Lichtblau, A., & Hausen, H.-Dieter. (1993). Correlation between structure and electron transfer in organometallic model compound for flavin with \dqButterfly\dq conformation. Journal of Organometallic Chemistry, 456(2), Article 2.
    3. Krejcik, M., Zalis, S., Klima, J., Sykora, D., Matheis, W., Klein, A., & Kaim, Wolfgang. (1993). 2,2’-Azobis(pyridine) (abpy) as a multiply reducible tetradentate ligand. EPR evidence for the configurational dependence of intramolecular electron transfer in the stereoisomeric tris-chelate ruthenium complexes Ru(abpy)n(bpy)3-nm (n = 2, 3; m = 2+ to 3-). Inorganic Chemistry, 32(15), Article 15. https://doi.org/10.1021/ic00067a029
    4. Sitzmann, H., Bock, H., Boese, R., Dezember, T., Havlas, Z., Kaim, W., Moscherosch, M., & Zanathy, L. (1993). Pentaisopropylcyclopentadienyl: Singlet anion, doublet radical, and triplet cation of a carbocyclic p system. Journal of the American Chemical Society, 115(25), Article 25. https://doi.org/10.1021/ja00078a043
    5. Poppe, J., Moscherosch, M., & Kaim, Wolfgang. (1993). An unusually weak intervalence transition in a very stable bis chelate analog of the ruthenium mixed-valent Creutz-Taube ion. UV/visible/near-IR and EPR spectroelectrochemistry of (NH3)4Ru(m-bptz)Ru(NH3)4n+ (bptz = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine; n = 3 - 5). Inorganic Chemistry, 32(12), Article 12. https://doi.org/10.1021/ic00064a012
    6. Reinhardt, R., & Kaim, Wolfgang. (1993). Complexes of a-diimines with pentamethylcyclopentadienylrhodium in different oxidation states. Zeitschrift fuer Anorganische und Allgemeine Chemie, 619(12), Article 12.
    7. Hausen, H. D., Kaim, W., Schulz, A., Moscherosch, M., & Jordanov, Jeanne. (1993). First evidence for p-p dimerization of stable 1,4-dialkylquinoxalinium radical cations. Structure, spectroscopy, and magnetism. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 48(9), Article 9. https://doi.org/10.1515/znb-1993-0905
    8. Bruns, W., Hausen, H.-D., Kaim, W., & Schulz, Andreas. (1993). Tungsten(0) complexes of p-acids N-methylpyrazinium cations and of N-methylpyrazinium radicals. Crystal and molecular structure of (C4H4N2-Me)W(CO)3(PCy3)2(PF6), Cy = cyclohexyl. Journal of Organometallic Chemistry, 444(1–2), Article 1–2.
    9. Waldhoer, E., Schwederski, B., & Kaim, Wolfgang. (1993). Ruthenium(II) coordination to a model for the topasemiquinone cofactor of amine oxidases. Resolution of 1H and 99,101Ru EPR hyperfine structure. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 11, Article 11.
    10. Poppe, J., Kaim, W., Ben Altabef, A., & Katz, N. E. (1993). EPR characteristics of radical complexes with coordinated ammineruthenium(II) fragments. Evidence for the metal-to-ligand charge transfer (MLCT) nature of the low-lying excited states in precursor complexes. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 11, Article 11.
    11. Hausen, H. D., Schulz, A., & Kaim, Wolfgang. (1993). Flavosemiquinone model systems. Part 3. Molecular and crystal structure of the cation radical salt 1,4,6,7-tetramethylquinoxalinium triiodide. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 3, Article 3.
    12. Uhl, W., Vester, A., Kaim, W., & Poppe, Juergen. (1993). Dialane radical anions R2Al-AlR2·-. Journal of Organometallic Chemistry, 454(1–2), Article 1–2.
    13. Vogler, C., Kaim, W., & Hausen, H. D. (1993). Dinuclear bis(phosphine)copper(I) complexes with 2,2’-bipyrimidine as bridging ligand: Structural analogy to \dqblue\dq copper centers and reduction to paramagnetic species. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 48(11), Article 11. https://doi.org/10.1515/znb-1993-1104
    14. Lichtblau, A., Hausen, H. D., & Kaim, Wolfgang. (1993). First structural characterization of an easily oxidized derivative of 1,4-dihydroquinoxaline. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 48(6), Article 6. https://doi.org/10.1515/znb-1993-0603
    15. Fees, J., Kaim, W., Moscherosch, M., Matheis, W., Klima, J., Krejcik, M., & Zalis, Stanislav. (1993). Electronic structure of the \dqmolecular light switch\dq bis(bipyridine)dipyrido3,2-a:2’,3’-cphenazineruthenium(2+). Cyclic voltammetric, UV/visible and EPR/ENDOR study of multiply reduced complexes and ligands. Inorganic Chemistry, 32(2), Article 2. https://doi.org/10.1021/ic00054a009
    16. Kaim, W., Bruns, W., Poppe, J., & Kasack, Volker. (1993). Spectroscopy of mixed valent states in dinuclear ions and metalloproteins. Journal of Molecular Structure, 292, 221--228. https://doi.org/10.1016/0022-2860(93)80102-2
    17. Schaefer, R., Fiedler, J., Moscherosch, M., & Kaim, Wolfgang. (1993). First characterization of a tetrathiomolybdate(V) derivative by EPR, UV-VIS and IR spectroelectrochemistry. Journal of the Chemical Society, Chemical Communications, 11, Article 11. https://doi.org/10.1039/C39930000896
    18. Moscherosch, M., Field, J. S., Kaim, W., Kohlmann, S., & Krejcik, Michael. (1993). „Inverse cryptate“ structure of an exceptionally stable dicopper(I) semiquinonoid intermediate. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry, 2, Article 2.
    19. Hosmane, N. S., Wang, Y., Zhang, H., Maguire, J. A., Waldhoer, E., & Kaim, Wolfgang. (1993). Synthesis and crystal structure of a novel, TMEDA-stabilized closo-cobalt(II) carborane: An intermediate for anionic, commo-cobalt(III) carborane complexes. Organometallics, 12(10), Article 10. https://doi.org/10.1021/om00034a001
    20. Kaim, W., Schulz, A., Hilgers, F., Hausen, H. D., Moscherosch, M., Lichtblau, A., Jordanov, J., & Roth, E. (1993). Structure, spectroscopy and magnetism of 1,4-dihydro-1,4-diazine radical cations: Exceptionally stable intermediates related to methylviologen and flavosemiquinone radicals. Research on Chemical Intermediates, 19(7), Article 7. https://doi.org/10.1163/156856793X00253
    21. Kaim, W., Moscherosch, M., Kohlmann, S., Field, J. S., & Fenske, D. (1993). Unusual stabilization of anion radicals by copper(I). Special Publication - Royal Society of Chemistry, 131(Chemistry of the Copper and Zinc Triads), Article Chemistry of the Copper and Zinc Triads.
    22. Bruns, W., Kaim, W., Waldhoer, E., & Krejcik, Michael. (1993). Spectroelectrochemical characterization of a pyrazine-bridged mixed-valent (4d5/4d6) organometallic analog of the Creutz-Taube ion. Journal of the Chemical Society, Chemical Communications, 24, Article 24. https://doi.org/10.1039/C39930001868
    23. Kaim, W., Kohlmann, S., Lees, A. J., Snoeck, T. L., Stufkens, D. J., & Zulu, M. M. (1993). Reinvestigation of the visible absorption bands of the 2,2’-bipyrimidine complexes W(CO)4(bpym) and (m-bpym)M(CO)42 (M = Mo, W) with resonance Raman spectroscopy; the emission spectrum of (m-bpym)Mo(CO)42. Inorganica Chimica Acta, 210(2), Article 2. https://doi.org/10.1016/S0020-1693(00)83322-8
    24. Lichtblau, A., Hausen, H. D., Schwarz, W., & Kaim, Wolfgang. (1993). Inorganic hybrid analogs of Thiele’s and Chichibabin’s hydrocarbons. Spectroscopy, electrochemistry, and structure. Inorganic Chemistry, 32(1), Article 1. https://doi.org/10.1021/ic00053a012
  29. 1992

    1. Schafer, R., Kaim, W., Moscherosch, M., & Krejcik, Michael. (1992). Tetrathiorhenate(VI), ReS42-. Spectroelectrochemical characterization (UV-visible-IR) of a small new d1 system and of its tetrakis(2,2’-bipyridine)diruthenium(II) complex (EPR). Journal of the Chemical Society, Chemical Communications, 11, Article 11. https://doi.org/10.1039/C39920000834
    2. Schwederski, B., & Kaim, Wolfgang. (1992). Complexes of folic acid, lumiflavin and riboflavin with bis(2,2’-bipyridine)ruthenium(II). Facilitated formation of flavosemiquinone complexes and substantial decrease of pKa(NH). Inorganica Chimica Acta, 195(1), Article 1. https://doi.org/10.1016/S0020-1693(00)83859-1
    3. Wolmershaeuser, G., Kaim, W., Heckmann, G., & Lichtblau, Alexander. (1992). Benzo-1,3,2-diselenazolylium salts: Synthesis and reactivity. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 47(5), Article 5. https://doi.org/10.1515/znb-1992-0511
    4. Kaim, Wolfgang. (1992). Coordinative aspects of single electron exchange between Main group or transition metal compounds and unsaturated organic substrates. Studies in Physical and Theoretical Chemistry, 78(Electron Proton Transfer Chem. Biol), Article Electron Proton Transfer Chem. Biol.
    5. Vogler, C., Schwederski, B., Klein, A., & Kaim, Wolfgang. (1992). Electrochemistry, electron spin resonance, optical spectroscopy, and reactivity of organometallic platinum(II) complexes containing strongly p-accepting aromatic a-diimine ligands. Journal of Organometallic Chemistry, 436(3), Article 3. https://doi.org/10.1016/0022-328X(92)85067-7
    6. Schwederski, B., Kaim, W., Olbrich-Deussner, B., & Roth, Thomas. (1992). Electron transfer catalyzed substitution in carbonyl complexes VI. Highly variable rates of substitution by tetracyanoethylene. Journal of Organometallic Chemistry, 440(1–2), Article 1–2. https://doi.org/10.1016/0022-328X(92)83491-Y
    7. Ladwig, M., & Kaim, Wolfgang. (1992). Electronic structure of catalytic intermediates for production of hydrogen: (C5Me5)Ir(bpy) and its conjugated acid. Journal of Organometallic Chemistry, 439(1), Article 1. https://doi.org/10.1016/0022-328X(92)80055-3
    8. Vogler, C., & Kaim, Wolfgang. (1992). Mononuclear bis(triphenylphosphine)copper(I) complexes of bidiazines. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 47(8), Article 8. https://doi.org/10.1515/znb-1992-0801
    9. Kaim, W., Roth, T., Olbrich-Deussner, B., Gross-Lannert, R., Jordanov, J., & Roth, E. K. H. (1992). Unexpected paramagnetism of mono- and polynuclear 18 valence electron metal carbonyl complexes (CnRn)(CO)2Mk(L), M = chromium, manganese; k = 1, 2, 4. Implications for photoreactivity. Journal of the American Chemical Society, 114(14), Article 14. https://doi.org/10.1021/ja00040a031
    10. Klein, A., Hausen, H.-D., & Kaim, Wolfgang. (1992). protection of the axial positions of square-planar platinum(II) center of (2,2’-bipyridine)dimesitylplatinum, characterized by X-ray diffraction. Luminescence and electrochem. reversible formation of Platinum(III). Journal of Organometallic Chemistry, 440(1–2), Article 1–2.
    11. Lichtblau, A., Kaim, W., Schulz, A., & Stahl, Thomas. (1992). Organoboron substituent effects in EPR/ENDOR spectroscopy. Radical ions with boron-carbon and boron-nitrogen bonds. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 9, Article 9.
    12. Braterman, P. S., Song, J. I., Vogler, C., & Kaim, Wolfgang. (1992). EPR and absorption spectra of singly reduced mono- and dinuclear diorganoplatinum complexes of heterocyclic a-diimines. Inorganic Chemistry, 31(2), Article 2. https://doi.org/10.1021/ic00028a018
    13. Krejcik, M., Zalis, S., Ladwig, M., Matheis, W., & Kaim, Wolfgang. (1992). A study of the reduced states of four isomeric bidiazines (diaza-2,2’-bipyridines) by UV-VIS/NIR-spectroelectrochemistry. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 11, Article 11.
    14. Braterman, P. S., Song, J. I., Kohlmann, S., Vogler, C., & Kaim, Wolfgang. (1992). Spectroelectrochemistry of aromatic ligands and their derivatives. III. Binuclear transition metal complexes of copper(I), molybdenum(0), and rhenium(I) with 2,2’-bipyrimidine. Erratum to document cited in CA116(2):12392f. Journal of Organometallic Chemistry, 424(1), Article 1.
    15. Roth, T., & Kaim, Wolfgang. (1992). Electron-transfer-induced isomerization h2(C:C) $\rightarrow$ h1(N) of the tetracyanoethylene complex, pentacarbonyl(tetracyanoethylene)tungsten (0/1-). Inorganic Chemistry, 31(10), Article 10. https://doi.org/10.1021/ic00036a038
    16. Moscherosch, M., & Kaim, Wolfgang. (1992). EPR/ENDOR detection of stable titanium(III) and titanium(IV) radical products generated by single electron transfer from (iso-PrO)3TiCH3. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 9, Article 9.
    17. Braterman, P. S., Song, J. I., Wimmer, F. M., Wimmer, S., Kaim, W., Klein, A., & Peacock, R. D. (1992). Electrochemistry and spectroelectrochemistry (EPR, UV-visible-near-IR) of platinum(II) 2,2’-bipyridine and ring-metalated bipyridine complexes: PtII(L-) and PtI(L-) but not PtI(L). Inorganic Chemistry, 31(24), Article 24. https://doi.org/10.1021/ic00050a030
    18. Bell, S. E., Field, J. S., Haines, R. J., Moscherosch, M., Matheis, W., & Kaim, Wolfgang. (1992). Novel and stable metal-metal-bonded diruthenium(I) complexes containing TCNX0/.bul.- in both the inner and the outer coordination sphere (TCNX = TCNE, TCNQ). A combined EPR/ENDOR-, UV/visible/near-IR-, and IR-spectroscopic and electrochemical investigation. Inorganic Chemistry, 31(15), Article 15. https://doi.org/10.1021/ic00041a020
    19. Oki, A. R., Zhang, H., Maguire, J. A., Hosmane, N. S., Ro, H., Hatfield, W. E., Moscherosch, M., & Kaim, Wolfgang. (1992). Chemistry of C-trimethylsilyl-substituted heterocarboranes. 10. Syntheses, structures, and properties of anionic chromium(III) and neutral chromium(IV) sandwiched metallacarborane complexes 1,1’-commo-Cr2-(SiMe3)-3-(R)-2,3-C2B4H42- and 1,1’-commo-Cr2,3-(SiMe3)2-2,3-C2B4H42 (R = SiMe3, Me, and H). Organometallics, 11(12), Article 12. https://doi.org/10.1021/om00060a043
  30. 1991

    1. Stufkens, D. J., Snoeck, T. L., Kaim, W., Roth, T., & Olbrich-Deussner, Barbara. (1991). Resonance Raman study of (h2-TCNE)M(CO)5 (M = Cr, W; TCNE = tetracyanoethene). Evidence for an olefin-complex $\rightarrow$ metallacyclopropane transition upon low-energy metal-to-ligand charge-transfer excitation. Journal of Organometallic Chemistry, 409(1–2), Article 1–2. https://doi.org/10.1016/0022-328X(91)86144-F
    2. Ladwig, M., & Kaim, Wolfgang. (1991). Spectroscopic and electrochemical properties of the isomeric bidiazine complexes (C5Me5)ClRh(bdz)+ and (C5Me5)Rh(bdz) and their relevance to the catalysis of the 2 H+ $\rightarrow$ H2 reaction by 2,2’-bipyridine analogs. Journal of Organometallic Chemistry, 419(1–2), Article 1–2. https://doi.org/10.1016/0022-328X(91)86178-S
    3. Kaim, W., & Moscherosch, Michael. (1991). Detection of electron paramagnetic resonance signals from three different isotope combinations 63Cu/63Cu, 63Cu/65Cu and 65Cu/65Cu in stable dicopper(I) radical complexes. Journal of the Chemical Society, Faraday Transactions, 87(19), Article 19. https://doi.org/10.1039/ft9918703185
    4. Bruns, W., & Kaim, W. (1991). First stable organometallic analog mer-(OC)3(PiPr3)2W(m-pyrazine)W(PiPr3)2(CO)3+ of the Creutz-Taube ion: Similarities and differences. NATO ASI Series, Series C:  Mathematical and Physical Sciences, 343(Mixed Valency Syst.:  Appl. Chem., Phys. Biol), Article Mixed Valency Syst.:  Appl. Chem., Phys. Biol.
    5. Kaim, W., Olbrich-Deussner, B., & Roth, Thomas. (1991). Specific solvatochromism of the prototypical olefin complexes (h2-TCNE)M(CO)5 (M = chromium, tungsten) resulting from n and p donation of aprotic solvents toward the p-acceptor ligand. Organometallics, 10(2), Article 2. https://doi.org/10.1021/om00048a015
    6. Matheis, W., & Kaim, Wolfgang. (1991). Electronic structure of heterodinuclear complexes (bpy)2RuII(m-bpym)MLn; bpy = 2,2’-bipyridine; bpym = 2,2’-bipyrimidine; MLn = Cu(PPh3)2, Mo(CO)4, Re(CO)3Cl. Inorganica Chimica Acta, 181(1), Article 1. https://doi.org/10.1016/S0020-1693(00)85254-8
    7. Kaim, W., & Matheis, Walter. (1991). Bis(1,4-di-tert-butyl-1,4-diazabutadiene)gallium is not a gallium(II) compound. Journal of the Chemical Society, Chemical Communications, 8, Article 8. https://doi.org/10.1039/c39910000597
    8. Schulz, A., & Kaim, Wolfgang. (1991). Electrochemical and spectroscopic characterization of N,N’-dialkylquinoxalinium redox systems. Chemische Berichte, 124(1), Article 1.
    9. Kantlehner, W., Lehmann, H., Stahl, T., & Kaim, Wolfgang. (1991). Ortho amides. XLVII. 2,3-Dicyano-4,4-bis(dimethylamino)-N,N,N’,N’-tetramethyl-3-butenamidinium-2-yl. An extremely stable, isolable radical cation with electrochemical and ENDOR detectable limits of mobility. Chemiker-Zeitung, 115(6), Article 6.
    10. Bruns, W., Kaim, W., Ladwig, M., Matheis, W., & Roth, T. (Hrsg.). (1991). Storage and liberation of molecular hydrogen by ligand-stabilized metal centers: Energietraeger Wasserst., Jahreskolloq. Sonderforschungsbereichs 270 Univ. Stuttgart. VDI-Verlag.
    11. Braterman, P. S., Song, J. I., Kohlmann, S., Vogler, C., & Kaim, Wolfgang. (1991). Spectroelectrochemistry of aromatic ligands and their derivatives. III. Binuclear transition metal complexes of copper(I), molybdenum(0), and rhenium(I) with 2,2’-bipyrimidine. Journal of Organometallic Chemistry, 411(1–2), Article 1–2. https://doi.org/10.1016/0022-328X(91)86019-M
    12. Kaupp, M., Stoll, H., Preuss, H., Kaim, W., Stahl, T., van Koten, G., Wissing, E., Smeets, W. J. J., & Spek, A. L. (1991). Theoretical and experimental study of diamagnetic and paramagnetic products from thermal and light-induced alkyl transfer between zinc or magnesium dialkyls and 1,4-diaza-1,3-butadiene substrates. Journal of the American Chemical Society, 113(15), Article 15. https://doi.org/10.1021/ja00015a014
    13. Matheis, W., & Kaim, Wolfgang. (1991). Homo- and heterodinuclear complexes of D2h-symmetric bis(chelate) ligand 2,2’-bipyrimidine with electron-rich metal fragments Mo(CO)4, Re(CO)3Cl, Cu(PPh3)2+, and Ru(bpy)22+. Zeitschrift fuer Anorganische und Allgemeine Chemie, 593, 147--159. https://doi.org/10.1002/zaac.19915930114
    14. Kaim, W., Kohlmann, S., Jordanov, J., & Fenske, D. (1991). Edge-sharing of two five-membered metal chelate rings; structures and magnetism of molybdenum(0)-, copper(I)-, and cobalt(II)-complexes with the S-frame ligand azo-2,2’-pyridine. Zeitschrift fuer Anorganische und Allgemeine Chemie, 598–599, 217--234.
  31. 1990

    1. Vogler, C., & Kaim, Wolfgang. (1990). Electronic structure of a heterotetranuclear copper(I)2-iron(II)2 complex bridged by p-accepting 2,2’-bipyrimidine. Close-lying but orthogonal frontier orbitals. Journal of Organometallic Chemistry, 398(3), Article 3. https://doi.org/10.1016/0022-328X(90)85515-Z
    2. Kaim, W., & Kohlmann, Stephan. (1990). The nature of reduced and excited states of p-electron-deficient complexes between tricarbonylhalorhenium and diimine ligands. Inorganic Chemistry, 29(16), Article 16. https://doi.org/10.1021/ic00341a010
    3. Kaim, W., & Olbrich-Deussner, Barbara. (1990). Paramagnetic main Group and transition metal complexes containing unsaturated nitrogen ligands. Journal of Organometallic Chemistry Library, 22(Organomet. Radical Processes), Article Organomet. Radical Processes.
    4. Bruns, W., & Kaim, Wolfgang. (1990). Bond character of the hydrogen coordinated fragment W(CO)3(PR3)2. Unusual optical and electrochemical properties of binuclear pyrazine complexes. Journal of Organometallic Chemistry, 390(2), Article 2.
    5. Schwederski, B., Kasack, V., Kaim, W., Roth, E., & Jordanov, Jeanne. (1990). Ambident behavior of the new vitamin methoxatine (cofactor PQQ) toward metals. Coordinative stabilization of pyrrolide and semiquinone forms. Angewandte Chemie, 102(1), Article 1.
    6. Kaim, W., & Kasack, Volker. (1990). Stability rules for d5/d6 mixed-valent dimers. Effects from the donor/acceptor capability of the metal (ruthenium vs osmium) and from the occupancy of the mediating ligand orbital (LUMO vs HOMO). Inorganic Chemistry, 29(23), Article 23. https://doi.org/10.1021/ic00348a022
    7. Kaim, W., & Matheis, Walter. (1990). Coupling between polypyridineruthenium(II) and methylviologen moieties in p-conjugated hybrid systems. Chemische Berichte, 123(6), Article 6.
    8. Kaim, W., Ernst, S., & Kasack, Volker. (1990). ESR of homo- and heteroleptic mono- and dinuclear tris(a-diimine)ruthenium radical complexes. Journal of the American Chemical Society, 112(1), Article 1. https://doi.org/10.1021/ja00157a028
    9. Gross-Lannert, R., Kaim, W., & Olbrich-Deussner, Barbara. (1990). Electron delocalization in molecule-bridged polymetallic systems. Unique neutral complexes of TCNE or TCNQ and up to four organometallic fragments (C5R5)(CO)2Mn. Inorganic Chemistry, 29(25), Article 25. https://doi.org/10.1021/ic00350a009
    10. Matheis, W., & Kaim, Wolfgang. (1990). A first radical cation chelate ligand: Electron paramagnetic resonance spectra of singly reduced 3,3’-diazamethylviologen, DAMV.+ and the rhenium(I) complex(DAMV.+)Re+(CO)3(PPh3)2+. Journal of the Chemical Society, Faraday Transactions, 86(19), Article 19. https://doi.org/10.1039/FT9908603337
    11. Kaim, W., & Kohlmann, Stephen. (1990). Design and evaluation of conjugated bridging p systems. Molecular orbital characterization and electrochemical determination of the pentacarbonyltungsten binding site in two new ambidentate ligands. Inorganic Chemistry, 29(10), Article 10. https://doi.org/10.1021/ic00335a027
  32. 1989

    1. Kaim, W., Kramer, H. E. A., Vogler, C., & Rieker, Jochen. (1989). Synthesis, electrochemistry and emission spectroscopy in fluid solution of four isomeric (a-diimine)Re(CO)3Hal complexes. Journal of Organometallic Chemistry, 367(1–2), Article 1–2. https://doi.org/10.1016/0022-328X(89)87212-2
    2. Bessenbacher, C., & Kaim, Wolfgang. (1989). Coordination ambivalence and fluxional behavior in mono- and binuclear pentacarbonyltungsten complexes of pteridine and its deaza derivatives. Journal of Organometallic Chemistry, 369(1), Article 1.
    3. Olbrich-Deussner, B., Gross, R., & Kaim, Wolfgang. (1989). Electron transfer catalyzed substitution in carbonyl complexes. IV. Mononuclear s- and p-coordinated complexes of manganese, chromium and tungsten with tetracyanoethylene and tetracyano-p-quinodimethane. Journal of Organometallic Chemistry, 366(1–2), Article 1–2.
    4. Baumgarten, J., Bessenbacher, C., Kaim, W., & Stahl, Thomas. (1989). Molecular and electronic structure of electron-transfer active main-group organometallics Erratum to document cited in CA110(15):135328y. Journal of the American Chemical Society, 111(13), Article 13. https://doi.org/10.1021/ja00195a085
    5. Baumgarten, J., Bessenbacher, C., Kaim, W., & Stahl, Thomas. (1989). Molecular and electronic structure of electron-transfer active main-group organometallics. Journal of the American Chemical Society, 111(6), Article 6. https://doi.org/10.1021/ja00188a028
    6. Bessenbacher, C., Vogler, C., & Kaim, Wolfgang. (1989). Stabilization of biochemically interesting intermediates by metal coordination. 6. Charge transfer in complexes of 1,3-dimethyllumazine with low-valent metals. Inorganic Chemistry, 28(26), Article 26. https://doi.org/10.1021/ic00325a021
    7. Kohlmann, S., Kasack, V., Roth, E., & Kaim, Wolfgang. (1989). Binuclear radical complexes of heavy-metal fragments containing ruthenium, osmium, rhodium and gold. Journal of the Chemical Society, Faraday Transactions 1:  Physical Chemistry in Condensed Phases, 85(12), Article 12. https://doi.org/10.1039/f19898504047
    8. Bessenbacher, C., & Kaim, Wolfgang. (1989). Stabilization of biochemical relevant intermediates by metal coordination. IV. Rhenium(I) complexes of flavin- and pterin-analogous nitrogen-oxygen chelate ligands. Zeitschrift fuer Anorganische und Allgemeine Chemie, 577, 39--52.
    9. Alyea, E. C., Malito, J., Ernst, S. D., Kaim, W., & Kohlmann, S. J. (1989). A molybdenum-95 NMR study of electronic effects in tetracarbonyl-molybdenum complexes of aromatic a-diimine chelate ligands. Polyhedron, 8(7), Article 7. https://doi.org/10.1016/S0277-5387(00)86444-X
    10. Olbrich-Deussner, B., Kaim, W., & Gross-Lannert, Renate. (1989). Electron-transfer catalyzed substitution in carbonyl complexes. Part 5. Electron-transfer autocatalytic formation, intramolecular charge transfer, and qualitatively different solvatochromism of s and p transition-metal carbonyl complexes with polynitrile ligands. Inorganic Chemistry, 28(16), Article 16. https://doi.org/10.1021/ic00315a010
    11. Hausen, H. D., Kaim, W., Schulz, A., & Roth, Eberhard. (1989). Structure and magnetism of stable cation radical salts: N,N’-diethylquinoxalinium tetraphenylborate as compared with pyrazinium and phenazinium analogs. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 44(10), Article 10. https://doi.org/10.1515/znb-1989-1016
    12. Ernst, S. D., & Kaim, Wolfgang. (1989). Energy level tailoring in ruthenium(II) polyazine complexes based on calculated and experimental ligand properties. Inorganic Chemistry, 28(8), Article 8. https://doi.org/10.1021/ic00307a020
    13. Bessenbacher, C., & Kaim, Wolfgang. (1989). Electron-rich olefins. 3. Formation of the first N,N’-persilylated 1,4-diaminoethene via a 1,2,3-triazoline(4) intermediate with 8 cyclically conjugated p electrons and 3 neighboring nitrogen electron pairs. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 44(5), Article 5. https://doi.org/10.1515/znb-1989-0502
    14. Kaim, W., Olbrich-Deussner, B., Gross, R., Ernst, S., Kohlmann, S., & Bessenbacher, Christian. (1989). Electron transfer induced metal addition and ligand exchange in organometallic anion radical complexes. NATO ASI Series, Series C:  Mathematical and Physical Sciences, 257(Paramagn. Organomet. Species Act./Sel., Catal), Article Paramagn. Organomet. Species Act./Sel., Catal.
    15. Bessenbacher, C., Kaim, W., & Stahl, Thomas. (1989). Electron-rich olefins. 4. Electron-rich compounds with thiophosphinamide, carboxamide, O-silylurethane and O-silylisourea functionality. Synthesis, spectroscopy, chemical and electrochemical reactivity. Chemische Berichte, 122(5), Article 5.
    16. Olbrich-Deussner, B., & Kaim, Wolfgang. (1989). Electron-transfer-catalyzed carbonyl substitution. III. Synthesis and spectroscopy of mono- and binuclear cis-phosphinetetracarbonyltungsten(0) complexes of electron-poor pyridines. Journal of Organometallic Chemistry, 361(3), Article 3.
    17. Vogler, C., Hausen, H. D., Kaim, W., Kohlmann, S., Kramer, H. E. A., & Rieker, Jochen. (1989). Copper(I)-induced formation of an organic sandwich structure. Structural hypothesis for luminescence of binuclear copper bipyrimidine complexes. Angewandte Chemie, 101(12), Article 12.
    18. Bessenbacher, C., & Kaim, Wolfgang. (1989). Stabilizing biochemically important intermediates through metal coordination. 5,8-Bis(trimethylsilyl)-5,8-dihydropteridine and its deaza derivative. Journal of Organometallic Chemistry, 362(1–2), Article 1–2.
    19. Gross-Lannert, R., Kaim, W., Lechner, U., Roth, E., & Volger, Conny. (1989). On the reaction of aromatic phosphanes with electrons. IV. Significance of low-lying orbitals at phosphorus for the mobility and coordinative characteristics of PR2 substituents in reduced p-phenylenediphosphanes. Zeitschrift fuer Anorganische und Allgemeine Chemie, 579, 47--56.
    20. Bessenbacher, C., & Kaim, Wolfgang. (1989). Evidence for the 1-thia-3-sila-2,4-diazetidine heterocyclic system with three parallel lone pairs from an ESR spectroscopic study of its cation radical. Journal of the Chemical Society, Chemical Communications, 8, Article 8. https://doi.org/10.1039/c39890000469
    21. Bessenbacher, C., Ernst, S., Kohlmann, S., Kaim, W., Kasack, V., Roth, E., & Jordanov, Jeanne. (1989). Stabilization of biochemically interesting intermediates by metal coordination. 5. Complexes of zinc, copper(I), rhenium(I), and ruthenium(II) with singly reduced 2,5-diacetylpyrazine. Journal of the Chemical Society, Faraday Transactions 1:  Physical Chemistry in Condensed Phases, 85(12), Article 12. https://doi.org/10.1039/f19898504075
    22. Kaim, W., Kohlmann, S., Lees, A. J., & Zulu, Mthembeni. (1989). 2-Heteroatom-1,3-diazoles and quinoxaline as bridging p-acceptor ligands for Group VIB metal carbonyl fragments M(CO)5 (M = Cr, Mo, W). Synthesis, electrochemistry, absorption and emission spectroscopy. Zeitschrift fuer Anorganische und Allgemeine Chemie, 575, 97--114.
    23. Schulz, A., & Kaim, Wolfgang. (1989). Organoboron redox systems. Chemische Berichte, 122(10), Article 10.
    24. Ernst, S., Haenel, P., Jordanov, J., Kaim, W., Kasack, V., & Roth, Eberhard. (1989). Stable binuclear o- and p-semiquinone complexes of Ru(bpy)22+. Radical ion versus mixed-valence dimer formulation. Journal of the American Chemical Society, 111(5), Article 5. https://doi.org/10.1021/ja00187a026
  33. 1988

    1. Kaim, W., & Gross, Renate. (1988). Bridging the fields of organometallic and classical coordination chemistry: Localized and delocalized bonding in polynuclear complexes of (C5R5)(CO)2Mn. Comments on Inorganic Chemistry, 7(5), Article 5. https://doi.org/10.1080/02603598808072312
    2. Olbrich-Deussner, B., & Kaim, Wolfgang. (1988). Electron transfer catalyzed carbonyl substitution. I. Synthesis and spectroscopy of phosphine tricarbonyl metal complexes of bidiazine. Journal of Organometallic Chemistry, 340(1), Article 1.
    3. Ernst, S., Kasack, V., & Kaim, Wolfgang. (1988). What determines the comproportionation constant in molecule-bridged mixed-valence complexes? Evidence for the crucial role of the ligand LUMO in four ruthenium(II)ruthenium(III) dimers. Inorganic Chemistry, 27(7), Article 7. https://doi.org/10.1021/ic00280a010
    4. Hausen, H. D., & Kaim, Wolfgang. (1988). Electron-rich olefins. 1. The relationship between structure, spectroscopy, and reactivity of tetrakis(trimethylsilylmethyl)ethene. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 43(1), Article 1. https://doi.org/10.1515/znb-1988-0115
    5. Kaim, W., Kasack, V., Binder, H., Roth, E., & Jordanov, Jeanne. (1988). A stable bis(chelate) analog of Creutz-Taube ions. Angewandte Chemie, 100(9), Article 9.
    6. Ernst, S., Kohlmann, S., & Kaim, Wolfgang. (1988). cis-Bis(tributylphosphine)molybdenum dicarbonyl complexes with four isomeric bidiazine ligands. Journal of Organometallic Chemistry, 354(2), Article 2.
    7. Hausen, H. D., Bessenbacher, C., & Kaim, Wolfgang. (1988). Electron rich olefins. 2. Structure and electron transfer reactivity of the cyclic s/p-hyperconjugated carbosilane 3,3,6,6-tetrakis(trimethylsilyl)-1,4-cyclohexadiene. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 43(9), Article 9.
    8. Ernst, S., & Kaim, Wolfgang. (1988). On charge transfer-assisted polynucleation reactions. A trinuclear carbonyl-tungsten complex of ambident 4,4’-bipyrimidine. Inorganica Chimica Acta, 144(2), Article 2. https://doi.org/10.1016/S0020-1693(00)86290-8
    9. Kaim, Wolfgang. (1988). Trapping of the coordinatively unsaturated organosilicon anion radical Me3SiC$\equiv$CC$\equiv$CSiMe3·- by double ate-complex formation with AlR3. Journal of Organometallic Chemistry, 339(3), Article 3. https://doi.org/10.1016/S0022-328X(00)99386-0
    10. Scherer, O. J., Schwalb, J., Swarowsky, H., Wolmershaeuser, G., Kaim, W., & Gross, Renate. (1988). Triple-decker sandwich complexes with cyclo-P6 as middle deck. Chemische Berichte, 121(3), Article 3.
    11. Hausen, H. D., Schulz, A., & Kaim, Wolfgang. (1988). Electronic stabilization through 7-p electron conjugation in heterocycles. Molecular and crystal structure of an inert monocyclic radical cation. Chemische Berichte, 121(11), Article 11.
    12. Pohl, K., Wieghardt, K., Kaim, W., & Steenken, Steen. (1988). Redox reactivity of bis(1,4,7-triazacyclononane)iron(II/III) complexes in alkaline solution and characterization of a deprotonated species: Amidoiron(III) vs aminyliron(II) ground-state formulation. EPR, kinetic, pulse radiolysis, and laser photolysis study. Inorganic Chemistry, 27(3), Article 3. https://doi.org/10.1021/ic00276a003
    13. Schulz, A., Kaim, W., & Hausen, H. Dieter. (1988). Crystalline heterocyclic radical cation salts as stable intermediates of new redox-mediating systems. Journal of the Chemical Society, Faraday Transactions 1:  Physical Chemistry in Condensed Phases, 84(10), Article 10. https://doi.org/10.1039/f19888403207
  34. 1987

    1. Gross, R., & Kaim, Wolfgang. (1987). Tetranuclear mixed valent manganese complexes with reduced TCNE or TCNQ as h4-bridged ligands. Angewandte Chemie, 99(3), Article 3.
    2. Scherer, O. J., Swarowsky, H., Wolmershaeuser, G., Kaim, W., & Kohlmann, Stephan. (1987). (h5-C5Me5)2Ti2P6, a distorted dimetallaphosphacubane. Angewandte Chemie, 99(11), Article 11.
    3. Kaim, W., & Kohlmann, Stephan. (1987). Four bridging bis chelate ligands with very low lying p* orbitals. MO perturbation calculations, electrochemistry, and spectroscopy of mononuclear and binuclear group 6 metal tetracarbonyl complexes. Inorganic Chemistry, 26(1), Article 1. https://doi.org/10.1021/ic00248a016
    4. Scherer, O. J., Bach, I., Schwalb, J., Sitzmann, H., Wolmershaeuser, G., Kaim, W., & Gross, R. (1987). Px Hueckel systems as complex ligands. Phosphorus and Sulfur and the Related Elements, 30(1–2), Article 1–2. https://doi.org/10.1080/03086648708080574
    5. Kaim, Wolfgang. (1987). The transition metal coordination chemistry of anion radicals. Coordination Chemistry Reviews, 76, 187--235. https://doi.org/10.1016/0010-8545(87)85004-X
    6. Kaim, W., & Kohlmann, S. (1987). EPR evidence for related electronic structures of a-diimine complexes with bis(bipyridine)ruthenium(2+) (Ru(bpy)22+) and rhenium carbonyl(Re(CO)3)(halide) fragments. Chemical Physics Letters, 139(3–4), Article 3–4. https://doi.org/10.1016/0009-2614(87)80574-2
    7. Gross, R., & Kaim, Wolfgang. (1987). Coordination ambivalence and electron structure of mono- and binuclear methylcyclopentadienylmanganese dicarbonyl complexes of cyanopyridine and terephthalodinitrile. Journal of Organometallic Chemistry, 333(3), Article 3.
    8. Kaim, W., Ernst, S., & Kohlmann, Stephan. (1987). Colored complexes: The charge transfer phenomenon. Chemie in Unserer Zeit, 21(2), Article 2.
    9. Kaim, W., Kohlmann, S., Ernst, S., Olbrich-Deussner, B., Bessenbacher, C., & Schulz, Andreas. (1987). What determines the solvatochromism of metal-to-ligand charge transfer transitions? A demonstration involving 17 tungsten carbonyl complexes. Journal of Organometallic Chemistry, 321(2), Article 2. https://doi.org/10.1016/0022-328X(87)85041-6
    10. Gross, R., & Kaim, Wolfgang. (1987). Deprotonated p-phenylenediamines as noninnocent ligands. Metal-to-ligand spin transfer in the ground state and ligand-to-metal charge transfer in the lowest excited state of low-spin manganese(II) complexes. Inorganic Chemistry, 26(21), Article 21. https://doi.org/10.1021/ic00268a035
    11. Kaim, W., & Kohlmann, Stephan. (1987). Paramagnetic copper(I) dimers. Inorganic Chemistry, 26(10), Article 10. https://doi.org/10.1021/ic00257a001
    12. Kaim, Wolfgang. (1987). Heterocycles with 7 and 8p electrons. Models for flavin and pteridine intermediates and candidates for novel inorganic rings. Reviews of Chemical Intermediates, 8(3), Article 3. https://doi.org/10.1007/BF03156156
    13. Ernst, S., Kasack, V., Bessenbacher, C., & Kaim, Wolfgang. (1987). Mono- and binuclear bis(2,2’-bipyridine)ruthenium complexes with N,O-ligands modeling dehydrogenase cofactors. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 42(4), Article 4. https://doi.org/10.1515/znb-1987-0407
  35. 1986

    1. Gross, R., & Kaim, Wolfgang. (1986). Neutral spin-delocalized mixed-valence manganese(I)-manganese(II) dimers bridged by alkoxide, imidazolate, or malonodinitrile anions. Inorganic Chemistry, 25(27), Article 27. https://doi.org/10.1021/ic00247a018
    2. Kaim, W., & Kohlmann, Stephan. (1986). Semireduced bridging ligands containing N-N multiple bond coordination sites. ESR study of binuclear Group 6 metal carbonyl complexes. Inorganic Chemistry, 25(19), Article 19. https://doi.org/10.1021/ic00239a025
    3. Kaim, W., & Ernst, Sylvia. (1986). ESR and ENDOR study of three isomeric bidiazine anion radicals and of their Group 6 metal carbonyl complexes. Coordinative effects on the spin distribution. Journal of Physical Chemistry, 90(21), Article 21. https://doi.org/10.1021/j100412a028
    4. Kaim, W., & Kohlmann, Stephan. (1986). Exceptionally variable solvatochromism of centrosymmetric octacarbonyldimolybdenum(0) complexes. Rules to estimate the solvent sensitivity of charge-transfer absorption energies. Inorganic Chemistry, 25(18), Article 18. https://doi.org/10.1021/ic00238a040
    5. Kaim, W. (1986). Oligomerization and polymerization of olefins on homogeneous and heterogeneous nickel catalysts (Ch 1). 2(Ch 1), Article Ch 1.
    6. Ernst, S., Kurth, Y., & Kaim, Wolfgang. (1986). Correlation between solvatochromism and back-bonding in four isomeric (a-diimine)M(CO)4 complexes (M = Cr, Mo, W). Journal of Organometallic Chemistry, 302(2), Article 2. https://doi.org/10.1016/0022-328X(86)80084-5
    7. Gross, R., & Kaim, Wolfgang. (1986). Charge-transfer and electron-transfer properties of d6 metal complexes with m-pyrazine. Mononuclear and binuclear manganese(I) compounds. Inorganic Chemistry, 25(4), Article 4. https://doi.org/10.1021/ic00224a021
    8. Ernst, S., & Kaim, Wolfgang. (1986). 3,3’-Bipyridazine: The „second-best“ bidiazine ligand for metal carbonyl M(CO)4 fragments (M = chromium, molybdenum, tungsten). Inorganica Chimica Acta, 114(2), Article 2. https://doi.org/10.1016/S0020-1693(00)86442-7
    9. Seitz, F., Fischer, H., Riede, J., Schoettle, T., & Kaim, Wolfgang. (1986). Metalloheterocumulenes. 6. Isocyanide as a complex-ligand. Angewandte Chemie, 98(8), Article 8.
    10. Ernst, S., & Kaim, Wolfgang. (1986). Coordination characteristics of four isomeric a-diimine ligands. p Molecular orbital perturbation calculations for the bidiazines and their correlation with the properties of group 6 metal carbonyl complexes. Journal of the American Chemical Society, 108(13), Article 13. https://doi.org/10.1021/ja00273a005
    11. Kaim, W., Ernst, S., & Kohlmann, Stephan. (1986). Mono- and binuclear molybdenum carbonyl complexes with charge-transfer absorptions in the near IR. Polyhedron, 5(1–2), Article 1–2. https://doi.org/10.1016/S0277-5387(00)84948-7
  36. 1985

    1. Ernst, S., & Kaim, Wolfgang. (1985). Ambidentate ligand with high p-acceptor capacity: D6-metal complexes of 4,4’-bipyrimidine. Angewandte Chemie, 97(5), Article 5.
    2. Kohlmann, S., Ernst, S., & Kaim, Wolfgang. (1985). Extremely long-wavelength charge-transfer absorption of binuclear complexes with azo-modified 2,2’-bipyridyl ligands. Angewandte Chemie, 97(8), Article 8.
    3. Kaim, W., Ernst, S., Kohlmann, S., & Welkerling, P. (1985). First observation of resolved ESR hyperfine structure for a reduced ruthenium(II) polyazine complex. Chemical Physics Letters, 118(4), Article 4. https://doi.org/10.1016/0009-2614(85)85405-1
    4. Kaim, Wolfgang. (1985). Electronic structure of 1,4-dihydro-1,2,4,5-tetrazines and of related 1,4-dihydroaromatic compounds. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 10, Article 10.
    5. Kaim, W., & Kohlmann, Stephan. (1985). Coordination chemistry of p-electron deficient ligands. Binuclear tungsten pentacarbonyl complexes of the weakly basic 2,1,3-benzochalcogenadiazoles. Inorganica Chimica Acta, 101(2), Article 2. https://doi.org/10.1016/S0020-1693(00)85989-7
    6. Bessenbacher, C., Gross, R., & Kaim, Wolfgang. (1985). Persistent cation radicals containing carboxamide and thiophosphinic amide functions. The one electron oxidation of acceptor stabilized 1,4-dihydropyrazines. Journal of the Chemical Society, Chemical Communications, 20, Article 20. https://doi.org/10.1039/c39850001369
    7. Gross, R., & Kaim, Wolfgang. (1985). Three compounds from the reaction between dicarbonyl(methylcyclopentadienyl)(tetrahydrofuran)manganese and 4-cyanopyridine. Journal of Organometallic Chemistry, 292(3), Article 3. https://doi.org/10.1016/0022-328X(85)80234-5
    8. Kaim, Wolfgang. (1985). Radical-forming electron-transfer reactions involving main-group organometallics. Accounts of Chemical Research, 18(6), Article 6. https://doi.org/10.1021/ar00114a001
    9. Bock, H., Haenel, P., Kaim, W., & Lechner-Knoblauch, Ulrike. (1985). Radical ions. Part 72. The stable radical cation of tetrakis(dimethylamino)-p-benzoquinone. Tetrahedron Letters, 26(42), Article 42. https://doi.org/10.1016/S0040-4039(00)98876-2
    10. Giordan, J. C., Moore, J. H., Tossell, J. A., & Kaim, Wolfgang. (1985). Interaction of frontier orbitals of Group 15 and Group 16 methides with the frontier orbitals of benzene. Journal of the American Chemical Society, 107(20), Article 20. https://doi.org/10.1021/ja00306a003
    11. Kaim, Wolfgang. (1985). Reaction of aromatic phosphine derivatives with electrons, III. Phosphine-boranes, -alanes, and -gallanes. Zeitschrift fuer Naturforschung, Teil B:  Anorganische Chemie, Organische Chemie, 40B(1), Article 1.
    12. Kaim, Wolfgang. (1985). N,N’-Dialkylpyrazinium and quinoxalinium salts. N-Heterocyclic redox systems with the radical cation intermediate as most persistent oxidation state. Heterocycles, 23(6), Article 6. https://doi.org/10.3987/R-1985-06-1363
    13. Hausen, H. D., Mundt, O., & Kaim, W. (1985). The structural flexibility of the antiaromatic 1,4-dihydropyrazine system. The crystal and molecular structure of organometallic derivatives. Journal of Organometallic Chemistry, 296(3), Article 3.
    14. Kaim, Wolfgang. (1985). Electron donation capability of the trimethylsiloxy substituent as studied by photoelectron spectroscopy and electron spin resonance of polysubstituted benzene derivatives. Journal of Organometallic Chemistry, 282(1), Article 1. https://doi.org/10.1016/0022-328X(85)87137-0
    15. Gross, R., & Kaim, Wolfgang. (1985). Stabilization of Cp(CO)2Mn fragment radicals? Angewandte Chemie, 97(10), Article 10.
  37. 1984

    1. Bock, H., Kaim, W., Kira, M., Rene, L., & Viehe, H. Guenther. (1984). Radical ions, 61. Dialkylamino-substituted acetylenes and allenes: Ionization, oxidation, and aluminum chloride-catalyzed hydrogen transfer. Zeitschrift fuer Naturforschung, Teil B:  Anorganische Chemie, Organische Chemie, 39B(6), Article 6.
    2. Kaim, Wolfgang. (1984). Chemical and electrochemical reduction of pentacarbonyl(4-cyanopyridine) complexes of chromium(0), molybdenum(0) and tungsten(0). Inorganic Chemistry, 23(4), Article 4. https://doi.org/10.1021/ic00172a025
    3. Kaim, Wolfgang. (1984). Flavosemiquinone model systems. Part 1. 4-Hydro-1-alkylpyrazinium radical cations. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 8, Article 8.
    4. Kaim, Wolfgang. (1984). One-electron transfer: Departure from electron-pair mechanisms? Nachrichten aus Chemie, Technik und Laboratorium, 32(5), Article 5.
    5. Kaim, Wolfgang. (1984). The molecular geometry of the elusive 1,4-dihydropyrazine. An MNDO study. Journal of Molecular Structure: THEOCHEM, 18(3–4), Article 3–4. https://doi.org/10.1016/0166-1280(84)80011-1
    6. Kaim, Wolfgang. (1984). Flavosemiquinone model systems. Part 2. Methyl-substituted quinoxaline radical ions. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 11, Article 11.
    7. Kaim, Wolfgang. (1984). Isoelectronic radical ions from single electron transfer reactions: Direct detection of stable, solvent-separated radical anion/radical cation pairs. Angewandte Chemie, 96(8), Article 8.
    8. Kaim, Wolfgang. (1984). Mono- and binuclear tri- and tetracarbonyl complexes of chromium(0), molybdenum(0), and tungsten(0) with the 2,2’-bipyrimidine radical anion. Inorganic Chemistry, 23(21), Article 21. https://doi.org/10.1021/ic00189a019
    9. Kaim, Wolfgang. (1984). The reduction behavior of pentacarbonylpyridinechromium, -molybdenum and -tungsten complexes. Zeitschrift fuer Naturforschung, Teil B:  Anorganische Chemie, Organische Chemie, 39B(6), Article 6.
    10. Kaim, Wolfgang. (1984). Single electron transfer reaction of aluminum hydride with nitrogen-containing heterocycles. ESR characterization of the radical products. Journal of the American Chemical Society, 106(6), Article 6. https://doi.org/10.1021/ja00318a026
    11. Gross, R., & Kaim, Wolfgang. (1984). p-Backbonding and stability of oxidation steps in tetracarbonyldicyclopentadienyl(m-pyrazine)dimanganese(I) complexes. Angewandte Chemie, 96(8), Article 8.
    12. Kaim, Wolfgang. (1984). Mono- and binuclear pentacarbonyl complexes of chromium, molybdenum and tungsten with the anion radicals of 2,1,3-benzoxadiazole, 2,1,3-benzothiadiazole and 2,1,3-benzoselenadiazole. Journal of Organometallic Chemistry, 264(3), Article 3. https://doi.org/10.1016/0022-328X(84)85078-0
    13. Kaim, Wolfgang. (1984). Binuclear radical complexes of molybdenum and tungsten tetracarbonyls with bridging N-heterocycles and Group VA ligands. ESR evidence for a cis configuration. Journal of Organometallic Chemistry, 262(2), Article 2. https://doi.org/10.1016/S0022-328X(00)99140-X
    14. Kaim, W., & Schulz, Andreas. (1984). p-Phenylenediboranes: Mirror image of p-phenylendiamines? Angewandte Chemie, 96(8), Article 8.
  38. 1983

    1. Kaim, Wolfgang. (1983). Many aspects of chemistry of 1,4-diazines: Organic, inorganic, and biochemical aspects. Angewandte Chemie, 95(3), Article 3.
    2. Kaim, Wolfgang. (1983). Effects of cyclic 8p-electron conjugation in reductively silylated nitrogen heterocycles. Journal of the American Chemical Society, 105(4), Article 4. https://doi.org/10.1021/ja00342a005
    3. Kaim, Wolfgang. (1983). Metallaviolenes. An ESR study. Journal of Organometallic Chemistry, 241(2), Article 2. https://doi.org/10.1016/S0022-328X(00)98503-6
    4. Kaim, W., Lechner-Knoblauch, U., Haenel, P., & Bock, Hans. (1983). Organophosphorus redox systems. Journal of Organic Chemistry, 48(23), Article 23. https://doi.org/10.1021/jo00171a010
    5. Kaim, W., & Lubitz, Wolfgang. (1983). Radical products in single electron transfer reactions of lithium triethylhydridoborate as detected by ESR and multinuclear (proton, boron-10, boron-11, and nitrogen-14) ENDOR spectroscopy. Angewandte Chemie, 95(11), Article 11.
  39. 1982

    1. Kaim, Wolfgang. (1982). Electron transfer by Grignard reagents: Direct detection of organomagnesium radical complexes. Angewandte Chemie, 94(2), Article 2.
    2. Kaim, Wolfgang. (1982). Ambivalent coordination behavior of lithium aluminum hydride in electron transfer reactions. Angewandte Chemie, 94(2), Article 2.
    3. Kaim, W., Haenel, P., & Bock, Hans. (1982). The reduction of triphenylphosphine derivatives to their radical anions and to the radical dianion of dibenzophosphole. Zeitschrift fuer Naturforschung, Teil B:  Anorganische Chemie, Organische Chemie, 37B(11), Article 11.
    4. Kaim, W., Haenel, P., Lechner-Knoblauch, U., & Bock, Hans. (1982). Radical ions. 48. Radical anions as intermediates in the reductive desulfurization of tertiary phosphine sulfides. Chemische Berichte, 115(4), Article 4.
    5. Kaim, Wolfgang. (1982). Electron transfer to complex ligands. Radical anions and organomagnesium radical complexes of 2,2’-bipyridines and 1,10-phenanthrolines. Journal of the American Chemical Society, 104(14), Article 14. https://doi.org/10.1021/ja00378a010
    6. Bock, H., & Kaim, Wolfgang. (1982). Organosilicon radical cations. Accounts of Chemical Research, 15(1), Article 1. https://doi.org/10.1021/ar00073a002
    7. Baral, S., Cotton, F. A., Ilsley, W. H., & Kaim, Wolfgang. (1982). Axially coordinated tetrakisN-2,6-dimethyphenyl)lacetamidodimolybdenum(II) compounds. Structures of Mo2(xylyl)NC(CH3)O4.L (L = NC5H4CH3). Inorganic Chemistry, 21(4), Article 4. https://doi.org/10.1021/ic00134a074
    8. Kaim, Wolfgang. (1982). Coordination chemistry of reduced nitrogen heterocycles. Dinuclear pentacarbonyl complexes of molybdenum and tungsten with paramagnetic bridging ligands. Chemische Berichte, 115(3), Article 3.
    9. Kaim, Wolfgang. (1982). Organoaluminum radical complexes from the single electron transfer reaction of diisobutylaluminum hydride with nitrogen heterocycles. Zeitschrift fuer Naturforschung, Teil B:  Anorganische Chemie, Organische Chemie, 37B(6), Article 6.
    10. Kaim, W., & Kasack, Volker. (1982). Heterocyclic radical anions as ligands: An unexpected coordination change in pentacarbonylmetal complexes. Angewandte Chemie, 94(9), Article 9.
  40. 1981

    1. Cotton, F. A., Ilsley, W. H., & Kaim, Wolfgang. (1981). (Acetato)tris(N,N’-diphenylacetamidinato)dimolybdenum and bis(acetato)bisN,N’-bis(2,6-xylyl)acetamidinatodimolybdenum tetrakis(tetrahydrofuranate). Two new mixed-ligand quadruply bonded dimolybdenum compounds. Inorganic Chemistry, 20(3), Article 3. https://doi.org/10.1021/ic50217a058
    2. Kaim, Wolfgang. (1981). Antiaromaticity of 1,4-dihydropyrazines. Angewandte Chemie, 93(6–7), Article 6–7.
    3. Kaim, Wolfgang. (1981). Organoaluminum radical complexes of nitrogen heterocycles. II. 1,4-Diazines. Journal of Organometallic Chemistry, 215(3), Article 3.
    4. Kaim, Wolfgang. (1981). From ion pairs to radical complexes: Coordination compounds of reduced 2,2’-bipyridine with organometallic cations. Chemische Berichte, 114(12), Article 12.
    5. Kaim, Wolfgang. (1981). Organoaluminum radical complexes of nitrogen heterocycles. I. Pyridine derivatives. Journal of Organometallic Chemistry, 215(3), Article 3.
    6. Kaim, Wolfgang. (1981). Coordination compounds of reduced pyrazine with alkyl derivatives of boron, aluminum, gallium, and indium. Zeitschrift fuer Naturforschung, Teil B:  Anorganische Chemie, Organische Chemie, 36B(6), Article 6.
    7. Kaim, Wolfgang. (1981). Reaction of aromatic phosphoranylidene derivatives with electrons. I. Zeitschrift fuer Naturforschung, Teil B:  Anorganische Chemie, Organische Chemie, 36B(2), Article 2.
    8. Kaim, Wolfgang. (1981). The reaction of heterocyclic anion radicals with Group VI carbonyls. ESR characterization of paramagnetic binuclear complexes. Inorganica Chimica Acta, 53(4), Article 4. https://doi.org/10.1016/S0020-1693(00)84778-7
    9. Kaim, W., & Bock, Hans. (1981). Radical ions. 45. Radical anions of dimethylphosphino-substituted benzenes. Chemische Berichte, 114(4), Article 4.
    10. Kaim, Wolfgang. (1981). Coordination chemistry of reduced N-heterocycles. Complexes of pyrazine anion radical with phenyl metal cations +MPh of beryllium, magnesium and zinc. Zeitschrift fuer Naturforschung, Teil B:  Anorganische Chemie, Organische Chemie, 36B(9), Article 9.
    11. Kaim, Wolfgang. (1981). Electron transfer to 1,10-phenanthroline by Grignard reagents. The spin distribution in organomagnesium radical complexes. Journal of Organometallic Chemistry, 222(2), Article 2. https://doi.org/10.1016/S0022-328X(00)89165-2
    12. Kaim, Wolfgang. (1981). Organometallically stabilized 1,4-dihydropyrazines: Extremely electron-rich heterocycles. Angewandte Chemie, 93(6–7), Article 6–7.
  41. 1980

    1. Bock, H., Kaim, W., Timms, P. L., & Hawker, Pelham. (1980). Radical ions. 41. Durosemiquinone and its boron fluoride analog - detection of 1,4-diborin as an unexpected elimination product. Chemische Berichte, 113(10), Article 10. https://doi.org/10.1002/cber.19801131008
    2. Cotton, F. A., Ilsley, W. H., & Kaim, Wolfgang. (1980). Some reactions of the octahalodirhenate(III) ions. 11. Two new quadrupoly bonded dirhenium amidinato-bridged complexes. Inorganic Chemistry, 19(8), Article 8. https://doi.org/10.1021/ic50210a037
    3. Cotton, F. A., Ilsley, W. H., & Kaim, Wolfgang. (1980). Two new amidato-bridged dimolybdenum(II) compounds: TetrakisN-(2,6-dimethylphenyl)formamidodimolybdenum bis(tetrahydrofuranate) and tetrakis(N-phenylpivalamido)dimolybdenum. Inorganic Chemistry, 19(12), Article 12. https://doi.org/10.1021/ic50214a006
    4. Bock, H., & Kaim, W. (1980). Radical ions. 37. Ionization and one-electron oxidation of electron-rich silylalkyl olefins. Journal of the American Chemical Society, 102(13), Article 13. https://doi.org/10.1021/ja00533a023
    5. Cotton, F. A., Ilsley, W. H., & Kaim, Wolfgang. (1980). A mixed-ligand complex of quadruply bonded ditungsten(II): Bis(2,4-dimethyl-6-oxopyrimidine)bis(1,3-diphenyltriazeno)ditungsten. Inorganic Chemistry, 19(6), Article 6. https://doi.org/10.1021/ic50208a006
    6. Cotton, F. A., Ilsley, W. H., & Kaim, Wolfgang. (1980). Lewis basicity of a chlorine atom bound to an aliphatic carbon atom as sensed by a quadruple chromium-chromium bond. Structures of M2(2,6-xylyl)NC(CH3)O4.2CH2Cl2, M = chromium, molybdenum. Journal of the American Chemical Society, 102(10), Article 10. https://doi.org/10.1021/ja00530a027
    7. Bock, H., Braehler, G., Kaim, W., Kira, M., Roth, B., Semkow, A., Stein, U., & Tabatabai, A. (Hrsg.). (1980). Radical ions. Part XXXVIII. Novel radical ions: Generation and properties an interim report on PES and ESR investigations by the Frankfurt West Germany group: Comput. Methods Chem., Proc. Int. Symp. Plenum.
    8. Kaim, W., Bock, H., Hawker, P., & Timms, P. L. (1980). Radical ions. Part 40. Radical anion of 1,4-diborabenzene. Journal of the Chemical Society, Chemical Communications, 12, Article 12. https://doi.org/10.1039/c39800000577
    9. Kaim, Wolfgang. (1980). Isoelectronic radical ions and redox systems. Angewandte Chemie, 92(11), Article 11.
    10. Bock, H., Kaim, W., Noeth, H., & Semkow, A. (1980). Radical ions. 36. Structural changes accompanying the one-electron oxidation of hydrazine and its silyl derivatives. Journal of the American Chemical Society, 102(13), Article 13. https://doi.org/10.1021/ja00533a022
    11. Kaim, W., Tesmann, H., & Bock, Hans. (1980). Substituent effects and perturbation of p-systems. XXXVI. tert-Butyl-, trimethylsilyl-, trimethylgermyl-, trimethylstannyl- and trimethylplumbyl-substituted benzene and naphthalene derivatives and their anion radicals. Chemische Berichte, 113(10), Article 10.
    12. Cotton, F. A., Ilsley, W. H., & Kaim, Wolfgang. (1980). Homologous chromium, molybdenum, and tungsten derivatives of 6-chloro-2-hydroxypyridine. Inductive effects on the metal-metal bond length. Inorganic Chemistry, 19(6), Article 6. https://doi.org/10.1021/ic50208a007
    13. Kaim, Wolfgang. (1980). Paramagnetic organoaluminum complexes. Journal of Organometallic Chemistry, 201(2), Article 2. https://doi.org/10.1016/S0022-328X(00)87936-X
    14. Cotton, F. A., Ilsley, W. H., & Kaim, Wolfgang. (1980). Sensitivity of the chromium-chromium quadrupole bond to axial interactions in dichromium(II) compounds. Journal of the American Chemical Society, 102(10), Article 10. https://doi.org/10.1021/ja00530a026
    15. Cotton, F. A., Ilsley, W. H., & Kaim, Wolfgang. (1980). Tetrakisbis(difluorophosphino)methylaminedichlorodimolybdenum. A new type of compound with a metal-metal triple bond. Journal of the American Chemical Society, 102(6), Article 6. https://doi.org/10.1021/ja00526a026
  42. 1979

    1. Cotton, F. A., Ilsley, W. H., & Kaim, Wolfgang. (1979). Tetracarbanilanilidodichromium(II): A key to the understanding of the chromium-chromium quadruple bond. Angewandte Chemie, 91(11), Article 11.
    2. Bock, H., Kaim, W., Kira, M., Osawa, H., & Sakurai, H. (1979). Radical ions. XXVIII. Tris(trimethylsilylmethyl)aminium, +̇N(CH2Si(CH3)3)3: A stable fluxional aminium radical cation. Journal of Organometallic Chemistry, 164(3), Article 3. https://doi.org/10.1016/S0022-328X(00)81693-9
    3. Bino, A., Cotton, F. A., & Kaim, Wolfgang. (1979). Tetraacetanilidodichromium and -dimolybdenum: Another supershort chromium-chromium bond and an unexpected structural difference. Inorganic Chemistry, 18(11), Article 11. https://doi.org/10.1021/ic50201a017
    4. Bino, A., Cotton, F. A., & Kaim, Wolfgang. (1979). A tetrakis(amidinato)dichromium complex with a \dqsupershort\dq chromium-chromium quadruple bond. Inorganic Chemistry, 18(12), Article 12. https://doi.org/10.1021/ic50202a054
    5. Cotton, F. A., Ilsley, W. H., & Kaim, Wolfgang. (1979). Chelate rings in a quadruply bonded dimetal compound: Preparation and structure of diacetatodi(4-phenylimino-2-pentanonato)dimolybdenum. Inorganica Chimica Acta, 37(2), Article 2. https://doi.org/10.1016/S0020-1693(00)95556-7
    6. Cotton, F. A., Illsley, W. H., & Kaim, Wolfgang. (1979). A new mixed-ligand complex of the quadruply bonded ditungsten unit bis(N,N’-diphenylacetamidinato)bis(2,4-dimethyl-6-hydroxypyrimidinato)ditungsten bis(tetrahydrofuranate). Inorganic Chemistry, 18(12), Article 12. https://doi.org/10.1021/ic50202a055
    7. Bino, A., Cotton, F. A., & Kaim, Wolfgang. (1979). The \dqsupershort\dq chromium-to-chromium quadruple bond: Its occurrence in a tetracarboxamidatodichromium(II) compound. Journal of the American Chemical Society, 101(9), Article 9. https://doi.org/10.1021/ja00503a056
    8. Cotton, F. A., Ilsley, W. H., & Kaim, Wolfgang. (1979). N-(2-Pyridyl)acetamido-N,N’dimolybdenum; The (new) shortest known molybdenum-molybdenum quadruple bond. Inorganic Chemistry, 18(10), Article 10. https://doi.org/10.1021/ic50200a017
    9. Noeth, H., Winterstein, W., Kaim, W., & Bock, Hans. (1979). Chemistry of boron. C. Radical ions. XXXI. NMR and ESR spectroscopic investigations on five- and six-membered boron-nitrogen heterocycles. Chemische Berichte, 112(7), Article 7.
    10. Bock, H., Kaim, W., Kira, M., & West, R. (1979). Novel organosilicon radical cations. One-electron oxidation of permethylcyclopolysilanes. Journal of the American Chemical Society, 101(26), Article 26. https://doi.org/10.1021/ja00520a006
    11. Kaim, W., & Bock, Hans. (1979). Radical ions. XXVII. Radical ions of tetrakis(trimethylsilyl)butatriene. Journal of Organometallic Chemistry, 164(3), Article 3. https://doi.org/10.1016/S0022-328X(00)81692-7
    12. Bock, H., & Kaim, W. (1979). Radical ions. XXX. Reduction of R3SiO substituted benzene derivatives. Zeitschrift fuer Anorganische und Allgemeine Chemie, 459, 103--110.
  43. 1978

    1. Bock, H., Kaim, W., Semkow, A., & Noeth, Heinrich. (1978). Chemistry of boron. 97. Radical ions. 17. Structure changes during the oxidation of boron-, carbon-, silicon-, or phosphorus-substituted hydrazines. Angewandte Chemie, 90(4), Article 4.
    2. Kaim, W., & Bock, Hans. (1978). Radical ions, XXI. ESR investigation of trimethylsilylmethyl or trimethylsilyl substituted radical cations of anthracene, biphenyl, and 9,10-dihydroanthracene. Chemische Berichte, 111(11), Article 11.
    3. Bock, H., Kaim, W., & Tesmann, Holger. (1978). Substituent effects and perturbation of p systems, XXXV. Radical anions of tin-substituted naphthalenes. Zeitschrift fuer Naturforschung, Teil B:  Anorganische Chemie, Organische Chemie, 33B(11), Article 11.
    4. Bock, H., Kaim, W., & Rohwer, H. E. (1978). Photoelectron spectra and molecular properties. 76. Radical ions, XX. The hyperconjugative stabilization of p-xylene radical cations by trimethylsilyl substituents. Chemische Berichte, 111(11), Article 11.
    5. Kaim, W., & Bock, H. (1978). Radical ions. 22. Radical anion and radical trianion of 1,4-bis(dimethylphosphino)benzene. Journal of the American Chemical Society, 100(20), Article 20. https://doi.org/10.1021/ja00488a042
    6. Bock, H., & Kaim, Wolfgang. (1978). Photoelectron spectra and molecular properties. 75. Radical ions, XIX. One-electron oxidations of (trimethylsilylmethyl-substituted benzenes in the gaseous phase and in solution. Chemische Berichte, 111(11), Article 11.
    7. Kaim, W., & Bock, Hans. (1978). Photoelectron spectra and molecular properties. 77. Radical ions, XXIII. R2P and R2N substituted benzenes: Charge distribution in their cations, anions, and trianions. Chemische Berichte, 111(12), Article 12.
    8. Bock, H., Kaim, W., Wiberg, N., & Ziegleder, Gottfried. (1978). Radical ions, XVI. Tetrazene and its derivatives. 6. One-electron oxidation of silyl-substituted tetrazenes and pentazenes. Chemische Berichte, 111(9), Article 9.
    9. Kaim, W., Bock, H., & Noeth, Heinrich. (1978). Radical ions, XVIII. Do stable radical cations of phosphines exist? Chemische Berichte, 111(9), Article 9.
  44. 1977

    1. Bock, H., & Kaim, Wolfgang. (1977). Radical ions. Part X. Electron-rich alkyl olefins and their radical cations. Tetrahedron Letters, 27, Article 27. https://doi.org/10.1016/S0040-4039(01)83759-X
    2. Bock, H., Kaim, W., & Rohwer, H. E. (1977). Radical ions. XI. One-electron oxidation of alkylsilyl benzenes in the gas phase and in solution. Journal of Organometallic Chemistry, 135(1), Article 1. https://doi.org/10.1016/S0022-328X(00)91700-5
  45. 1976

    1. Bock, H., Kaim, W., & Connolly, J. W. (1976). Radical ions. 9. Radical cations of tetrasilyl-substituted hydrazines. Angewandte Chemie, 88(22), Article 22.

Vorlesungsschwerpunkte liegen auf der Bioanorganischen Chemie und der modernen Koordinationschemie.

Desweiteren wird die Einführung in die Chemie für Umweltschutz- und Verfahrenstechniker betreut.

geboren 1951 in Bad Vilbel (Hessen)

1970 - 1974 Studium der Chemie und Physik an der Johann Wolfgang Goethe-Universität Frankfurt/Main und an der Universität Konstanz
1974 Anfertigung der Diplomarbeit an der Universität Konstanz bei Prof. Dr. E. Daltrozzo
19.12.1974 Diplom-Chemiker-Hauptexamen, Prädikat "mit Auszeichnung"
1975 - 1977 Anfertigung der Dissertation an der Universität Frankfurt bei Prof. Dr. H. Bock ("Herstellung und Untersuchung neuartiger Radikalkationen")
10.02.1978 Promotion zum Dr. phil. nat., Prädikat "summa cum laude"
1978 - 1979 Forschungsaufenthalt als Liebig-Stipendiat des Verbandes der Chemischen Industrie an der Texas A&M University in College Station/Texas bei Prof. Dr. F.A. Cotton
1981 - 1987 Hochschulassistent (C1) am Institut für Anorganische Chemie der Universität Frankfurt
11.10.1982 Habilitation an der Universität Frankfurt, ("Koordinationschemie reduzierter N-Heterocyclen"), Ernennung zum Privatdozenten für Anorganische Chemie
1982 - 1987 Karl Winnacker-Stipendium der Hoechst AG
1987 Heisenberg-Stipendium
18.08.1987 Berufung auf eine ordentliche Professur (C4, Fiebiger-Plan) am Institut für Anorganische Chemie der Universität Stuttgart
21.12.1987 Ernennung zum Professor ebenda
15.10.1993 Verleihung des Literaturpreises des Fonds der Chemischen Industrie für das Buch "Bioanorganische Chemie" (Koautorin Dr. B. Schwederski)
3.11.2003 Ernennung zum Adjunct Professor an der Northern Illinois University (USA)
27.4.2005 Ernennung zum Visiting Professor an der Sun Yat-sen University in Guangzhou (China)
2006 Gastprofessor an der Universidad de Chile in Santiago
2007 Gastprofessor an der Universidad de Concepcion (Chile)
2012 IIT Bombay Review Paper Award 2012
2013 Dr. Luis Federico Leloir-Preis für Internationale Kooperation in Wissenschaft, Technologie und Innovation (Argentinien)
2014 Alfred-Stock Gedächtnispreis der Gesellschaft Deutscher Chemiker (GDCh)
2016-17 Distinguished Visiting Professor am Indian Institute of Technology Bombay (Indien)
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